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Application of multifunctional carbon quantum dot taken as fluorescent whitening agent

A fluorescent whitening agent and carbon quantum dot technology, which is applied in the field of fluorescent whitening agents, can solve problems such as poor light resistance, narrow application range, and poor mutual solubility, and achieve simple and effective synthesis methods, wide application fields, and whitening effects Good results

Active Publication Date: 2014-08-20
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the current fluorescent whitening agent can produce better whitening effect, it also shows increasingly serious drawbacks
First, from the perspective of molecular structure, these fluorescent whitening agents are organic compounds with aromatic groups, which have poor water solubility and poor miscibility with other dyes, and are prone to precipitate; second, the fluorescence intensity is affected by pH changes. Larger, narrow application range; third, poor structural stability, prone to photoisomerization, resulting in poor light resistance; fourth, a large amount of chemical raw materials are used in the synthesis process and a large amount of dust is generated, which consumes a lot of energy and causes serious pollution
At present, although there are some environmentally friendly organic fluorescent whitening agents on the market at home and abroad, it is difficult to popularize them due to the difficulty of synthesis technology and high cost.

Method used

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  • Application of multifunctional carbon quantum dot taken as fluorescent whitening agent
  • Application of multifunctional carbon quantum dot taken as fluorescent whitening agent
  • Application of multifunctional carbon quantum dot taken as fluorescent whitening agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A preparation of multifunctional carbon quantum dots using corn as a carbon source mainly includes the following steps:

[0046] Put 5 grams of seaweed into a beaker, add 1mL of 0.5mM NaOH aqueous solution, add 1mL of N,N-dimethylformamide, and mix well; transfer the well-mixed reaction solution into a microwave reactor, and control the reaction temperature at 200°C , react for 30 minutes, separate and purify after cooling, and obtain multifunctional water-soluble carbon quantum dots. (absorption spectrum such as figure 1 a, Fluorescence emission spectrum as figure 1 b, TEM as figure 2 ). Further experiments prove that the fluorescence intensity of the water-soluble carbon quantum dots does not change with temperature, illumination time and pH value (such as Figure 3-5 ), showing good heat resistance, light resistance, strong acid and alkali resistance and other excellent characteristics. The carbon quantum dots did not affect the normal growth of HeLa cells when...

Embodiment 2

[0050] A preparation of multifunctional carbon quantum dots using leaves as a carbon source mainly includes the following steps:

[0051] Put 50 grams of fresh green leaves into a beaker and add 50 mL of 10M H 2 SO 4 The aqueous solution is uniformly mixed; the uniformly mixed reaction solution is transferred to an ultrasonic reactor, the reaction temperature is controlled at 100°C, and the ultrasonic reaction is performed for 12 hours, separated and purified after cooling to obtain multifunctional water-soluble carbon quantum dots.

[0052] The application of the above-mentioned multifunctional carbon quantum dots prepared from leaves as a carbon source as a new type of fluorescent whitening agent in the washing industry:

[0053] When preparing detergent, add different amounts of carbon quantum dots (0-10%), according to the method of cycle washing, after washing pure cotton white cloth with detergent containing carbon quantum dots, carry out the test of cotton cloth whiten...

Embodiment 3

[0055] A preparation of multifunctional carbon quantum dots using citrus as a carbon source mainly includes the following steps:

[0056] Put 10 grams of fresh citrus into a beaker, mash it, add 50mL of 1M NaOH aqueous solution, add 10mL of methanol, and mix well; transfer the well-mixed reaction liquid into a hydrothermal reaction kettle, control the reaction temperature at 250°C, and react 1 Hours, separated and purified after cooling to obtain multifunctional water-soluble carbon quantum dots.

[0057] The application of the above-mentioned multifunctional carbon quantum dots prepared from citrus as a carbon source as a new type of fluorescent whitening agent in the textile industry:

[0058] The prepared carbon quantum dots are mixed with other dyeing agents (the mixing ratio is 2%). After the pure white cotton cloth is printed and dyed, the cotton cloth shows a higher whiteness (90%). At the same time, the cotton cloth is exposed to sunlight. Under irradiation, it has a ...

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Abstract

The invention discloses application of a multifunctional carbon quantum dot taken as a fluorescent whitening agent in the fields of spinning printing and dyeing, washing agents, papermaking, plastics, leathers or coatings and the like. The carbon quantum dot disclosed by the invention has the advantages of wide application field, good whitening effect and good light resistance, is innoxious and environmentally friendly, can be applied to the fields of spinning printing and dyeing, washing agents, papermaking, plastics, leathers or coatings and the like, and can generate unforeseeable technical effect because the carbon quantum dot can generate active oxygen free radicals under the condition of illumination, wherein the unforeseeable technical effect is as follows: the bacteria attached to the surfaces of spinning printing and dyeing materials, the washing agents, paper sheets, the plastics, the leathers or the coatings and the like can be effectively killed after the spinning printing and dyeing materials, the washing agents, paper sheets, the plastics, the leathers or the coatings and the like which are doped with the carbon quantum dot absorb ultraviolet light.

Description

technical field [0001] The present invention relates to the technical field of fluorescent whitening agents. More specifically, it relates to the application of a multifunctional carbon quantum dot as a fluorescent whitening agent. Background technique [0002] White items (such as fabrics, papers, white plastics, etc.) can absorb blue light (350-500nm) in visible light due to the organic compounds contained in them, making them slightly yellow, and at the same time, the reduction of reflected light makes people feel dull in color . The following two methods are usually used for surface whitening. One is to add a small amount of blue dye to the article, and use the complementary principle of increasing the blue color and the yellowish color of the substrate to achieve the purpose of whitening. Although this method can whiten, but because the total amount of reflected light is reduced, the color of the item is dull and gray, and the effect is not good. Another method is ch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H21/30C11D3/42C11D9/44C09D7/12C09D5/22D06P1/00D06P3/60D06M11/74C08L27/06C08K3/04C01B31/02C09K11/65C01B32/15
Inventor 汪鹏飞蓝敏焕张文军刘卫敏葛介超
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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