The invention discloses a manufacturing process of a transient voltage suppression diode chip. The manufacturing process of the transient voltage suppression diode chip includes two production processes: a diffusion process and a GPP process. The steps of the diffusion process include original silicon wafer testing, original silicon wafer washing, phosphorus attachment, phosphorus diffusion, phosphorus wafer separation, single side sand blasting, single blasting washing, boron coating, boron diffusion, boron wafer separation, boron side sand blasting, and boron blasting washing, wherein the step of boron diffusion comprises primary boron diffusion and secondary boron diffusion; and the steps of the GPP process sequentially include oxidation, primary photoetching, groove etching, photoresist sintering, groove washing, SIPOS passive film formation, glassivation, secondary photoetching, surface etching, and nickel-gold plating. The manufacturing process of the transient voltage suppression diode chip in the invention reduces defects of the chip, enables voltage distribution to be relatively concentrated, and reduces reverse leakage current at the same time.