898 results about "Cyanogen" patented technology

The invention discloses a method of plating Nickel with magnalium alloy without cyanogen and the plating technique. The direction for the plating solution is: 20 to 80g.dm-3 of copper charred phosphate; one or several of the 60 to 320g.dm-3 of sodium charred phosphate or Potassium charred phosphate or 60 to 250g.dm-3 of sodium citric acid, 5 to 20g.dm-3 of Potassium sodium tartaric acid, 60 to 250g.dm-3 of HEDP and 60 to 250g.dm-3 of amine ethylene; one or several of the 5 to 20g.dm-3 of hydrogen amine di-fluorin or 5 to20 g.dm-3 sodium fluoride or 5 to 20g.dm-3 of Potassium fluoride or 5 to 20g.dm-3 of lithium fluoride. The plating solution chooses the nickel sulfate or alkali type nickel carbonate or nickel acetic acid as the main salt and adds the reducing agent, combination agent and stabilization agent. The plating technique adopts the acid plating copper-plating three nickel-plating chromium. The invention has little pollution to the environment, high binding power and erosion-proof property.

The invention relates to a combined technique of treating and reusing the organic sewage which is rich in cyanogen, ammonia and salt, and adopts the combined techniques of acidified decyanation (with the sodium cyanide recollected), basified ammonia blowing (with ammonium salt recollected), oxidation by adding chlorine, biological treatment, precipitation and clarification, deep oxidation, biological active carbon filtering, one-time brine refining, microstraining film, and other combined techniques, and then the chlorine alkali is produced after the secondary brine refining in the chlorine alkali industry and the entrance into the ionic membrane electrobath. The combined technique can be used for treating the industrial sewage in the tricyanogen chloride, chlorine alkali, gold mine, galvanization and other industries and conduct recovery of the resources, thereby overcoming the disadvantages that the prior art has narrow applicability and treatment function and disappointing treatment result, cannot recollect the resources, and has high treatment cost and unobvious economical benefit. The combination of the technique is scientific and reasonable, the technique is novel, unique and mature, the treatment is good, and the combined technique has a plurality of functions, strong applicability, wide use range and remarkable environmental and economical benefit.

This invention discloses a wet pre-process method for unwieldy gold mines containing As and Sb and a method for picking up gold not using cyanogens, which applies two steps of wet pre-process and no cyanogens to pick up gold and turns As and Sb to soluble materials to be solved in water and turns them in the state not influending the soak of gold then to remove them, which alters the tranditional method for picking up gold with cyanides, thus, gold can be picked up smoothly from the unwieldy gold mines of the type of fine particle dip-dye containing AS and Sb, the pick-up rate reaches to 70-95%.

The invention discloses a technique and a system for zero discharging treatment of electroplating effluent. The system comprises a material classifying pre-treatment system, a biochemical comprehensive treatment system, a membrane method system, a membrane concentrated liquor vaporization system and a sludge classifying treatment system which are connected with each other in turn, wherein the sludge classifying treatment system is connected with the material classifying pre-treatment system and the biochemical comprehensive treatment system; the raw wastewater enters into the material classifying pre-treatment system; water generated by the membrane method system is recycled; the condensed liquid from the membrane concentrated liquor vaporization system is re-injected into the material classifying pre-treatment system. According to the technique provided by the invention, the wastewater is firstly treated in classifying form, so that the heavy pollution ions, such as, chromium, cyanogen, nickel, and the like, and the oily matters in the wastewater are effectively removed, and then the biochemical comprehensive treatment system is used for further treating, and lastly, the RO+SuperRo two-level combination mode is utilized to achieve the gross recovery at 94%, and meanwhile, the liquid amount for evaporation treatment is less than 6% of the gross wastewater quantity, the cost of the evaporation treatment is saved, the sludge is recycled, the waste of resources is avoided and the sludge treating cost is saved.

