The present invention relates to an energy storage self-lighting road marking dope which is characterized in that the raw materials of the dope consist of 15 to 16 portions of petroleum resin, 15 to 16 portions of quartz sand, 25 to 50 portions of calcium carbonate powder, 18 to 20 portions of glass bead, 0.8 to 1.2 portions of polyethylene wax, 0.8 to 1.5 portions of dioctylphthalate, 1.0 to 1.2 portions of EVA hot-melt adhesive, 2.0 to 4.0 portions of titanium pigment and 2.0 to 10 portions of energy storage luminescent material by weight proportion. All the raw materials of the energy storage self-lighting road marking dope are commercial universal industrial raw materials, the energy storage self-lighting road marking dope has low manufacturing cost and simple technology, also has good energy storage self-lighting and reflecting functions and ensures that a road marking has the characteristics of good luminescent recognizability, high luminescent intensity and long luminescent time no matter under the condition with light or without light; and the marking dope can be widely applied to various kinds of roads without illuminating device, such as highway, town road, village road, montane road, and the like, and can improve the traffic safety factor greatly.