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469results about How to "High fluorescence quantum efficiency" patented technology

Organic electroluminescent materials, and preparation method and application thereof

The invention discloses a series of organic electroluminescent materials, and a preparation method and an application thereof. A structural formula of the materials is shown as a formula I. The organic electroluminescent materials shown as the formula I have capacities of electron transportation and hole transportation. An organic electroluminescent device prepared by using the materials has a reduced starting voltage. The series of the materials have relatively good fluorescent quantum efficiency and electroluminescent efficiency, and relatively good film-forming property. Besides, the method for material synthesis and purification is simple and suitable for large-scale production. The organic electroluminescent materials are ideal selection for blue-light emitting materials of the organic electroluminescent device. Applications of the organic electroluminescent materials as luminescent materials independently or as main materials or doping dyes in luminescent layers are also in a protection range. The formula I is shown in the description.
Owner:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD

Benzothiazole-cyanophenyl compound serving as hydrazine fluorescence probe as well as preparation method and application method of benzothiazole-cyanophenyl compound

The invention discloses a benzothiazole-cyanophenyl compound serving as a hydrazine fluorescence probe. The benzothiazole-cyanophenyl compound has a structural formula as shown in (I); the compound is prepared by performing cyclodehydration with bromobenzaldehyde and 2-amino-4-chloro thiophenol serving as the raw materials, then performing coupled reaction in order to connect with a bromobenzaldehyde derivate, and finally performing Knoevenagel reaction with malononitrile. The benzothiazole-cyanophenyl compound has the advantages that the raw materials are low in price and easy to gain, the synthetic route is simple, and the yield is relatively high; rigid structures such as benzothiazole and phenylacetylene groups are introduced into such a fluorescence probe, thus high fluorescence quantum efficiency is realized, and relatively high thermal stability and dissolubility are brought. The probe adopts the photoinduced charge transfer mechanism and the conjugate passivation mechanism, therefore, a response range respect to hydrazine can be expanded; the probe has the characteristics of being fast in response, high in sensitivity and high in selectivity, is suitable for being applied to safety detection of foods as well as safety detection of a laboratory, in particular applied to industrial wastewater monitor; and the probe has a wide application prospect in environment monitoring, ecological protection, disease diagnosis, industrial production and pollution discharge inspection.
Owner:浙江富昇科技有限公司

Compound with anthrone as core and use thereof

The invention discloses a compound with anthrone as a core and a use thereof. According to the compound, anthrone is a mother nucleus and is connected to an aromatic heterocyclic group so that molecular symmetry is destroyed, molecule crystallinity is destroyed, intermolecular aggregation is avoided and good film-forming performances are obtained. The compound as a light-emitting layer material is used for an organic light-emitting diode. An OLED device prepared from the compound has good photoelectric properties and can satisfy the requirements of the panel manufacturing companies.
Owner:JIANGSU SUNERA TECH CO LTD

Five-membered ring substituted compound with xanthone as core and use thereof

The invention discloses a five-membered ring substituted compound with xanthone as a core and a use thereof. According to the compound, xanthone is a mother nucleus and is connected to an aromatic heterocyclic group so that molecular symmetry is destroyed, molecule crystallinity is destroyed, intermolecular aggregation is avoided and good film-forming performances are obtained. The compound as a light-emitting layer material is used for an organic light-emitting diode. An OLED device prepared from the compound has good photoelectric properties and can satisfy the requirements of the panel manufacturing companies.
Owner:JIANGSU SUNERA TECH CO LTD

Organic electroluminescent phosphorescence luminescent material and application thereof

The present invention relates to one kind of electroluminescent phosphorescence material and the organic electroluminescent device with the material. The electroluminescent phosphorescence material has the general expression of LnMX(3-n), where, M is selected from Os, Pd, Pt, Rh and Ir; X is selected from phenylpyridine, acetylacetone and picolinic acid; n is 1, 2 or 3; and L has the structure as shown. The present invention is superior to available red light emitting material, and the electroluminescent phosphorescence material and the organic electroluminescent device with the material have excellent performances, including high light purity, high brightness and high light emitting efficiency.
Owner:TSINGHUA UNIV +1

Benzothiazole-aniline compound used as pH fluorescent probe and preparation method thereof

The invention discloses a benzothiazole-aniline compound used as a pH fluorescent probe and a preparation method thereof. The structural formula is shown as a chemical formula (shown in the description) (I), wherein in the formula, R1 is vinyl, acetenyl, styryl, phenylethynyl, biphenyl or perylene base; and R2 and R3 are both hydrogen, methyl or ethyl alkane. The preparation method comprises the following steps of: taking p-bromobenzaldehyde and 2-aminothiophenol as raw materials, and connecting with iodine-containing nitrobenzene derivative through dehydration cyclization reaction and coupling reaction; and generating the pH fluorescent probe benzothiazole-aniline derivative through reductive amination. Rigid structures, such as benzothiazole and phenylethynyl, are introduced into the fluorescent probe; the fluorescent probe is high in fluorescence quantum efficiency, and high in thermal stability and solubility. The probe can detect pH value under strong acid condition by adopting a photoinduced charge transfer mechanism and a conjugate passivation mechanism; and the probe has the characteristics of rapid response, high sensitivity and high selectivity, and has wide application prospect in environment monitoring, ecological protection, disease diagnosis, industrial production and sewage inspection.
Owner:浙江富昇科技有限公司