The invention discloses a cyanogen-free plating method of a zinc alloy die casting. The method is a plating method in which cyanogen-free copper-zinc alloy, copper-stannum alloy or ormolu is subjected to barrel plating or rack plating in a cyanogen-free copper-zinc alloy solution, copper-stannum alloy solution or ormolu solution as grounding layers so as to provide a pre-plating layer with good bonding force for subsequent plating or chemical plating. The method comprises the following steps: (1) carrying out ultrasonic wax removal or tumbling wax removal on a zinc alloy die casting blank; (2) washing; (3) chemically removing oil; (4) washing; (5) activating with 0.5% sulfuric acid; (6) washing; (7) carrying out barrel plating or rack plating on the alloys in the cyanogen-free copper-zinc alloy solution, copper-stannum alloy solution or ormolu solution; (8) washing; and (9) carrying out the subsequent plating or chemical plating. By using the method provided by the invention, cyanogen-free barrel plating or rack plating alloy is carried out on the zinc alloy die casting so that the obtained plating layer is semi-bright and has good bonding force.

The invention discloses cyanogen-free silver-plating electroplating liquid containing an auxiliary complexing agent. The cyanogen-free silver-plating electroplating liquid containing the auxiliary complexing agent is composed of a silver ion source material, a complexing agent, the auxiliary complexing agent, a supporting electrolyte, an electroplating additive, a pH adjusting agent and the like;the components of the electroplating liquid and the contents are as follows: 30-60 g/L of silver ion source material, 140-200 g/L of complexing agent, 10-50 g/L of auxiliary complexing agent, 10-30 g/L of supporting electrolyte, 100-800 mg/L of electroplating additive and 10-30 g/L of pH adjusting agent. The cyanogen-free silver-plating electroplating liquid containing the auxiliary complexing agent provided by the invention has the advantages that: the electroplating liquid is stable and has low toxicity, the anodic passivation in the electroplating process can be better inhibited, the anodeis normally dissolved, the electroplating liquid can be continuously utilized for long time, the electroplating layer has a good bonding force and is bright, and the electroplating liquid can be applied to multiple fields including decorative electroplating, functional electroplating and the like.

The invention discloses a recycling and harmless treatment method for cyaniding tailing slurry. In the method, the cyaniding tailing slurry containing cyanogen, thiocyanate, heavy metal and arsenic and liquid containing hydrogen peroxide are subjected to direct mixing treatment; the method utilizes high specific surface area of micro-fine granular ore to add the contact opportunity between the thiocyanate and the hydrogen peroxide and the contact area between gas phase and liquid phase through surface adsorption to accelerate a speed of oxidation-reduction reaction and an acidifying and stripping speed, utilizes metallic substances contained in slag to accelerate the reaction rate of the oxidation-reduction reaction without the addition of catalyst, and can reduce cost; meanwhile, in neutralization, Fe3+ in the slag is utilized to meet the requirement of arsenic precipitation without the addition of an arsenic precipitation reagent; when residual cyanides is removed from the hydrogen peroxide liquid, the hydrogen peroxide liquid and cyano complexes which are difficult to remove through the oxidation-reduction reaction form sediment so that the residual thiocyanate is further removed; the method can make the conversion rate of the thiocyanate in the ore slurry more than or equal to 88 percent; and compared with the treatment of filter pressing clear liquid of homogeneous ore slurry, the total reclaiming rate can be increased by over 20 percent.

The invention relates to a DNA-targeted o-dicyano-acenaphtho pyrazine compound in the field of application of antineoplastic medicaments. The compound is prepared by taking acenaphthene quinone as a raw material and performing bromination, cyclization and aromatic nucleophilic substitution reaction. The compound is characterized in that: one end takes an amino straight chain of a flexible side chain or an annular group as an electron-donating group, while the other end takes two cyanogen groups as electron-withdrawing groups; the two ends form an electron deficient large-plane conjugated system; and the structure accords with an ideal DNA intercalator. The compound shows obvious inhibitory activity to an in vitro test of MCF-7 (human mammary cancer cells).

