The invention relates to an organic electroluminescent material of a large-pi
conjugated system. A structural general formula is shown in the specification, wherein A represents aromatic groups. By the organic electroluminescent material, phenanthro-
carbazole series derivatives are synthesized; the series derivatives are large in
conjugated system and high in film-forming performance, can form a large large-pi
conjugated system, and can be used as organic electroluminescent devices (
OLED) easily; and particularly, by substituting the introduction of an F atom,
electron transition can be regulated, the emission range of different materials emitting
blue light from light blue to dark blue can be formed, the demand on light-emitting materials and particularly the required light
blue light emitting materials is met. Simultaneously, the organic electroluminescent material is easy to synthesize and purify and low in cost, and can meet the demand of industrial development. The efficiency of the material can be regulated, the efficiency can be improved obviously, the film-forming performance is improved obviously, and the service life of the material is prolonged obviously; and the material is easy and convenient to synthesize and wide in application range, can be used in multiple materials of the devices, and has a bright prospect.