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10297 results about "Nonionic surfactant" patented technology

Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant

In an aspect of the invention, a fluoropolymer dispersion, preferably a PTFE dispersion, is provided that comprises fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion has an amount of solids between 35 and 70% by weight. The dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g / mol (hereinafter called low molecular weight fluorinated surfactant) or contains the low molecular weight fluorinated surfactant in an amount of not more than 0.05% by weight based on the total weight solids of the dispersion. The dispersion further comprises a non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants and one or more non-fluorinated anionic surfactants. Through the use of a non-fluorinated anionic surfactant, a dispersion is obtained that has a low viscosity at room temperature (20° C.). The dispersion is further free of aromatic group containing non-ionic surfactants and is accordingly environmentally more friendly and can yield coatings that are less susceptible of discoloration. The amount and nature of the non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants is selected such that the Viscosity Transition Temperature (VTT) (measured as set forth in the examples) of the fluoropolymer dispersion is at least 26, preferably at least 28° C. In a further aspect of the invention, a method is provided to obtain the aforementioned dispersion.
Owner:3M INNOVATIVE PROPERTIES CO

Dimerized alcohol compositions and biodegradible surfactants made therefrom having cold water detergency

There is provided an alcohol composition obtained by dimerizing an olefin feed comprising C6-C10 linear olefins to obtain C12-C20 olefins, followed by conversion to alcohols, such as by hydroformylation. The composition has an average number of branches ranging from 0.9 to 2.0 per molecule. The linear olefin feed preferably comprises at least 85% of C6-C8-olefins. The primary alcohol compositions are then converted to anionic or nonionic surfactants, preferably sulfated or oxyalkylated or both. The sulfated compositions are biodegradable and possess good cold water detergency. The process for making the dimerized primary alcohol comprises dimerizing, in the presence of a homogeneous dimerization catalyst under dimerization conditions, an olefin feed comprising C6-C10 olefins and preferably at least 85 weight % of linear olefins based on the weight of the olefin feed, to obtain a C12-C20; optionally double bond isomerizing said C12-C20 olefins; and converting the C12-C20 olefins to alcohols, preferably through hydroformylation. The process is preferably a one-step dimerization. The homogenous catalyst comprises a mixture of a nickel carboxylate or a nickel chelate, with an alkyl aluminum halide or an alkyl aluminum alkoxide.
Owner:SHELL OIL CO

Corrosion protective cleaning agent for tin-plated steel

PCT No. PCT / EP96 / 01137 Sec. 371 Date Sep. 24, 1997 Sec. 102(e) Date Sep. 24, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96 / 30558 PCT Pub. Date Oct. 3, 1996The invention concerns an aqueous corrosion-protective cleaning solution for tin-plated steel, in particular for tin-plated steel cans, the solution containing complex fluorides of the elements boron, titanium, zirconium, and hafnium; non-ionic surfactants; and corrosion inhibitors and having a pH within the range from 3 to 6. The invention also concerns an aqueous concentrate for preparing the solution by dilution with water and a method of cleaning tin-plated cans using the solution.
Owner:HENKEL KGAA
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