The invention relates to a catalytic wet oxidation method of cyanogen-containing industrial wastewater. With the method, problems of catalysts in existing technologies, such as difficult shaping, low activity, easy crushing, short service life, low COD removing rate, and complicated technology, can be solved. According to the invention, industrial wastewater and gas containing elementary oxygen are adopted as raw materials. Under a reaction temperature of 230-300 DEG C, a reaction pressure of 3-10MPa, and a liquid space velocity of 0.5-2.5h<-1>, the raw materials contact a catalyst, such tat a COD removing rate is higher than 95%. After the treatment, a total cyanogen content is smaller than 5ppm. The adopted catalyst is a composite carrier loaded with at least one metal selected from Pt,Pd, Ru, Ir, or Rh, or an oxide of the metals. With the method provided by the invention, the problem is well solved. The method can be used in industrial treatment of cyanogen-containing industrial wastewater.

The invention discloses achromobacter xylosoxidans subsp.xylosoxidans LH-N25 with CGMCC No.6972. The invention also discloses a heterotrophic nitrification and aerobic denitrification microorganism bactericide. The microorganism bactericide comprises achromobacter xylosoxidans subsp.xylosoxidans LH-N25 or also comprises paracoccus aminovorans LH-N40; and the strains are combined according to any ratio. The invention also discloses a preparation method of the microorganism bactericide. The microorganism bactericide disclosed by the invention not only can solve the problem that total nitrogen cannot be easily removed in the traditional reactor, but also can effectively remove ammonia nitrogen and total nitrogen in a water body in the same reactor, and has tolerance and degradation ability on the toxic substances such as phenols, amines, hetercyclics, cyanogens and polyaromatic hydrocarbon in the wastewater at the same time. The microorganism bactericide is especially suitable for chemical wastewater containing nitrogen, is simple in treatment process, stable in effect, and resistant to impact of environmental toxic substances, and has a wide application prospect in treatment of chemical wastewater containing nitrogen.

The invention relates to an aluminum electrolysis waste tank lining harmless treatment device and a treatment method. The treatment device is characterized by comprising a water adding reaction bin, a cyanogen removing agent or fluorine removing agent adding reaction bin, a fluorine removing agent or cyanogen removing agent adding reaction bin, a neutralizing agent adding reaction bin and a collecting bin connected in sequence. The treatment method comprises the following process: an aluminum electrolysis waste tank lining is crushed and milled as powder to feed in the water adding reaction bin, the cyanogen removing agent or fluorine removing agent adding reaction bin, the fluorine removing agent or cyanogen removing agent adding reaction bin, the neutralizing agent adding reaction bin and the collecting bin in sequence; charging, reaction and discharge are performed at the same time to form continuous aluminum electrolysis waste tank lining harmless treatment process; treated slurry is totally poured in the collecting bin, and is injected in a filter press by the collecting bin for pressing and filtration; harmless slag is carried out; and filtrate is recycled, so that the waste tank lining harmless treatment is realized, the treatment efficiency is high, the effect is good, and the operation is flexibility, simple and convenient.

The invention discloses a high density copper electroplating liquid without cyanogen and aluminum alloy boss electroplating craft, which is characterized by the following: allocating 250-400ml/l high density copper opening jar agent without cyanogen, 80-120 ml/l high density copper accelerant without cyanogen, 0-5 ml/l high density copper additive without cyanogen and surplus as water; adjusting pH value at 9. 2-10. 0; getting the electroplating liquid; adding following steps between twice depositing zinc step and acid bright coppering step; pre-coating the high density copper without cyanogen; petting the aluminum alloy boss into high density coppering liquid without cyanogen; electroplating; thick-plating; putting the aluminum alloy boss into thick coating liquid; proceeding thick electroplating. This craft can decrease cost and modify electroplating quality.

The invention relates to a light-sensitive resin composite and a method for manufacturing a printed circuit board using the same. The resin composition comprises the following components: (A) an adhesive polymer, (B) a light polymeric compound with an ethylene unsaturated bond and (C1) a stilbazole compound represented by the following general formula (1); in the formula (1), R1, R2 and R3 respectively represent alkyl with the carbon number of 1-20, alkoxyl with the carbon number of 1-6, alkyl ester with the carbon number of 1-6, amido, and alkyl amido, carboxyl, cyanogen group, nitryl or (methyl) acryloyl group with the carbon number of 1-20 independently, m and n respectively represent the integer of 1-3 independently, and a, b and c respectively represent the integer of 0-5 independently.

