350 results about "Organic sulfonic acid" patented technology

A solid electrolyte capacitor having a solid electrolyte layer that is formed of a polymeric product layer of a polymerizable monomer. The polymeric product layer is doped with an organic sulfonic acid selected from the group consisting of an aromatic polysulfonic acid, an organic sulfonic acid having a hydroxy group, an organic sulfonic acid having a carboxyl group, an alicyclic sulfonic acid, and a benzoquinone sulfonic acid.

A corrosion inhibiting paint composition comprises from about 1 to 20 parts by weight of a corrosion inhibiting additive mixture comprising 1 to 25 parts by weight of an organic sulfonic acid in a mixture of 75 to 99 parts by weight of butyrolactone; from about 10 to 99 parts by weight of film forming polymer; and from about 0 to 89 parts by weight of a liquid medium selected from the group consisting of water, organic solvents for the film forming polymer and mixtures thereof. Another corrosion inhibiting paint composition comprises from about 1 to 20 parts by weight of a corrosion inhibiting additive mixture comprising 1 to 25 parts by weight of an organic sulfonic acid in a mixture of 75 to 99 parts by weight of butyrolactone; from about 10 to 98.5 parts by weight of film forming polymer; from about 0.5 to 20 parts of an intrinsically conductive polymer; and from about 0 to 89 parts of liquid medium selected from the group consisting of water and organic solvents for the film forming polymer and mixtures thereof. Metal substrates containing a coating composition comprise an organic film forming matrix and an additive mixture comprising organic sulfonic acid and butyrolactone. A method for imparting corrosion resistance to metal substrates comprises providing a layer of a coating composition on at least one surface of the substrate, formed from an organic film forming matrix and an additive mixture comprising an organic sulfonic acid and butyrolactone.

A method for metallizing a through silicon via feature in a semiconductor integrated circuit device substrate comprising immersing the semiconductor integrated circuit device substrate into an electrolytic copper deposition composition comprising a source of copper ions, an organic sulfonic acid or inorganic acid, or one or more organic compounds selected from among polarizers and / or depolarizers, and chloride ions.

A method for metallizing a through silicon via feature in a semiconductor integrated circuit device substrate comprising immersing the semiconductor integrated circuit device substrate into an electrolytic copper deposition composition comprising a source of copper ions, an organic sulfonic acid or inorganic acid, or one or more organic compounds selected from among polarizers and / or depolarizers, and chloride ions.

The invention relates to a metallized solar cell and the method of making thereof that includes depositing a metal or metals such as silver, nickel, copper, tin, indium, gallium, or selenium or their alloys on solar cells in a manner to form more substantial and robust electrical contacts that can carry current more efficiently and effectively or to provide the active layers required to convert sunlight into electricity. These deposits also protect the underlying metallic materials from corrosion, oxidation or other environmental changes that would deleteriously affect the electrical performance of the cell. The invention also relates to the use of specialized electroplating chemistries that minimize residual stress and / or are free of organic sulfonic acids to minimize chemical attack on solar cell substrates or prior metallizations that include organic and / or inorganic binders or related materials for depositing the initial metallic portions of the cell.

The present invention discloses a polyaniline / polyacrylonitrile composite conductive fibre and its preparation method. Its preparation method includes the following steps: firstly, preparing soluble polyaniline doped by organic sulfonic acid, then using solvent to dissolve the organic sulfonate of polyaniline and polyacrylonitrile; adopting wet spinning technology to press the mixed solution through spinning nozzle, and extruding the mixed solution into the coagulating bath, drawing and washing with water so as to obtain the invented composite conductive fibre. The electric conductivity of said fibre can be controlled in the range of 10(-7)-10(-1)(S / cm), and said fibre has good strength, generally it is 1.5CN / dtex-3.4 / detex, can be used for making electromagnetic shielding material and anti-static material.

