2133 results about "Silane" patented technology

A thin film structure is formed that includes hafnium silicon oxide using an atomic layer deposition process. A first reactant including tetrakis ethyl methyl amino hafnium (TEMAH) is introduced onto a substrate. A first portion of the first reactant is chemisorbed to the substrate, whereas a second portion of the first reactant is physorbed to the first portion of the first reactant. A first oxidant is provided onto the substrate. A first thin film including hafnium oxide is formed on the substrate by chemically reacting the first oxidant with the first portion of the first reactant. A second reactant including amino propyl tri ethoxy silane (APTES) is introduced onto the first thin film. A first portion of the second reactant is chemisorbed to the first thin film, whereas a second portion of the second reactant is physorbed to the first portion of the second reactant. A second oxidant is provided onto the first thin film. A second thin film including silicon oxide is formed on the first thin film by chemically reacting the second oxidant with the first portion of the second reactant.

In a film deposition apparatus where bis (tertiary-butylamino) silane (BTBAS) gas is adsorbed on a wafer and then O3 gas is adsorbed on the wafer so that the BTBAS gas is oxidized by the O3 gas thereby depositing a silicon oxide film by rotating a turntable on which the wafer is placed, a laser beam irradiation portion is provided that is capable of irradiating a laser beam to an area spanning from one edge to another edge of a substrate receiving area of the turntable along a direction from an inner side to an outer side of the table.

The present invention is directed to an adhesive composition, which comprises an epoxy resin, a coupling agent, filler, and an effective amount of an amine-curing agent or curative for said epoxy resin. Advantageously, tri-functional and / or tetrafunctional epoxy resins and / or acrylate monomers will be incorporated into the adhesive composition in order to reduce open time and enhance substrate adhesion. Advantageously, a mixture of amines will be used in the curative including aliphatic amines, which have low viscosities and efficiently wet the substrate for enhancing adhesion; polyamines, which can be used to manipulate open time and allow for improved ratio tolerance of the adhesive system; and amine-terminated rubbers (ATBN), which can improve impact resistance and the toughness of the cured adhesive. Preferred coupling agents are silanes.

Embodiments of the present invention generally provide methods for forming a silicon nitride layer on a substrate. In one embodiment, a method of forming a silicon nitride layer using remote plasma chemical vapor deposition (CVD) at a temperature that is less than 300 degrees Celsius is disclosed. The precursors for the remote plasma CVD process include tris(dimethylamino)silane (TRIS), dichlorosilane (DCS), trisilylamine (TSA), bis-t-butylaminosilane (BTBAS), hexachlorodisilane (HCDS) or hexamethylcyclotrisilazane (HMCTZ).

The invention relates to an irradiation crosslinking halogen-free high flame-retardant cable material and a preparation method thereof. The cable materials comprise the following compositions: 45-90 parts of basic resin, 10-55 parts of functional polyolefine resin, 45-125 parts of carbonate hydroxide flame retardant, 30-50 parts of charing agent, 30-50 parts of flame-retardant lubricant, 0.3-3 parts of methyl silicone rubber shell forming agent, 0.5-2 parts of silane surface modifier, 2-5 parts of crosslinking sensitizing agent, 0.2-2 parts of antioxidant, 1-4 parts of lubricant and 0.1-1.0 parts of initiator. The preparation method of the cable material comprises the following steps of: stirring the carbonate hydroxide flame retardant, the charing agent and the flame-retardant lubricant at a high speed for 2 min; and then adding the shell forming agent and continuously stirring at a high speed until the temperature rises to above 100 DEG C, coating the surface of the mixture with the shell forming agent; adding silane coupling agent and stirring for 5-8 min, and carrying out secondary surface treatment; adding initiator-alcohol solution, and discharging after mixing; extruding and pelletizing; finally drying and cooling to obtain the finished cable material product. The flame retardant performance of the product is obviously enhanced, and the product has good shell forming performance in conbustion without droplets.

