3957 results about "Industrial waste water" patented technology

The present invention is an industrial waste water microwave electrodeless ultraviolet photocatalysis-dual membrane separation coupling treatment device, the device mainly consists of a reactor (1), a membrane separation system (2), a microwave electrodeless ultraviolet light source system (4), an aeration system, and an ozone tail gas decomposition device (7) connected to the reactor, and an inlet and outlet water system, wherein: the upper and lower parts of the reactor are respectively the reaction zone and the aeration zone, which are separated by a water distribution plate (5); the membrane separation system The microwave electrodeless ultraviolet light source system is located in the reaction zone and is separated by a corrugated partition (3); the aeration system is composed of a microporous aeration head (6) and a blower (8), and the microporous aeration head is located in the aeration At the bottom of the zone, the blower sends air to the aeration zone through the air duct. The invention has the characteristics of high reaction rate, complete degradation of organic matter, long-term operation and the like, and has strong operability and high safety. It is suitable for the treatment of refractory organic industrial wastewater, and it is also suitable for sterilization and disinfection in the field of water supply.

The invention relates to microwave photocatalytic degradation reaction equipment and belongs to the technical field of waste water treatment. The equipment provided by the invention aims at solving the problems that a membrane separation component is destroyed owning to thermal abrasion and the outer side of an electrodeless ultra violet lamp screen is scaled as the electrodeless ultraviolet lamp screen adopts a quartz tube in the prior art of microwave photocatalytic degradation on industrial waste water containing organic pollutant in a package manner. According to the invention, an organic matter membrane separation assembly is contained in a metal cage-shaped microwave shielding case, influence of microwave is isolated, and the absorption of metal particles and carbon particles, which are inevitably attached on the surface of the membrane separation assembly, to microwave energy is inhibited, so that thermal abrasion destruction on the membrane separation assembly is avoided; meanwhile, the cage-shaped microwave shielding case disclosed by the invention does not influence the function and operation of the membrane separation assembly; and an ultrasonic transducer is attached to the outer side of the wall face of a reactor, and the scale is immediately eliminated by high frequency ultrasonic wave through sound wave propagation by virtue of the wall of the reactor and a liquid mixture inside the wall.

The invention belongs to the technical fields of environmental engineering and bioengineering and particularly relates to a sphingomonas strain and applications thereof in the aspects of shortcut nitrification-denitrification of nitrogen-containing industrial waste water and domestic sewage and treatment of a polluted water source. The sphingomonas strain is separated from a Taihu water in China,is a local strain and has high safety; and the strain can be grown in a basic medium, wherein in the basic medium, CO2 is used as a carbon source and energy or CO2 and an organism are used as a mixedcarbon source and energy, and ammonia nitrogen or nitrate nitrogen is used as a nitrogen source. The bacterium liquid, the dormancy cell and the immobilized strain of the sphingomonas can decompose ammonia nitrogen into nitrite nitrogen and simultaneously can decompose the ammonia nitrogen into nitrogen, can be used as denitrification microorganism for converting the ammonia nitrogen into the nitrite nitrogen and the nitrogen, thereby achieving the shortcut nitrification-denitrification. The strain can rapidly decompose the ammonia nitrogen and is suitable for treating the nitrogen-containingindustrial waste water and domestic sewage as well as polluted water source.

The invention discloses a granular filtering material for adsorbing and removing heavy metals in water and a preparation method thereof. The granular material consists of the following components in part by mass: 80-120 parts of an adsorbent, 7-14 pats of an additive and 0.5-3 parts of a binding agent, wherein the adsorbent consists of the following components in part by mass: 50-70 parts of coal ash and 30-50 parts of zeolite powder or sea-foam stone powder; the additive consists of the following components in part by mass: 5-7 parts of Mg-Al hydrotalcite, 2-6 parts of biochar and 0.5-1 part of magnesium Lignosulfonate; the binding agent is bentonite. The granular filtering material is prepared through the steps of adsorbent acid modification, biochar preparation, granulation and heat treatment process. According to the invention, the prepared granular filtering material is 3-6 mm in granule size, is large in adsorption capacity and excellent in adsorption effect and can effectively remove heavy metals in water, and no secondary pollutants are dissolved out, so that the granular filtering material can be applied to the treatment on heavy metal micro-polluted water and industrial waste water containing heavy metals, and has good economic and social benefits.