The invention relates to a hazard-free treatment and utilization method for an aluminium electrolysis waste slot liner. The hazard-free treatment and utilization method is characterized by comprising the steps of (1) performing sorting and separating on the aluminium electrolysis waste slot liner based on an aluminium electrolysis waste negative electrode carbon material and a waste fireproof material; (2) performing smashing separately; (3) performing powder grinding separately; (4) measuring content values of cyanogen and fluorine;(5) adding a solid cyanogen removal agent and a solid fluorine removal agent, and performing material mixing; (6) performing a cyanogen removal and fluorine removal and neutral reaction on the waste fireproof material; (7) performing a cyanogen removal and fluorine removal reaction on the waste negative electrode carbon material; (8) pressing and filtering material slurry obtained in the step (6), recycling the filtering liquid, and taking filtering slag for road pavement; and (9) pressing and filtering material slurry obtained in the step (7), recycling the filtering liquid, and taking filtering slag as carbon brick for manufacturing a blast furnace. By adoption of the hazard-free treatment and utilization method, different kinds of waste materials in the waste slot liner are processed, respective optimal technological parameters specific to different kinds of waste materials are selected, and the hazard-free slag can be sorted and reasonably recycled.

The method discloses a method for treating wastewater generated during the production of acrylic fibers. The method is to treat comprehensive wastewater generated during the production of acrylic fibers taking acrylonitrile as a first monomer by steps of uniform settlement, pH value adjustment, aerobic biochemical treatment and flocculation precipitation. The method adds iron ions, magnesian ion, calcium ion and other metallic ions during the biochemical treatment to react the ions with cyanogens, nitrile, amine and other substances in the wastewater to form chelate complexs, thereby preventing the substances form damaging enzymes of microorganisms, solving the problem of chelating poisoning of microorganisms during water treatment, improving activities of microorganisms and wastewater treatment effect, shortening treatment process, reducing treatment cost and having the characteristics of simpleness, practicality, stable treatment effect, high removal efficiency and wide application range, etc.

The invention discloses a preparation method and application of 2-mercaptobenzothiazole modified activated carbon, belonging to the fields of wet metallurgy and precious metal recovery. The preparation method comprises the steps of dissolving 2-mercaptobenzothiazole as an activated carbon modifying agent with an organic solvent or a strong base solution, and preparing 2-mercaptobenzothiazole modified activated carbon by virtue of an impregnation method, wherein the 2-mercaptobenzothiazole modified activated carbon is used for adsorbing Au(S2O3)2<3->. According to the preparation method, the disadvantages that cyanogen is polluted during adsorption recovery of activated carbon supported copper cyanide complex ions (Cu(CN)4<2->), a modifying process of loaded prussian blue is complicated, and continuous adsorption is difficultly realized, and the like are solved; the modified activated carbon is capable of adsorbing gold in thiosulfate gold leaching and has the advantages of multistage adsorption capacity and the like.

The invention discloses a method for culturing a microbial flora for purifying waste water, which comprises the following steps: A, filtering, settling and concentrating active sludge, adding coking wastewater at the temperature of below 33 DEG C, adding nutrients, proteins and microbial growth hormone at the same time, aerating for 3 to 5 days under a constant-temperature condition, settling, discharging supernatant, adding glucose solution and domesticating according to the operation mode of a batch reactor activated sludge process; B, at the end of domestication, screening cocci, bacilli and spirilla, placing into containers for low-temperature storage respectively, injecting 10 percent glucose solution into the containers for repair, and taking the bacterial strains out 24 hours later for mixing; and C, performing aerobic and anaerobic culture of the mixed bacterial strains, and adding a stabilizer and strain protective agent. For common active sludge, the method can reduce the phenol, cyanogens, COD and ammonia nitrogen content of coking wastewater more effectively and reduce sludge discharge obviously.