A method for making an article comprising a core material and a
coating thereon, the method comprising the steps of:(a) providing the core material;(b) applying one or more
layers of a crosslinkable polycationic material, wherein the polycationic material is a
reaction product of:(i) an
epoxide of formula (I)wherein X equals bromo, chloro, iodo, or cyano, and R1, R2, R3, R4, independently of one another, are selected from the group consisting of
hydrogen, linear or branched C1-C6-
alkyl, and linear or branched C1-C6-
alkyl which is substituted with
halogen, and(ii) a
polymer having repeating units comprising one or more secondary or
tertiary amine group(s);(c) applying one or more
layers of a polyanionic material; and(d) cross-linking the
layers of polyelectrolytes formed by steps (b) and (c).The articles obtainable by the method of the invention have desirable characteristics regarding adherence to the core material, durability, hydrophilicity, and wettability and are thus useful for the manufacture of medical articles such as ophthalmic devices.