A method for monitoring the composition and flow rate of wastes discharged from industrial waste water treatment facilities into a common collection system for eventual processing at central waste water treatment plant (WWTP). The information is transmitted to a remote computer and stored in a database, and is then analyzed to prepare reports of particular interest to the receiving WWTP or treatment facility. The system includes a data collection and sending unit, a remote Internet Server computer with a database capable of receiving and storing the collected information, and a web server and reporting unit to analyze the data, prepare reports, and send out alarms. It is a further intention of this invention to correlate the incoming data from said industrial waste water treatment plants with known flows and compositions at said central WWTP to predict the flow and composition of influx water at the WWTP.

The invention discloses an advanced treatment system and method for high-concentration percolate in a comprehensive garbage disposal plant, belonging to the field of industrial waste water treatment. The system is formed by connecting a regulating tank, a coagulative precipitation tank, an upflow anaerobic sludge bed reaction tank, a primary anoxic and aerobic membrane bioreactor, advanced oxidation treatment equipment, a secondary anoxic and aerobic membrane bioreactor, nanofiltration membrane treatment equipment, an ozone contact tank and an active carbon filtering tower in sequence. According to the system, garbage percolate can be treated comprehensively, different pollutants in garbage percolate are treated in a classified way by combining physical, chemical and biological treatment,advanced treatment of garbage percolate is realized, and classified treatment for removing pollutants such as organic matters, heavy metals, ammonia, nitrogen and the like is performed, so that treated effluent strictly reaches the requirement of water pollution discharge degree limit in the Household Garbage Landfill Pollution Control Standard, the system runs stably for a long time, and treatment cost is lower than that of a secondary disc pipe reverse osmosis membrane process.

The invention relates to a catalyst for catalyzing and oxidizing waste water under normal temperature and normal pressure. The catalyst comprises active carbon, oxide of Fe and oxides of any two, three or four elements selected from Cu, Zn, Mn, Co, Ni or Ce, wherein the active carbon is used as a carrier, the oxide of Fe is used as a primary active component, and the oxides of any two, three or four elements selected from Cu, Zn, Mn, Co, Ni or Ce are used as secondary active components. The invention also relates to a preparation method of the catalyst.

The invention relates to a combined technique of treating and reusing the organic sewage which is rich in cyanogen, ammonia and salt, and adopts the combined techniques of acidified decyanation (with the sodium cyanide recollected), basified ammonia blowing (with ammonium salt recollected), oxidation by adding chlorine, biological treatment, precipitation and clarification, deep oxidation, biological active carbon filtering, one-time brine refining, microstraining film, and other combined techniques, and then the chlorine alkali is produced after the secondary brine refining in the chlorine alkali industry and the entrance into the ionic membrane electrobath. The combined technique can be used for treating the industrial sewage in the tricyanogen chloride, chlorine alkali, gold mine, galvanization and other industries and conduct recovery of the resources, thereby overcoming the disadvantages that the prior art has narrow applicability and treatment function and disappointing treatment result, cannot recollect the resources, and has high treatment cost and unobvious economical benefit. The combination of the technique is scientific and reasonable, the technique is novel, unique and mature, the treatment is good, and the combined technique has a plurality of functions, strong applicability, wide use range and remarkable environmental and economical benefit.

The invention discloses a salt-separation zero-discharge system for high-salt industrial wastewater and belongs to the field of water treatment. The high-salt industrial wastewater enters a first-stage salt separation system after subjected to chemical softening through a precise pretreatment unit and concentration desalination through a membrane separation concentration unit, nanofiltration produced water and nanofiltration concentrated water which are produced after first-stage salt separation are concentrated by a high-pressure flat membrane system and conveyed to an advanced oxidation system of a crystallization recycling unit for oxidation treatment respectively, and obtained products are supplied to a second-stage salt separation system; the second-stage salt separation system adopts two multiple-effect evaporation or MVR systems or adopts a multiple-effect evaporation or MVR system and a freezing crystallization system. The salt-separation zero-discharge system has the beneficial effects as follows: the two stages of salt separation systems supplement each other, various inorganic salts are separated completely, and production of mixed abraum salts is reduced to the greatest extent; first-stage salt separation serves as guarantee of second-stage salt separation, the salt separation efficiency of the whole system can be guaranteed under the condition of larger fluctuation of quality of inflow water, and the impact load resistance of the system is enhanced.