Bi(trimethylphenyl) boron derivatives and application thereof in white organic light-emitting diode

The invention discloses bi(trimethylphenyl) boron derivatives. The derivatives are compounds with a structure show in a formula I; the formula I is as shown in the specification; the compounds shown in the formula I can emit efficient blue fluorescence, and also have high triplet level; green and red phosphor doped materials also can be sensitized when the efficient blue fluorescence is emitted; therefore, the technological conditions of preparation of white organic light-emitting diodes (WOLEDs) are met. Meanwhile, the invention also discloses a preparation method of the compounds shown in the formula I and application thereof in preparation of the white organic light-emitting diodes.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Phosphine-containing benzophenone organic light-emitting material, synthesis method and applications thereof

The invention discloses a phosphine-containing benzophenone organic light-emitting material, a synthesis method and applications thereof, wherein the molecular general formula is Ar-Ar'-R, Ar is a phosphine-containing functional group, Ar' is benzophenone, and R is alkane, halogen, aromatic ring or aromatic heterocyclic substituent, and the like. According to the present invention, the synthesis method has advantages of simple process and easy purification, and the synthesized light-emitting material has good electron transmission performance and high fluorescence quantum efficiency, is suitable for preparing the light-emitting layer or electron transmission layer in organic electroluminescent devices, and can further be adopted as the light-emitting material and the electron transmission material in OLEDs, wherein the two layers in the classic OLEDs structure are integrated into one layer so as to simplify the OLEDs device structure and the preparation process; and the light-emitting material of the present invention specifically responds to oxygen, metal ions and the like, and is suitable for use in chemical detection, biological detection, biological imaging, anti-counterfeiting, and other fields.
Owner:SUN YAT SEN UNIV

Blue-fluorescence material and application thereof

The invention relates to a blue-fluorescence material and an application thereof. The blue-fluorescence material and the application thereof start from the perspective of molecular design, tetraphenyl ethylene is taken as the core, and an electron-donating structure and an electron-withdrawing structure which are provided with anthryl groups are introduced to the two sides of a molecule. The tetraphenyl ethylene has the property of aggregation-induced emission, and the fluorescence quenching phenomenon produced by molecular aggregation can be effectively avoided; anthracene is a stable and efficient blue-fluorescence group, and the two anthracene structures are introduced, so that the number of chromophoric groups is increased, the relative molecular mass of the molecule is increased, the glass-transition temperature of the molecular is increased, and the heat stability of the molecule is enhanced. The D (electron-donating) group and the A (electron-withdrawing) group are introduced, transfer of electric charges inside the molecule can be effectively facilitated, and the luminescence property of the molecule is improved. Experiment results show that the blue-fluorescence material has good heat stability and electroluminescene properties, and when the blue-fluorescence material is used as luminescent layers of blue organic electroluminescence devices, blue-light with better color purity and emitting efficiency can be obtained.
Owner:VALIANT CO LTD

Near-infrared boron dipyrromethene (BODIPY) compound based on duplex heterocyclic pyrrole group, and preparation method and application of BODIPY compound

A near-infrared boron dipyrromethene (BODIPY) compound based on a duplex heterocyclic pyrrole group has the structure as follows (refer to the Specification), wherein the substituent group M, N, P, E, F, M', N', P', E' or F' refers to H or Br. The invention synthesizes a big conjugated BODIPY photosensitizer taking duplex thieno pyrrole as a parent for the first time. Due to introduction of two thiophene groups, the absorption spectrum of the photosensitizer is shifted to 680 to 720 nm in a red shift mode, the emission peak is 716 to 750 nm and is in the range (650 to 900 nm) of a biological window, and the fluorescence quantum efficiency of the dye is high. The molar absorption coefficient of the photosensitizer in solution is up to 200,000 M<-1>cm<-1>. S in the two thiophene groups refers to heavy atoms, so that the triplet efficiency of the photosensitizer is increased, the generation efficiency of singlet oxygen is increased, and attractive application prospect in the aspects of bioimaging and photodynamic therapy is achieved.
Owner:NANJING UNIV

Carbon quantum dot solution which contains carboxyl and emits reddish orange fluorescent light and preparing method thereof

The invention discloses a carbon quantum dot solution which contains carboxyl and emits reddish orange fluorescent light and a preparing method thereof and relates to the technical field of quantum dot luminescence. The carbon quantum dot solution which contains carboxyl and emits reddish orange fluorescent light and the preparing method thereof aim to solve the problems of existing red-light-emitting materials that quantum efficiency is low, service life is short, and color purity is low, and the problems of existing red-light-emitting material preparing methods that complexity is high and cost is high. Maleic anhydride and o-phenylenediamine are dissolved in absolute ethyl alcohol and placed in a polytetrafluoroethylene reaction still; ultrasonic treatment and stirring are conducted in sequence; the reaction still is placed in a steel kettle, heating and natural cooling are conducted, and then a reactant is taken out after temperature is reduced to be room temperature; the reactant is filtered, and then the carbon quantum dot solution which contains carboxyl and emits reddish orange fluorescent light is obtained. The method is simple, easy to operate, low in cost and high in yield. The carbon quantum dot solution obtained with the method is high in fluorescence quantum efficiency, high in stability, capable of being placed in the air for a long time, and high in color purity. The carbon quantum dot solution is suitable for serving as a red-light-emitting material, and the method is suitable for preparing the carbon quantum dot solution which emits reddish orange fluorescent light.
Owner:HARBIN INST OF TECH
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