The invention discloses a preparation method of a silica aerogel aqueous heat-insulating coating, and is characterized in that: prepared SiO2 microspheres are hydrophobic inside and hydrophilic outside; and the aerogel microspheres can be added into an aqueous coating carrier to prepare a good heat-insulating material. The main preparation method comprises the following steps of: before drying the prepared wet gel microspheres, performing surface modification by using an organic silane or an organic chlorosilane, so that the prepared wet gel microspheres are hydrophobic by grafting a large number of alkoxy groups or alkyl groups on the surfaces thereof, or directly preparing the hydrophobic wet gel microspheres; performing surface modification on the microspheres by using a hydrophilic silane coupling agent, and drying to obtain the SiO2 microspheres which are hydrophobic inside and hydrophilic outside; and adding the prepared microspheres into an aqueous coating for preparing the aqueous heat-insulating coating.

The invention discloses an environment-friendly metal surface treating agent and a using method thereof. The treating agent comprises fluoride, zircon salt, silane, silicon dioxide, accelerating agent, dispersing agent and stabilizing agent. A conversion coating having the advantages of being compact and even, strong in corrosion resistance and excellent in adhesive force of the coating is respectively formed on the metal surface of steel and zinc; a treatment method of the metal surface treating agent is simple and is operated at the normal temperature; the original phosphating treatment equipment can be used without any change; and strong acid and strong base are not used as the treating agent; therefore, the environment-friendly metal surface treating agent is safe in production without emission, and is the best substitute product of the phosphating treatment technique and an energy-saving type environment-friendly product.

Methods for forming doped silane and / or semiconductor thin films, doped liquid phase silane compositions useful in such methods, and doped semiconductor thin films and structures. The composition is generally liquid at ambient temperatures and includes a Group IVA atom source and a dopant source. By irradiating a doped liquid silane during at least part of its deposition, a thin, substantially uniform doped oligomerized / polymerized silane film may be formed on a substrate. Such irradiation is believed to convert the doped silane film into a relatively high-molecular weight species with relatively high viscosity and relatively low volatility, typically by cross-linking, isomerization, oligomerization and / or polymerization. A film formed by the irradiation of doped liquid silanes can later be converted (generally by heating and annealing / recrystallization) into a doped, hydrogenated, amorphous silicon film or a doped, at least partially polycrystalline silicon film suitable for electronic devices. Thus, the present invention enables use of high throughput, low cost equipment and techniques for making doped semiconductor films of commercial quality and quantity from doped “liquid silicon.”

This invention relates to substrates for use in immobilizing biomolecules. More particularly, the invention relates to substrates (e.g. glass slides) having a coating of polylysine covalently attached to a silane layer coating the slide, wherein the polylysine compound has a functional NH2 group which can be coupled directly, indirectly, covalently, or non-covalently to a biomolecule (e.g., a DNA or RNA molecule). Even more particularly, the invention relates to specific prescribed addition of ethanalomine to the polylysine thereby forming a mixture which dramatically enhances the effectiveness of the polylysine for immobilizing DNA. Among other applications, the polylysine coated substrates can be used in the preparation of high density arrays for performing hybridization assays

The invention discloses a silane-modified white carbon black-carbon black composite filling and a preparation method thereof. The method is characterized in comprising the following steps of: (1) adding white carbon black which is prepared by means of precipitation and white carbon black which is prepared by means of gas phase into a high-speed mixer according to the weight ratio of 3:1-3:2, slowly and evenly adding silane polysulfide in a spraying way, and gradually heating up at 100-120 DEG C to promote the surface modification reaction to be thoroughly performed; and (2) adding carbon black and mixing for 60-180min according to the weight ratio of the carbon black to the white carbon black which is prepared by means of gas phase and the white carbon black which is prepared by means of precipitation of 1:5-1:10 under the condition of continuous stirring and temperature persevering, and cooling by means of temperature reducing to obtain the silane-modified white carbon black-carbon black composite filling. The silane-modified white carbon black-carbon black composite filling which is prepared by the method improves the dispersibility of the white carbon black which is prepared by means of gas phase in rubber, reduces the charging time of a production field, obviously improves the operation environment, is used for the prescription of a tread rubber of a tire, can obviously reduce the rolling resistance of the tire, and saves the gasoline.

