The invention relates to an organic and inorganic composite all-solid-state electrolyte, in particular to an organic polycarbonate macromolecule and inorganic fast-ion conductor composite all-solid-state electrode and preparation and application of an all-solid-state battery formed from the same. The organic and inorganic composite all-solid-state electrolyte comprises polycarbonate macromolecule, an inorganic fast-ion conductor, a lithium salt and a porous rigid support material, the thickness of the organic and inorganic composite all-solid-state electrolyte is 5-2,000 micrometers, the mechanical strength is 2-150MPa, the room-temperature ionic conductivity is 1*10<-4>-6*10<-3> S / cm, and an electrochemical window is greater than 4V. The organic and inorganic composite all-solid-state electrolyte provided by the invention is easy to prepare and simple to form, has favorable mechanical property, and is relatively high in room-temperature ionic conductivity and relatively wide in electrochemical window; and meanwhile, by the organic and inorganic composite all-solid-state electrolyte, the growth of lithium dendrites of a negative electrode can be effectively prevented, the interface stability is improved, and the long-circulation and safe application performance of the battery are further improved.