The invention belongs to the technical field of industrial waste water treatment and pollution treatment, in particular to a preparation method of a citric acid modified rape straw adsorbent and an application thereof. The method comprises the following steps of: firstly washing natural rape straws, drying, crashing, sieving for standby; and then modifying the surface of the rape straws with citric acid so as to prepare the novel adsorbent citric acid modified rape straws. The prepared adsorbent is used for treating industrial waste water, and removing cationic dye and heavy metal ions form the waste water. The result of a static absorption test shows the adsorbent has excellent adsorption effect for the cationic dye and heavy metal ions. By the invention, the agriculture waste resource is recycled; and cheap and efficient novel adsorbent is obtained to be used for treating the industrial waste water. The preparation process of the adsorbent is simple, and the prepared adsorbent has low cost and excellent adsorption effect.

The invention provides a method for preparing a metal ion imprinting adsorbent with an underwater selective recognition performance. The method comprises the steps of: preparation of an amino functional material: dispersing a nuclear body material into a methanol solution, slowly adding 3-propylaminoethoxy silane, uniformly stirring, and then, continuously adding a cross-linking agent and a stabilizer to form the amino functional material; and preparation of the metal ion imprinting adsorbent: dispersing the amino functional material in the methanol solution, and exposing to ultrasound to obtain a solution A; dissolving isonicotinic acid and metal template ions in deionized water to form a solution B; dripping the solution B into the solution A, and reacting to obtain a white sol-like product; and eluting the metal template ions: performing Soxhlet extraction by using an acetic acid-methanol solution, then eluting the metal template ions by using a hydrochloric acid, and drying to obtain the metal ion imprinting adsorbent. The metal ion imprinting adsorbent disclosed by the invention can be widely applied to advanced treatment of drinking water as well as enrichment recovery or rapid analysis detection of metal ions in different water bodies, such as industrial waste water, aquaculture water and seawater.

The invention discloses a large-scaled culture method of high-concentration nitrosobacteria and application thereof. The method comprises the following steps of: (1) adding an enrichment culture solution with initial ammonia nitrogen mass concentration of 30-500mg / L in a reaction device with functions of stirring, heating and aeration; preparing activated sludge of a waste water treatment plant in activated sludge of 0.5-20% for primary inoculation to conduct the enrichment culture of the nitrosobacteria by 2-6d as a culture cycle, wherein extra ammonium salts and a growth promoter are added during the enrichment culture of the nitrosobacteria; (2) ending the culture when the concentration of NO2-N in the solution is accumulated to reach 70-95% of the concentration of total nitrogen; adding a flocculating agent for flocculation and sedimentation; and allowing to stand still to remove supernate, and then adding the enrichment culture solution to start the culture of the second cycle; and (3) continuously conducting 3-8 cycles of the enrichment culture to obtain the high-concentration nitrosobacteria. By adopting the nitrosobacteria to strengthen the bi-nitrification treatment of ammonia nitrogen contained waste water, the method has the advantages of high stress resistance, low cost and high efficiency and is suitable for the complicated treatment of ammonia nitrogen contained industrial waste water.

A process for reducing the content and volume of organic matter in a wastewater stream comprises contacting the latter with a nanofiltration device so as to obtain a concentrate, and a permeate as an aqueous stream containing any salts of non-precipitable metal ions which may be present, then contacting the concentrate with a preferably backflashable ultrafiltration device, and optionally also with activated carbon. This process may be part of a broader one which also removes other components from the wastewater stream. A module comprising (a) a nanofiltration device; (b) a preferably backflashable ultrafiltration device; (c) conduit(s) adapted to convey nanofiltration device concentrate to the ultrafiltration device; and optionally (d) a vessel containing activated carbon; as well as a system for treating a wastewater stream which includes this module, also form part of the invention.