The invention relates to a transparent butyl hot-melt sealant, which is prepared with the following raw materials in parts by weight: 1-20 of butyl rubber, 10-80 of polyisobutylene, 5-30 of plasticizer, 3-10 of tackifier, 3-10 of softener, 0.1-5 of stabilizer, 5-30 of filler and 0.1-5 of adhesion promoting agent. The matching use of the butyl rubber and the polyisobutylene with different molecular weights facilitates the improvement of the strength and workability of the transparent butyl hot-melt sealant. The filler is selected from fumed silica or precipitated silica, which ensures the appearance transparency of the product. Due to the addition of the stabilizer and the strict control of the production process, the appearance transparency and the physical and chemical properties of the product are enhanced. The use of the active group substituted alkoxy silane as a coupling agent improves the adhesion of the product to glass, aluminum and other substrates.

The invention relates to a method for preparing an environment-friendly silicone-modified acrylate adhesive. Raw materials of the preparation method comprise a basic monomer, a modified monomer and an auxiliary agent, wherein the basic monomer comprises a hard monomer, a soft monomer and a crosslinking monomer; the modified monomer comprises a silane monomer, a coupling agent and inorganic nano-powder; the crosslinking monomer is glycidyl acrylate or glycidyl methacrylate; and the grain diameter of the inorganic nano-powder is less than 80 nanometers. In the preparation method, the crosslinking monomer adopts the glycidyl acrylate or the glycidyl methacrylate so as to be environment-friendly. The product prepared by the method is a nanometer / silicone double-modified molecular composite polymer material. The molecular composite material is combined with the advantages of two polymer materials, namely silicone and polyacrylic ester and an inorganic nanometer material, and has better performance and broad application.

A method for the treatment of micro pores (24) within a mica paper (20) that includes obtaining a silane with a molecular weight of between approximately 15 and 300, and adding the silane to the mica paper (20). Then reacting the silane with the inner surface of the micro pores within the mica paper. After this, a resin is impregnated into the mica paper, and the resin binds to the inner surfaces of the micro pores (24) with the mica paper through the silane.

The invention discloses an organic polysilazane / inorganic nano-material super-hydrophobic coating and a preparation method thereof. According to the preparation method, firstly, an organic polysilazane solution is prepared, a silane coupling agent containing hydrophobic units is used for carrying out hydrophobization on an inorganic nano-material, and dispersion liquid of the hydrophobic inorganic nano-material is prepared; then, an organic material or an inorganic material or a metal material serves as a base material, and an organic polysilazane and the hydrophobic inorganic nano-material alternatively deposit on the surface of the base material in sequence through a deposition method; finally, appropriate heat treatment is carried out on the surface which is subjected to multiple times of alternative deposition. The obtained coating shows good super-hydrophobic performance, the contact angles of water drops on the surface of the coating are larger than 150 degrees, the rolling angles are smaller than 10 degrees, and the coating has good mechanical and chemical stability and has wide application prospect in the field of waterproof clothes, exterior wall coating, oil-water separation, biomedicine and the like. According to the method, the preparation process is simple, and large hydrophobic coatings can be established on various base material surfaces.

A composition for modifying a surface of a substrate, the composition comprising: (a) a first polyfluoropolyether silane of the Formula Ia: CF3CF2CF2O(CF(CF3)CF2O)pCF(CF3)—C(O)NH(CH2)3Si(Y)3 wherein each Y is independently a hydrolyzable group and wherein p is 3 to 50; and (b) a second polyfluoropolyether silane of the Formula IIa: (Y′)3Si(CH2)3NHC(O)—CF2O(CF2O)m(C2F4O)qCF2-C(O)NH(CH2)3Si(Y′)3 wherein each Y′ is independently a hydrolyzable group and wherein m is 1 to 50 and q is 3 to 40. A method of making a medicinal inhalation device or a component of a medicinal inhalation device comprising a step of applying to at least a portion of a surface of the device or the component, respectively, the composition.

