The invention relates to a method for selective hydrogenation of full-run
pyrolysis gasoline, which mainly solves the technical problem in the prior art that it is difficult to selectively hydrogenate full-run
pyrolysis gasoline with high
colloid and
free water content. The present invention adopts the
pyrolysis gasoline and
hydrogen of the
hydrocarbon compound fraction with C5
hydrocarbon to dry point of 204 DEG C as raw materials, the
reaction temperature is 30 to 80 DEG C, the reaction pressure is 2.0 to 3.0 MPa, and the fresh oil
space velocity is 2.5 to 5.0 hour-1, under the condition that the
hydrogen / oil volume ratio is 60-120:1, the
raw material is contacted with the catalyst and reacts to convert the diolefin and alkenyl aromatic components in the
raw material into monoolefin and alkylaromatic. Including
alumina support,
active component metal palladium or its
oxide, at least one element selected from IA or IIA in the
periodic table or its
oxide, at least one element selected from IVA or VA in the
periodic table or its
oxide Oxide, the specific surface area of the carrier is 40-160 m2 / g, the total pore volume is 0.3-1.2 ml / g, and the carrier has a technical solution of composite
pore distribution, which solves this problem well and can be used for full-run
pyrolysis gasoline In the industrial production of selective hydrogenation.