A covalent triazine skeleton doped hybrid membrane preparation method comprises the steps of (1) preparation of a covalent triazine skeleton, to be more specific, the formula is organic monomer: a trifluoromethanesulfonic acid, wherein a = 5-50, the organic monomer and the trifluoromethanesulfonic acid are rapidly mixed in a microwave reactor for synthetic of CTFs material by microwave heating, the synthesis temperature is 100 to 150 DEG C, and the synthesis time is 10 to 60 minutes; (2) preparation of a hybrid membrane solution, to be more specific, the formula is b covalent triazine skeleton powder: organic matter, b = 1wt%-60wt%, the organic matter is polydimethylsiloxane, polymethylphenyl siloxane, polyimide, polysulfone and poly trimethyl silane-1-propyne; (3) preparation of the hybrid membrane on a porous carrier by a dipping method; and (4) drying of the hybrid membrane. The hybrid membrane prepared by the method has high liquid separation performance and certain gas separation performance, and the synthesis repeatability is good.