The invention provides a preparation method for super-hydrophobic silica particles and super-hydrophobic coatings. The method includes the following steps that in step S1, nanometer silica particles and silane modifiers are dispersed in a solvent to form a mixed solution, wherein weight ratio for nanometer silica particles and silane modifiers and the solvent is 1:0.05-0.5:3-20; the PH value of the mixed solution is adjusted to 2.0-5.0 by hydrochloric acid, and then the mixed solution is stirred for 2 to 24 hours at the temperature from 0 DEG C to 50 DEG C; the PH value of the mixed solution is adjusted to 6.0-7.5 by ammonia water, and then the mixed solution is stirred for 0.5 to 3 hours; a dispersion solution of modified nanometer silica particles is achieved; in step S2 the dispersion solution is dispersed into droplets by an ultrasonic nebulization technology and is dried at the temperature from 80 DEG C to 120 DEG C; the super-hydrophobic silica particles are achieved. With the preparation method for super-hydrophobic silica particles and super-hydrophobic coatings, the super-hydrophobic silica particles and the super-hydrophobic coatings are achieved, and have the advantages of being good in super-hydrophobic effect and simple in manufacturing process.

The invention discloses a corrosion and fingerprint resistant surface treatment agent and a preparation method thereof as well as a use method on stainless steel plates. The weight percentages of the chemical ingredients are as follows: 7-45% of organic macromolecule resin, 2-15% of organic silicon resin solution, 0.5-10% of water system wax, 0.5-10% of nano-oxide, 0.1-20% of metallic compound, 0.1-15% of silane mixture and water being the rest. The preparation method comprises: a pH regulator is added into water, and then the silane mixture and nano oxide are slowly added to prepare nano oxide concentrate; the concentrate is mixed and stirred with the ingredients to form film and is mixed into a treatment agent. The use method of the treatment agent on the stainless steel plates comprises washing, coating and drying. Compared with the prior art, the coating of the invention has good adhesion and ductibility on the surface of the stainless steel and is free from flaking off, thereby enhancing the production efficiency. Coatings resisting corrosion, fingerprint and scratch and stainless steel plates can be obtained.

This invention discloses a method for preparing rubber compositions that exhibit unique combinations of properties that are desirable for tire tread applications for enhanced snow / ice and wet traction, low rolling resistance and increased treadwear performance in comparison with conventional silica compounds. Specifically, a high reactively silane coupling agent, such as a mercaptosilane, is used in combination with a silane coupling typically used for silica tread compounds such as bis(triethoxylsilylpropyl)disulfide to treat silica pellets in a hydrocarbon solvent at elevated temperatures. The treated silica is then blended with solution elastomer cement in a hydrocarbon solvent. The deposited reactive silanes partially react with the elastomer molecules forming a layer of polymer grafted on the silica surfaced. This structure significantly improves the silica retention during the steam stripping operation. Almost 100% (99+%) silica retention has been achieved by this invention. After solvent removal from steam stripping, the treated silica / elastomer mixer is dewatered and dried using conventional equipment such as shaker screens, expellers and expanders to form a well-dispersed silica masterbatch. This technique results in silica compounds with excellent silica dispersion and increased filler-polymer interaction, hence enhanced compound performance such as better physical properties, more desirable dynamic properties (low hysteresis at high temperatures and high hysteresis at low temperatures) and increased abrasion resistance.

A preparation method capable of realizing chemical blending of modified nano silicon dioxide particles in an acrylate monomer relates to the field of the application of uniform dispersity of acryloyl oxygen radical contained silane couplint agent modified nano silicon dioxide particles in the acrylate monomer and the application of photocuring products in coating material. According to the method, the modified silicon dioxide is formed in a way that alkoxy on silane couplint agent and hydroxy on the surfaces of the nano silicon dioxide particles are reacted to form firm silicon-oxygen-silicon bonds; the double-bond silane couplint agent modified nano silicon dioxide is mixed in the monomer; during the photopolymerization process of the product, the acryloyl oxygen radical contained silane couplint agent modified nano silicon dioxide and the monomer are polymerized through the chemical bonds, so as to allow the nano silicon dioxide to be more uniformly distributed in the polymer; and the acryloyl oxygen radical contained silane couplint agent modified nano silicon dioxide particles are subjected to laser size analysis and transmission electron microscopy. The purpose of improving the application of the nano silicon dioxide composite acrylate monomer in the coating material field is achieved.

