The invention provides
nitrogen mixed
grapheme hydrogel of which the
water content is 90 to 99.5 percent, the electric
conductivity is 10-3-100 S / m, and the
molar ratio of N and C is 1 to 25 percent. The invention further provides
nitrogen mixed
aerogel of which the
molar ratio of N and C is 2 to 20 percent, the
molar ratio of C and O is 15 to 5,
nitrogen atoms existing in the form of
amidogen nitrogen accounts for 40 to 70 percent,
pyridine type nitrogen accounts for 10 to 40 percent,
graphite type nitrogen accounts for 10 to 30 percent, the specific area is 300 to 1500 m<2> / g, the apertures which are micropore account for 10 to 20 percent, the apertures which are mesoporous 20 to 50 percent, the apertures which are
macropore 30 to 70 percent, the
apparent density is 0.01 to 0.2 g / cm<3>, the pore volume is 5 to 20 cm<3> / g, and the electric
conductivity is 1 to 1000 S / m. The nitrogen mixed
grapheme hydrogel or
aerogel and preparation method thereof provided by the invention has the characteristics that the operation is simple, the
equipment requirement is low, the production efficiency is high, the scale-up of the technology is easy, the nitrogen mixed content is controllable and the compounding with other functional substances is simple.