The invention provides a processing technique of waste water containing antibiotic and the purpose thereof, wherein, the technique adopts the following steps: pretreatment, two-phase anaerobic, improving SBR, immobilized microorganism-aeration biological filter, and improving the coagulating sedimentation combination technique. The detailed technique is introduced in the specification. The invention has the advantages that the industrial waste water is pretreated and the two-phase anaerobic technique is adopted, the great mass of sulfate radical is eliminated, the treatment effect for producing firedamp anaerobic phase and the stability of operation are improved, the energy is recycled and the operating cost is lowered; through the immobilized microorganism-aeration biological filter, the biological treatment effect is improved, and the operating cost for back end processing is lowered; the deep processing can ensure that the waste water is discharged by reaching the standard, and can meet the requirement to the upgrade and reorganization of sewage treatment plants when the environment protection standard is improved in the future. The invention has the purpose that the processing technique not only is applicable to the treatment for the waster water containing antibiotic and the upgrade and reorganization of the prior engineering of sewage disposal, but also is applicable to the engineering of sewage disposal and other sewage disposals with high salt content, high sulfate radical content, high ammonia and nitrogen content, high COD content and higher concentration organic matter which is hard to be degraded.

The invention relates to a method for treating wastewater and discloses a method for treating wastewater in an automobile manufacturing plant. A method of pretreatment, two-stage physicochemical treatment, biochemical treatment and advanced treatment is adopted to treat wastewater. The method for treating wastewater in the automobile manufacturing plant has little investment, small occupied area and low operating cost and has good integrated treatment effect on industrial wastewater and domestic sewage discharged from the automobile manufacturing plant.

The invention discloses a preparation method of a chitosan / titanium dioxide composite material. The chitosan is dissolved in colloid titanium dioxide solution containing acetic acid or the chitosan is blended with the colloid titanium dioxide after being dissolved by the acetic acid, by stirring, the dioxide is homogeneously dispersed in TiO2 colloid solution, and homogeneous chitosan / TiO2 mixed solution is prepared. The mass weight percentage of the chitosan in the mixed solution is 1 to 10 percent, and the mass weight percentage of TiO2 is 0.5 to 20 percent; the chitosan / titanium dioxide composite material is consolidated and prepared after the mixed solution is degassed. The compound membrane prepared by the method is transparent or semitransparent. The preparation method of the invention is simple, the raw material is inexpensive, the material source is abundant, and TiO2 is distributed in the compound material at nano-size. The prepared product has wide application range, and has photocatalysis degradation characteristic on waste water of helianthine and other dye, etc. The composite material can be taken as an indoor air purifying agent, an industrial waste water treating agent, an antibacterial film, self-cleaning fiber and antibacterial fiber, etc.

An electrocoagulation system for removing contaminants from waste effluents comprising an electrocoagulation reactor having charged and uncharged plates and allowing serial flow of water therethrough. The reactor is connected to a voltage source to charge some of the plates positive and some negative, with uncharged plates between the positive and negative plates. The system allows waste water to enter the reactor for coagulation therein, the waste water leaving the reactor to enter a defoam tank for agitation which allows trapped bubbles to rise to the surface of the tank as foam. From the defoam tank, waste water goes through a sludge thickener, to allow sludge to settle at the bottom thereof and waste water is drawn off from the sludge thickener to flow to a clarifier. The pump removes sludge forming at the bottom of clarifier to take it back to the sludge thickener. The sludge is drawn out the bottom of the sludge thickener for transport to a press where most of the water is removed therefrom. Water is drawn off the top of the clarifier for transport to a conventional sewer system, or for reuse.

A pretreatment method for glyphosate industrial waste water relates to the technical field of the treatment method for the industrial waste water from pesticides. The invention provides the pretreatment method for the glyphosate industrial waste water, which can remove glyphosate, sodium chloride and reduce COD cr value. The pretreatment method can effectively remove the vast majority of sodium chloride and glyphosate in the glyphosate industrial waste water by adopting steps such as adjusting Ph value, catalytic oxidation, calcification phosphorus removal, triple effect evaporation crystallized sodium chloride removal and the like, and greatly reduces COD cr value; the pretreated waste water can be discharged into a follow-up biochemical treatment system for biochemical treatment, thus causing waste water to be discharged after reaching standards, being beneficial to the protection of the environment and having good social benefits.