The invention discloses a compound Janus colloid particle and a modified Janus colloid particle as well as preparation methods thereof. Inorganic particles are taken as seeds, and a silane coupling agent modification method, a seed emulsion polymerization method, an inorganic surface etching method, method for inducing recombination functional materials by using polymer gel, and the like are combined to prepare inorganic / polymer, inorganic / inorganic, inorganic / metallic, inorganic / metallic oxide Janus particles. The structure and the size of the Janus particle can be controlled by controlling the activity of reactants, feeding speed, and the concentration of reactants, and the compounding of various kinds of materials can be realized. The Janus particle provided by the invention not only has good dispersibility, but also has good strength and size stability.

The invention relates to a preparation method of the seal glue of an inflaming retarding construction, which belongs to the technical field of the seal glue and comprises: at first, a first polylol and a second polylol are mutually mixed; then isocyanate and dibutyl tin laurate are added for reacting and preparing polyurethane prepolymer; then a terminated silane coupling agent is added for obtaining silane terminated polyurethane prepolymer; then the silane terminated polyurethane prepolymer is stirred mutually and mixed with dried nanometer fillings, a chemical inhibitor, a UV absorbent, a plasticizer, a thixotropic agent, dye and a flame retardant; then a deicer, a caking accelerant, and a catalyst are added, stirred and mixed for preparing the seal glue. The seal glue of the inflaming retarding construction does not have dissociative isocyanate, adopts halogen-free and inflaming retarding technology which is harmless to environment, producing and the health of users, has very good sticking performance with the materials such as glass, aluminum, marble, cement and the like, has good UV resistance and stability and can be broadly applied to the fields of construction, container, road, airport construction, and the like.

The invention relates to the technical fields of photoelectricity and chemical industry, in particular to a low-stress epoxy / organic silicon / POSS nano hybrid material, and a preparation method and application thereof. The epoxy / organic silicon / POSS nano hybrid material comprises (a) an epoxy resin, (b) a polyorganosiloxane, (c) a cage-type polysilsesquioxane (POSS), (d) an epoxy hardener, (e) non-essential silane oxycompound and (f) non-essential assistants, wherein the polyorganosiloxane contains epoxy groups and silane oxygen groups. The cured nano hybrid system has excellent reticular cross-linked structure and does not have microphase separation. The epoxy / organic silicon / POSS nano hybrid material has the advantages of high mechanical strength, favorable heat resistance, favorable cohesive property, high chemical stability, favorable ultraviolet aging resistance, favorable optical transparency and other excellent properties, has the functions of low internal stress and pressure buffer, and can be used as an LED packaging material, optical protection material, circuit protection coating material, adhesive paint and the like.

Reflectors, for example, for lamps used for technical lighting purposes, having a surface which is resistant to mechanical and chemical attack and has high total reflectivity. The body (10) of the reflector, which is, for example, a rolled aluminum product such as a foil, a strip of a sheet, has a surface layer in the form of a layer system containing (a) a pretreatment layer (11), onto which is deposited (b) a functional layer (12) with silanes, having organo-functional groups, of a metal compound, and onto which is deposited (c) a metal-containing reflective layer (13). Layer (a) is deposited on the reflector body and increases the strength of bonding to the above lying layers (a) and (b). Layer (b) effects a flattening and increase in the mechanical strength of the above lying layer (c). The pretreatment layer can be a layer produced by anodic oxidation. The functional layer (b) can be a sol-gel layer. The reflective layer (c) can be a metallic reflective layer, in some cases with one or more protective layers, which are deposited, e.g., by vacuum thin layer deposition process.

