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142results about How to "Reduce electrostatic repulsion" patented technology

Preparation method and application of pH sensitive type magnetic demulsifier with surface charges and hydrophilic-hydrophobic properties controlled

The invention provides a preparation method and application of a pH sensitive type magnetic demulsifier with surface charges and hydrophilic-hydrophobic properties controlled. Based on magnetic Fe3O4 nanoparticles, through surface modification with silicon dioxide and a grafting copolymerization reaction, surface active monomers and pH sensitive monomer copolymer chains are introduced on the surfaces of the nanoparticles, and the surface grafting structure and the pH value are further adjusted to control the surface charges and hydrophilic-hydrophobic properties of the magnetic nanoparticles. The reduction of the pH value can enhance the hydrophobic property of the magnetic nanoparticles and reduce negative charge repulsive interaction between the demulsifier and oil droplets so that the demulsifier can be absorbed onto the surfaces of the emulsified oil droplets and quickly isolate the emulsified oil droplets under the action of an external magnetic field. Recycling of the magnetic nanoparticles can be achieved, and the demulsifier is be unlikely to be affected by pollution of negative-ion surface active materials in emulsified oil wastewater. According to the magnetic demulsifier, the preparation method is simple, the recycling process is convenient and efficient, the recycling performance is excellent, and therefore the magnetic demulsifier has very board application prospects in the fields of emulsified oil wastewater treatment and oil-water separation.
Owner:HANGZHOU DIANZI UNIV

Method for preparing layer-layer assembled microcapsule based on host-guest interactions

The invention discloses a method for preparing a layer-layer assembling microcapsule based on interaction of subject and object. The method obtains a microcapsule having multilayer structure, which capsule wall has interaction of subject and object by the steps of: forming a multilayer film on a surface of a colloidal particle in a manner of self-assembling layer upon layer, by the interaction of subject and object of beta-cyclodextrin and dicyclopentadienyl iron in polyallylamine grafting beta--cyclodextrin and polyallylamine grafting dicyclopentadienyl iron, based on the colloidal particle as a template; and removing the colloidal particle. Attractive force of the interaction of subject and object and electrostatic repulsive force of identical electrical charges exist in the capsule wall, so that relative size of the two forces can be controlled by changing chemical environment condition of the microcapsule such as PH value, ionic strength, molecular concentration of free subject and the like, thus controllable variation of the microcapsule size can be easily achieved. The method for preparing the microcapsule of the invention has extremely abroad latent applied cost in nanometer materials, drug releasing, biosensor, etc.
Owner:ZHEJIANG UNIV

Azlactone-based polyamide membrane and preparation method thereof

The invention discloses a novel azlactone-based polyamide membrane and a preparation method thereof, and belongs to the technical field of a nanofiltration membrane (loose reverse osmosis membranes).The azlactone-based polyamide membrane is formed by monomers containing azlactone groups and primary aliphatic monomers through interface polymerization reaction; the azlactone-based polyamide membrane shows the electric neutral state or the electropositivity state on a surface structure and has a smooth membrane surface; good anti-pollution performance and excellent interception effect on bivalent and multivalence cations are shown in aspects of performance; the CUT-OFF of the azlactone-based polyamide membrane is 300 to 600 Dalton. The azlactone-based polyamide membrane can be widely appliedto material separation processes such as water softening, dye / salt separation, and concentration and separation of amino acid polypeptide molecules with different molecular weights, and can also be used in the water treatment fields of sea water desalination, brackish water pretreatment and the like.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Slow breaking and quick setting cationic asphalt emulsifier and preparation method thereof

The invention discloses a slow breaking and quick setting cationic asphalt emulsifier, consisting of the following components: fatty acid containing 16-22 carbons, triethylene tetramine, organic solvent, antioxidant, catalyst and nonionic surfactant. In the preparation process of the slow breaking and quick setting cationic asphalt emulsifier, the asphalt emulsifier is prepared by adopting a microwave heating technology, so that the synthesis time is 2.5-3h shorter than the traditional time. When the emulsified asphalt prepared from the slow breaking and quick setting cationic asphalt emulsifier is used for a thin slurry sealing layer, the consumption is 0.8-1.2%; moreover, a pavement can be quickly set, the open traffic time can be shortened to 30-40min, and quick traffic can be realized. The asphalt content of the emulsified asphalt prepared from the slow breaking and quick setting cationic asphalt emulsifier can reach 70%. The whole synthesis process does not pollute the ambient environment.
Owner:抚顺职业技术学院

Chitosan/zwitter-ion and acrylic acid copolymer double network self-healing hydrogel and preparation method thereof

The invention discloses chitosan / zwitter-ion and acrylic acid copolymer double network self-healing hydrogel and a preparation method thereof, and relates to the technical field of hydrogel. The hydrogel is of a double network structure, and formed by a first network and a second network in a mutually penetrating mode, the first network is a physical cross-linking network formed by chitosan and polyvalent negative ions, the second network is a copolymer network formed by a zwitter-ion monomer and an acrylic acid monomer, the first network intersperses in the second network, the chitosan and the polyvalent negative ions are selected to form the first network, the zwitter-ion monomer and the acrylic acid monomer are selected to form the second network, the double network self-healing hydrogel, obtained by the cross-linking purely physical effect, with the mutually interspersed first network and the second network makes the hydrogel have excellent mechanical performance and self-healing ability, the high relative resistance change rate is provided when deformation occurs, and the chitosan / zwitter-ion and acrylic acid copolymer double network self-healing hydrogel has broad applicationprospects in the field of soft electronics, especially as biomedical sensors.
Owner:ZHEJIANG UNIV OF TECH

