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173results about How to "Good chemical and thermal stability" patented technology

Chemical vapor deposition method using alcohol for forming metal oxide thin film

ActiveUS7135207B2Excellent leakage current characteristicFine microstructureFixed capacitor dielectricSemiconductor/solid-state device manufacturingLow leakageMicrostructure
Provided is a method for fabricating a metal oxide thin film in which a metal oxide generated by a chemical reaction between a first reactant and a second reactant is deposited on the surface of a substrate as a thin film. The method involves introducing a first reactant containing a metal-organic compound into a reaction chamber including a substrate; and introducing a second reactant containing alcohol. Direct oxidation of a substrate or a deposition surface is suppressed by a reactant gas during the deposition process, as it uses alcohol vapor including no radical oxygen as a reactant gas for the deposition of a thin film. Also, since the thin film is deposited by the thermal decomposition, which is caused by the chemical reaction between the alcohol vapor and a precursor, the deposition rate is fast. Particularly, the deposition rate is also fast when a metal-organic complex with β-diketone ligands is used as a precursor. Further, a thin film with low leakage current can be obtained as the metal oxide thin film fabrication method using a chemical vapor deposition or atomic layer deposition method grows a thin film with fine microstructure.
Owner:SAMSUNG ELECTRONICS CO LTD

Gas phase approach to in-situ/ex-situ functionalization of porous graphitic carbon via radical-generated molecules

Embodiments disclosed herein include graphitic stationary phase materials functionalized through a gas-phase functionalization reaction, as well as and methods for making and using these materials, including the use of these materials in separation technologies such as, but not limited to, chromatography and solid phase extraction. In an embodiment, a functionalized graphitic stationary phase material may be prepared from high surface area porous graphitic carbon and a radical forming volatilized functionalizing agent. The radical forming volatilized functionalizing agent produces an intermediate that forms a covalent bond with the surface of the porous graphitic material and imparts desired properties to the surface of the graphitic carbon.
Owner:US SYNTHETIC CORP +1

Microporous aluminophosphate molecular sieve membranes for highly selective separations

The present invention discloses microporous aluminophosphate (AlPO4) molecular sieve membranes and methods for making and using the same. The microporous AlPO4 molecular sieve membranes, particularly small pore microporous AlPO-14 and AlPO-18 molecular sieve membranes, are prepared by three different methods, including in-situ crystallization of a layer of AlPO4 molecular sieve crystals on a porous membrane support, coating a layer of polymer-bound AlPO4 molecular sieve crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of AlPO4 molecular sieve crystals on a seed layer of AlPO4 molecular sieve crystals supported on a porous membrane support. The microporous AlPO4 molecular sieve membranes have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas and liquid separations, including carbon dioxide / methane (CO2 / CH4), carbon dioxide / nitrogen (CO2 / N2), and hydrogen / methane (H2 / CH4) separations.
Owner:UOP LLC

Method for separating tetrahydrofuran-ethyl alcohol-water mixture by mixed extraction agent

The invention relates to a method for separating a tetrahydrofuran-ethyl alcohol-water mixture by a mixed extraction agent and a device suitable for the method. According to the method, dimethyl sulfoxide and ethylene glycol are mixed into a mixed extraction agent in certain proportion, the tetrahydrofuran-ethyl alcohol-water mixture firstly enters a first extraction rectifying tower for separation, a tetrahydrofuran product is obtained at the tower top, tower bottom materials enter a second extraction rectifying tower for separation, an ethyl alcohol product is extracted from the tower top, a tower bottom extraction agent and water mixture enters an extraction agent recovery tower, water is extracted from the tower top, and the extraction agent is recycled after being extracted from the tower bottom. The method has the advantages that the energy consumption is low, the technology is simple, equipment investment is small, the product purity of the separated tetrahydrofuran and ethyl alcohol is high and the like, and the adopted ethylene glycol and dimethyl sulfoxide mixed extraction agent can break three binary azeotropes in the system simultaneously and is easy to recycle and good in chemical heat stability.
Owner:QINGDAO UNIV OF SCI & TECH

Preparation of chromatographic stationary phase having porous framework material as matrix for chiral separation

The novel porous framework materials (such as metal organic frameworks or covalent organic frameworks) having a wide range of applications, which was designed and developed in an inventive manner to resolve issues with respect to a carrier material in a stationary phase of a conventional chiral chromatographic column in which the carrier material has poor stability, a chiral resolving agent has a low loading rate, and the chiral resolving agent is prone to loss or is applied in a restricted manner. The porous framework material efficiently loads a chiral resolving agent (such as proteins, enzymes, or macrocyclic antibiotics) by means of covalent bonding, adsorption, embedding, and crosslinking, such that a variety of efficient and durable chiral stationary phases are prepared to serve as a novel high-performance chromatographic column filler used for chromatographic chiral separation (such as high-performance liquid chromatography or capillary chromatography). The various chiral stationary phases prepared by applying the above technique have high separation efficiency, high stability, and durability, and have been successfully applied to perform efficient separation of different kinds of chiral materials such as chiral amino acids and a chiral drug. The technique greatly widens the application range and extends the service life of a chiral chromatographic separation column.
Owner:NANKAI UNIV

Zirconia honeycomb ceramic body

The invention discloses a zirconia honeycomb ceramic body which comprises the raw materials as follows: ceramic raw material, alpha-Al2O3 powder, clay, Mgo, organic cellulose, a binder and ZrO2 powder. The raw materials are mixed evenly by weight percentage and then the binder and moderate amount of water are added, and ball milling, mixed milling and staleness are carried out to prepare pug; the pug is put into a vacuum pugmill for pug milling, and then extrusion molding wet honeycomb ceramic body is put into a far-infrared kiln for drying and shaping into a dry blank; the honeycomb ceramic body is calcined at 1500 DEG C to 1700 DEG C and then cooled and taken out from the kiln. The zirconia honeycomb ceramic body is not only applicable to be used under high temperature environment being over 1500 DEG C in a heating kiln; besides, the heat exchange of the heating kiln is fast and even, thus saving the fuel of the regenerative heating kiln by about 40 percent to 70 percent, promoting yield by more than 15 percent, reducing the emission of NOX gas to be lower than 100ppm and resulting in lower than 150 DEG C gas emission temperature; therefore, the zirconia honeycomb ceramic body greatly improves the burning effect of the regenerative heating kiln, saves fuel and energy, reduces the emission of harmful gases, prolongs the service life of the regenerative heating kiln, improves environment and promotes both economic and social benefits.
Owner:朱根源
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