The invention relates to the field of synthetic leather material
polyurethane, in particular to a preparation method of high-
solid-content aqueous
polyurethane for leather. The method comprises the process steps of: prepolymerization reaction: reacting
polyol, a hydrophilic chain
extender and
isocyanate monomer;
monomer modification: adding polyhydroxy
monomer to be modified together with
polyurethane prepolymer;
salt formation by
neutralization: adding a neutralizing agent so that an
emulsion forms salt
ion groups; and chain extension subsequent to emulsification: dissolving an external emulsifying agent and a
sulfonic acid chain
extender in water to obtain a solution and adding the solution to the
system for performing emulsification. In the invention, the emulsification property of theemulsion is improved by using
carboxylic acid type and
sulfonic acid type chain extenders, so that polyurethane and water are fully emulsified; simultaneously, due to the employment of the method in which self emulsification and external emulsification are combined, not only the stable
emulsion can be synthesized, but also the
solid content can be increased; in addition, the use of water as the
solvent in emulsification is consistent with the requirement of clean production process; and the finally-synthesized
emulsion has good film forming performance, high
drying speed, no yellowing, excellent mechanical properties and short process flow, is suitable for the synthesis of leather substrates or surface materials, and can take the place of
solvent-type products.