The invention belongs to the technical field of treatment of high concentration organic waste water, and particularly relates to a method for degrading nitrobenzene waste water by a polyphase electrocatalytic oxidation process. The invention solves the problems of high cost and long time consumption in the traditional nitrobenzene waste water methods, low efficiency and high energy consumption in the electrolytic process, high oxidant consumption, high cost and the like in the Fenton process in the prior art for treating high concentration nitrobenzene water waste. The invention mainly adopts the catalytic oxidation action of transition metal catalysts in the electric field, and combines the Fenton process, thereby effectively degrading the high concentration nitrobenzene waste water. The method comprises the following steps that: (1) heterocatalytic reagents (solid catalysts) and particle electrodes, mainly including active carbon, and transition metal oxides and salts, are used for avoiding economic loss and secondary pollution to the environment, which are caused by catalyst loss in heterocatalytic oxidation; (2) under the condition of low pH value of the waste water in cooperation with Fe2+ with strong reducibility, a coupling reactor composed of an electrolysis field and oxidation reaction is used for generating chain reaction for generating an OH hydroxyl free radical, and the OH hydroxyl free radical can carrying out nonselective oxidization on organic substances, thereby finally oxidizing organic pollutants into carbon dioxide and water; (3) by using electric energy as an excitation energy and using cheap air as raw material, nitrobenzene substances in waste water are efficiently degraded under the coupling action of the polyphase electrocatalytic oxidation process and the Fenton process; (4) and the reactor is composed of a direct current regulated power supply, a feed electrode and an electrolytic bath.

The invention belongs to the material field for removing the arsenic in water by settlement, more particularly relates to polyelement composite metal oxide arsenic removal settlement agent and an application method thereof based on iron oxide, manganese oxide, and aluminum oxide. The invention uses an ectopic preparation method or situ preparation method for preparing and obtaining polyelement composite metal oxide arsenic removal settlement agent which comprises hydrated iron oxide, hydroxyl-hydrated ferric hydroxide, hydrated aluminum oxide, hydroxyl-hydrated alumina, hydrated manganese oxide and the like. The polyelement composite metal oxide arsenic removal settlement agent can be used for removing the arsenic pollutants in water bodies such as lakes, reservoirs, rivers, groundwater, drinking water, industrial waste water, and the like; in addition, the settlement agent can also be used for removing the heavy metals such as copper, chromium, cadmium, lead, and the like, and the pollutants such as iron, manganese, phosphates, and the like in water by settlement.

The invention relates to a system for preparing potassium sulfate from high-salt-content industrial wastewater and belongs to the field of water treatment. The high-salt-content industrial wastewater is pretreated through a regulating pool, a pipeline mixer, a high-density precipitate pool, a V-type filter pool, ion exchange resin and an ultrafiltration membrane system and then concentrated through a first section reverse osmosis membrane system and a second section reverse osmosis membrane system and then enters a nanofiltration membrane system for salt separation, nanofiltration produced water and thick water enter a plate-pipe type high-pressure flat sheet membrane system II and a plate-pipe type high-pressure flat sheet membrane system I respectively to be concentrated again, the concentrated thick water enters a freezing crystallization system for crystallization, crystals enter a potassium sulfate preparing system to be converted, freezing mother liquor and the concentrated nanofiltration produced water enter an advanced oxidizing system for oxidation and then enter an evaporative crystallization system for crystallization, and produced sodium sulfate crystal salt enters a potassium sulfate preparing system for conversion. The system has the advantages that the scale of the nanofiltration system is reduced, and investment cost is reduced; salt separation is thorough, and operation cost is low; the purity of the crystallization salt is high; mirabilite and sodium sulfateare converted into potassium sulfate, and the economic value is improved.

The invention relates to a method for treating organic amine industrial waste water by Fenton-like oxidation-flocculation. According to the method, the pH value of the waste water is adjusted to 3-5, and the temperature of the waste water is adjusted to 20-40 DEG C; a catalyst is added, wherein active ingredients of the catalyst comprise: ferrous sulfate, anhydrous cupric sulphate and manganese sulfate monohydrate, wherein the mass ratio of the ferrous sulfate to the anhydrous cupric sulphate to the manganese sulfate monohydrate is (5-10):1:(0-5); H2O2 (30%) is added, and the oxidation reaction time is 4 hours; after completing the oxidation reaction, sodium hydroxide is added to adjust the pH value of the waste water to 8-10; adding a chemical coagulant and an organic polymer flocculant, such that partial suspended solids, colloids and partial organic amines in the waste water are concurrently coagulated. According to the present invention, the Fenton-like oxidation-flocculation is adopted as the pretreatment for the organic amine waste water, such that the organic amines in the waste water can be effectively removed, the poison and the impact on microorganisms due to the high concentration organic amines in the wastewater can be reduced, the subsequent biological treatment is easily performed for the sewage.