Hollow glass bead/titanium dioxide membrane composite material and preparation method thereof

The invention provides a hollow glass bead / titanium dioxide membrane composite material and a preparation method thereof. The composite material is of a core-shell structure; and the thickness of a titanium dioxide membrane is 0.3-0.7 microns, the titanium dioxide exists in an anatase type, and the coating quantity is 5-25 percent. The method comprises the following steps of mixing and dissolvingabsolute ethyl alcohol, tetrabutyl titanate and glacial acetic acid, and then dropwise adding a mixed aqueous solution obtained by mixing the absolute ethyl alcohol, water and a pH regulator in a tetrabutyl titanate solution to prepare a titanium dioxide sol; performing ultrasonic cleaning on a hollow glass bead to remove impurities on the surface and perform alkali activation on the surface; andadding the activated hollow glass bead in the titanium dioxide sol, and performing standing and ageing to realize uniformity and compactness of coating of the surface of the hollow glass bead. The hollow glass bead / titanium dioxide membrane composite material and the preparation method solve the problems of low coating ratio of titanium dioxide, unevenness and looseness in a coating layer, low near-infrared band reflectivity and the like.
Owner:CENT SOUTH UNIV

Quaternary ammonium salt modified Pd/C electrocatalyst as well as electrode and preparation and application thereof

The invention discloses a quaternary ammonium salt modified Pd / C electrocatalyst as well as an electrode and preparation and application thereof. The electrocatalyst comprises carbon dust and Pd nanoparticles, wherein the Pd nanoparticles are supported by the carbon dust to form a nano Pd / C composite material; and quaternary ammonium salt is adhered to the surface of the nano Pd / C composite material. The quaternary ammonium salt is adopted to modify Pd / C, by virtue of the electropositivity and the complexing effect (with pollutants) of the quaternary ammonium salt, the electrostatic repulsiveinteraction of chlorine-containing pollutants with cathode electrodes can be alleviated, adsorption of the chlorine-containing pollutants can be enhanced, and dechloridation efficiency can be improved.
Owner:CHONGQING TECH & BUSINESS UNIV

Coal water slurry and preparation method thereof

The invention discloses coal water slurry and a preparation method thereof. The coal water slurry is composed of 60-70wt% of coal powder, 29-39wt% of water and 0.5-1.5wt% of composite additive, and the composite additive comprises, by weight, 10-15 parts of acrylic acid and styrene polymer sodium salt, 45-50 parts of octaphenyl polyoxyethylene ether, 3-5 parts of polyacrylamide, 3-5 parts of sodium polyacrylate, 3-5 parts of hydroxyethyl cellulose, 5-10 parts of Arabic gum, 5-10 parts of inorganic salt, 10-15 parts of pH regulator, 1-3 parts of defoamer, 1-3 parts of emulsifier and 1-3 parts of sterilizing agent. The coal water slurry has the advantage of high concentration.
Owner:宁波敬业控股集团有限公司

Preparation method of cutting thickening liquid

InactiveCN109171082AWeaken electrostatic repulsionStrong shear thickening effectProtective garmentSpecial outerwear garmentsIonSio2 nanoparticle
The invention discloses a preparation method of cutting thickening liquid, wherein polyethylene glycol and modified nanometer silicon dioxide core-shell particles are added into the mixed solution under the action of stirring and ultrasonic waves, are stirred and dispersed under ultrasonic waves for 1-2 hours until a homogeneous emulsion is formed, and the emulsion is placed in a vacuum drying oven and left standing for 24 hours to remove bubbles in the dispersion and obtain a shear thickening liquid. The modified nano-SiO2 core-shell particles are NiAl-LDH / SiO2 nanoparticles. The modified nano-silica core-shell particles are used as the disperse phase, and the modified nano-silica core-shell particles are used as the disperse phase through NiAl-LDH layered bimetallic hydroxides coated onthe surface of SiO2 formed a polymer layer on the surface of SiO2 microspheres. The electrostatic repulsion between particles is weakened by polymer oxide layer to some extent. The core-shell ions ofSiO2 can come closer to each other and form larger particle clusters under the shear action, which results in stronger shear thickening effect.
Owner:XUZHOU NORMAL UNIVERSITY

Method of preparing lignin-based positive ion organic flocculant by using paper mill sludge

The invention relates to a method of preparing a lignin-based positive ion organic flocculant by using paper mill sludge. The method comprises the following steps: extracting a raw material and directly dissolving by alkali liquor; carrying out centrifugal separation to obtain supernate; adjusting the pH of the solution; placing the adjusted solution in a reactor and heating to a certain temperature; sequentially adding N,N-dimethylformamide epoxy chloropropane, ethanediamine and triethylamine; and stirring to react. According to the method provided by the invention, a quantity of amino radicals with positive charges are introduced through an ethanediamine crosslinking method to change the charge electrical property of alkali lignin, so that the potential of the prepared flocculant is +20 to 35mV and the flocculant is positive ion type, and the zeta potential is high, the flocculation efficiency is high, and the addition is about 2mg / l. Therefore, the UV254 removal rate and the DOC removal rate respectively reach 80% and 65% without adding other compounding agents. Meanwhile, paper mill sludge is recycled, so that the paper industry is in sustainable development.
Owner:SHANDONG UNIV
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