Compositions and methods for treating metal substrates and / or bonding metal substrates to polymeric materials, such as rubber, are provided. The compositions include at least one substantially hydrolyzed amino silane and at least one substantially hydrolyzed sulfur-containing silane. Optionally, the compositions include a nano-size particulate material. The compositions provide coatings on metal substrates for protecting the metal from corrosion and for adhering rubber-like polymeric compositions to the metal with polymer-to-metal vulcanization conditions less dependent on the coating thickness, and with use of less coating materials.

The invention discloses a magnetic luminescent composite nano-particle Fe3O4 / CdTe / SiO2 and a preparation method thereof. The method for preparing the magnetic luminescent composite nano-particle Fe3O4 / CdTe / SiO2 comprises the steps of: firstly preparing hydrophobic monodisperse Fe3O4 nano-particles by adopting a chemical oil-phase high-temperature method, and modifying the surfaces of the hydrophobic Fe3O4 nano-particles to ensure that the hydrophobic Fe3O4 nano-particles are dispersed in a water phase; preparing luminescent CdTe quantum dots of which the surfaces are provided with carboxyl groups, and precipitating the luminescent CdTe quantum dots on the surfaces of the magnetic Fe3O4 nano-particles through the co-precipitation; then utilizing ligand exchange to modify a silane coupling agent on the surfaces of the luminescent CdTe quantum dots; and finally forming an outermost SiO2 coating layer through silane or silicon ester hydrolysis. The diameter of the magnetic luminescent composite nano-particle Fe3O4 / CdTe / SiO2 is between 30 and 50nm; the magnetic luminescent composite nano-particle Fe3O4 / CdTe / SiO2has double functions of magnetism and fluorescence at the same time, has strong and durable fluorescence intensity after labeling rat bone marrow-derived mesenchymal stem cells, and apparently reduces cellular magnetic resonance signals. The particle has broad application prospect in the fields such as biological labeling, bioseparation and the like.

Compositions and methods for treating metal substrates and / or bonding metal substrates to polymeric materials, such as rubber, are provided. The compositions include at least one substantially hydrolyzed amino silane and at least one substantially hydrolyzed sulfur-containing silane. Optionally, the compositions include a nano-size particulate material. The compositions provide coatings on metal substrates for protecting the metal from corrosion and for adhering rubber-like polymeric compositions to the metal with polymer-to-metal vulcanization conditions less dependent on the coating thickness, and with use of less coating materials.

This invention discloses a thermoset crylic acid latex and its preparation method and a corrosion resistant bottom coat containing such latex and used in the Al fins of the heat converter of air conditioners, in which, said latex includes a crylic acid kind monomers, an ionic vinyl monomers, an ethene monomers, a vinyl silane coupler, a crosslink monomers, a surface active agent and an initiator to be got by seed latex and semi-continuous drop technology. Said bottom coat includes said thermoset crylic acid latex, water-base coating resin, water-base cross-linker, booster solvent, neutralization agent, a water-base adhesive force accelerant, a catalyst and water.

This invention belongs to the field of nana silicon dioxide modified by organic functioned molecules, especially related to the nano silicon dioxide modified by hindered phenolic antioxygen and its preparation method. The said method is using amino silane coupling agent as a bridge, and chemically grafting the hindered phenolic antioxygen upon the nano silicon dioxide. The amino silane coupling agent accounts for 3%-12% of the total weight of the said processed silicon dioxide and the hindered phenolic antioxygen for 2%-20% by weight. The nano silicon dioxide modified by the said antioxygen molecules can enhance the dispersibility of the nano silicon dioxide the polymer and the comprehensive dynamic performances of the polymer materials, especially the resistance to ageing caused by heat and oxidization during the machining and using processes.

The invention relates to a monocomponent flame-retardant silane modified polyether sealant and a preparation method thereof. The sealant of the invention comprises an MS-polymer resin, a plasticizer, a reinforcement filler, a thixotropic agent, an ultraviolet ray absorbing agent, an ultraviolet ray stabilizing agent, a flame retardant, a crosslinking agent, a hydroxy group scavenger, a coupling agent, an organic tin catalyst and the like. The obtained monocomponent flame-retardant silane modified polyether sealant has the advantages of flame retardation, fast solidification, strong strength, and high weather resistance.