The invention provides an amidoxime-based chelate polyacrylonitrile fiber and its preparation method. The preparation method of the amidoxime-based chelate polyacrylonitrile fiber comprises the following steps that 1, polyacrylonitrile fibers are subjected to irradiation cross-linking under the conditions of an inert gas atmosphere and an irradiation amount of 20 to 2000kGy; and 2, the polyacrylonitrile fibers subjected to irradiation cross-linking undergo an amidoximation reaction. The invention also provides a use of the amidoxime-based chelate polyacrylonitrile fiber as a metal ion adsorption material. Through the preparation method which is simple relatively, the amidoxime-based chelate polyacrylonitrile fiber which has good mechanical properties, high fiber breaking strength, a long reuse life and stable performances and is damaged difficultly is obtained. The amidoxime-based chelate polyacrylonitrile fiber can be utilized as a metal ion adsorption material, is suitable for the fields of purification of industrial waste water or slag, or extraction of uranium of seawater, has excellent effects of adsorbing multiple metal ions, and can greatly reduce an industrial cost.

The invention discloses a process for deeply treating and recycling high-salinity industrial waste water, which belongs to the technical field of environmental protection and comprehsnive resource utilization. Combined equipment is adopted, and comprises ultrafiltration equipment, ion exchange softening equipment, volume-type reverse osmosis equipment, medium-pressure flat plate reverse osmosis equipment, high-pressure flat plate reverse osmosis equipment, ultrahigh-pressure flat plate reverse osmosis equipment, high-pressure flat plate filtration equipment, secondary reverse osmosis equipment and the like. After being treated with a combined process, industrial waste water can be concentrated by 36-180 times; in combination with evaporative crystallization equipment, zero discharge of industrial waste water can be realized, and salts in industrial waste water can be recovered; and after secondary reverse osmosis treatment, produced water can be recycled by 100 percent. The process has the advantages of flexible combined process, small floor area, saving in investment, high efficiency, low running cost, stable and reliable effect, and the like.

The invention discloses an intensified deep concentration system for high-salt-content industrial wastewater and a technology thereof and belongs to the field of water treatment. The high-salt-content industrial wastewater is adjusted through an adjusting tank, settled through a softening settling pond, filtered through a V-type filter tank, filtered through an ultrafiltration device in an intensified mode and concentrated through a first-stage reverse osmosis device, then the hardness is removed through an ion exchange resin device, and salt separation is performed through a nanofiltration device; thick water of the nanofiltration device is concentrated through a frequent electrode transfer electrodialysis device, produced water is oxidized through an advanced oxidization device and then enters a general produced water tank, and thick water is crystallized through a freezing crystallization system and crystallized with sodium sulfate; produced water of the nanofiltration device is concentrated through a second-stage reverse osmosis device and concentrated again through the frequent electrode transfer electrodialysis device, produced water is oxidized through the advanced oxidization device and enters the general produced water tank, and thick water is crystallized through an MVR evaporative crystallization device and crystallized with sodium chloride. The intensified deep concentration system has the advantages that potential safety hazards caused by high-pressure operation are effectively reduced; the problem that the COD content is high after thick salt water is highly concentrated is effectively solved, the purity of crystallized salt is improved, and the using value of the crystallized salt is improved; the system is high in automation degree, easy to operate, low in operation pressure, stable in operation, high in purity of the crystallized salt, low in operation cost and the like.

The invention discloses a biological disposing method of waste water through coupling the anaerobic ammonoxidation and methanation denitrification, which is characterized by the following: inoculating the particle sludge with methanation, denitrification and anaerobic ammonoxidation activity in the expansion grain sludge bed (EGSB); inoculating aerobic ammonoxidation bacteria in the biological aerating filter (BAF) or SHARON technique or SBR reactor; connecting the EGSB reactor and BAF or SHARON technique or SBR reactor; realizing the biological disposal of waste water through controlling pH value, temperature, dissolved oxygen, external reflow rate, load velocity, oxidizing reducing potential and organic COD density, ammonia nitrogen density.

The invention relates to amphiprotic high-molecule chelated flocculating agent for various heavy metal waste water treatments and preparation method thereof. The amphiprotic high-molecule chelated flocculating agent of the invention is formed by following steps: configuring a basic skeleton by cationic dimethyl diallyl ammonium chloride and acrylamide copolymer; reacting with aldehydes and polyamine through Mannich to connect the polyamine to the high-molecule chain; then reacting with carbon bisulfide in alkaline condition. The invention mainly overcomes the disadvantages that the existing high-molecule chelating agent has excessive flocs negative charge caused by the suspension of part chelating radical because the space steric resistance of high-molecule chain and chelated radical are not matched so as to reduce the flocculating settling performance and the traditional heavy metal waste water processing method has complicated technique, high cost, low efficiency and cannot be suitable for large-scaled heavy metal waste water treatment. The invention is widely applied to the heavy metal waste water treatment of various types, in particular suitable for removing the heavy metal ions in industrial waste water and domestic sewage.

The invention discloses a preparation method and an application of immobilized bacteria for improving the denitrification efficiency of a constructed wetland. 1. The preparation steps are as follows: 1) screening and culturing aerobic denitrification strains which are screened out of the constructed wetland in a thermotank; 2) selecting aerobic denitrification bacteria in slope conservation, inoculating into a sterile enrichment culture medium and aerating to get bacterial suspension; 3) using sodium alginate-polyvinyl alcohol to embed so as to get the immobilized aerobic denitrification bacteria; and 4) taking pellets of the aerobic denitrification bacteria out of a refrigerator, washing with double distilled water or physiological saline, soaking in the physiological saline, and aerating to activate the immobilized pellets. 2. An application of the immobilized bacteria in the constructed wetland is as follows: filling the immobilized pellets into a simulation column of the constructed wetland for performing waste water denitrification treatment. The preparation method of the immobilized bacteria is simple, the production cost is low, the application in the industrial waste water treatment is easy, the denitrification efficiency is high, the accumulation amount of nitrite nitrogen is low, and the service life is long.

A method for treating wastewater with phenol and ammonia coal from chemical industry by double-tower steam stripping is disclosed. The steps of the technical method of the invention are as follows: 1. acidic gases are deacidified; 2. amino is removed; 3. ammonia is concentrated and purified. The invention has the advantages that: 1. by the method of the invention, acidic gases and ammonia can be removed comparatively thoroughly, residual quantity of the acidic gases can be reduced to be below 10mg / L and the total amount of ammonia can be reduced to below 10mg / L, thereby avoiding the resistance function of the ammonia to the follow-up biochemical section; 2. the method of the invention can greatly improve the desorption rate of phenol or decrease the operation cost of the extraction section; 3. the method of the invention can effectively separate volatile phenol from ammonia, and the content of the volatile phenol and the acidic gases can be decreased to below 10mg / L, thus lightening the energy consumption and purifying load in the follow-up ammonia refining process; 4. the concentration of the ammonia can be improved to over 98 percent; 5. the method can effectively remove oil contaminants with low boiling point.

The invention discloses a recycling harmless treatment method of stainless steel pickling waste water, belonging to the toxic and harmful industrial waste water treatment field. The method comprises the following steps of: 1) recycling inorganic acids by an acid separation method: pumping stainless steel pickling waste water in which suspended matters are removed through filtering into a resin column so that the inorganic acids are absorbed on the resin; 2) removing impurities by a goethite method: pumping heavy metal ion solution into a reaction kettle, adjusting pH to a range from 3.5 to 5.0, and continuing reacting for 30-90 min, thereby removing iron, chromium and fluorine in the heavy metal ion solution in the form of dregs; 3) recycling nickel by a neutralized sedimentation method: feeding an alkaline liquor to nickel solution to adjust pH to a range from 9.5 to 12.5, and filtering and washing the filter residues, thereby obtaining nickelous hydroxide; and 4) performing harmlesstreatment on the dregs: after washing the dregs, adding lime powder to the dregs to realize stabilization treatment of harmful elements. The method is simple in operation and convenient for management; the high-concentration inorganic acids and nickel and the like contained in the waste water are all recycled, and simultaneously the generated dregs are harmlessly treated; and therefore the integration of economic benefit,environmental benefit and social benefit is realized.