The present invention relates to an airgel and a preparation method thereof, in particular to a graphene / conductive polymer aerogel and a preparation method thereof, wherein the composition of the graphene / conductive polymer aerogel comprises: Graphene, organic sulfonic acid doped conductive high molecular polymer, the mass ratio of graphene and organic sulfonic acid doped conductive high molecular polymer is 1:20-20:1. The airgel has high electrical conductivity and excellent stability, and can be directly used in the fields of conductive materials, heat insulation materials, energy storage materials, catalytic materials, adsorption materials and the like.

The invention relates to a pyrophosphoric acid bath for use in cyanogen-free copper-tin alloy plating that contains an additive (A) composed an amine derivative, an epihalohydrin and a glycidyl ether compound with ratios of epihalohydrin to glycidyl ether compound being 0.5-2 to 0.1-5 on mol basis, per 1 mol of the amine derivative, has a pH of 3 to 9, and optionally contains an additive (B) composed of an organic sulfonic acid and / or an organic sulfonic acid salt, and to a copper-tin alloy coating obtainable by using the bath. The invention provides a pyrophosphoric acid bath for use in copper-tin alloy plating of the cyanogen-free type utilizable on an industrial scale, particularly, capable of performing uniform treatment to exhibit low defective product generation rates even with the current density being incessantly changing between a high state and a low state, as a barrel plating method, and a copper-tin alloy coating obtainable by using the bath.

One aspect of the invention is to provide a composition comprising a titanium dioxide particle having on the surface of said particle a substantially encapsulating layer comprising a pyrogenically-deposited metal oxide; said substantially encapsulating layer having on its surface at least one organic surface treatment material selected from an organo-silane, an organo-siloxane, a fluoro-silane, an organo-phosphonate, an organo-acid phosphate, an organo-pyrophosphate, an organo-polyphosphate, an organo-metaphosphate, an organo-phosphinate, an organo-sulfonic compound, a hydrocarbon-based carboxylic acid, an associated ester of a hydrocarbon-based carboxylic acid, a derivative of a hydrocarbon-based carboxylic acid, a hydrocarbon-based amide, a low molecular weight hydrocarbon wax, a low molecular weight polyolefin, a co-polymer of a low molecular weight polyolefin, a hydrocarbon-based polyol, a derivative of a hydrocarbon-based polyol, an alkanolamine, a derivative of an alkanolamine, an organic dispersing agent, or a mixture thereof. Another aspect of the invention is to provide processes for producing said composition.

The invention discloses alkyl sulfonic acid chemical tinning solution, which comprises the following components in terms of contents: 1 to 40 g / L of organic sulfonic acid tin salt, 5 to 250 g / L of organic acid, 5 to 300 g / L of complexing agent, 20 to 150 g / L of reducing agent, 0.5 to 50 g / L of surfactant, 0.1 to 25 g / L of antioxidant, 1 to 500 mg / L of noble metal salt and 0.5 to 3 g / L of brightening agent. The invention also discloses an alkyl sulfonic acid chemical tinning solution based tinning process, which comprises the following steps: 1) pre-treating a copper or copper alloy workpiece to be tinned; 2) putting the pre-treated copper or copper alloy workpiece into the alkyl sulfonic acid chemical tinning solution to be tinned; and 3) after tinning, performing neutralization and color change preventing treatment. The process adopts a two-step method of presoaking and chemical tinning to deposit a tin layer with the thickness of 2.0 mu m on the copper or copper alloy matrix; and the tin layer is applied to chemical tinning processes for PCBs and integrated circuits and the like, has the advantages of good weldability, strong whisker growth resistance, low cost, stable process and the like.

An aqueous precipitation process for the preparation of particles comprising primarily silver sulfate, comprising reacting an aqueous soluble silver salt and an aqueous soluble source of inorganic sulfate ion in an agitated precipitation reactor vessel and precipitating particles comprising primarily silver sulfate, wherein the reaction and precipitation are performed in the presence of an aqueous soluble organo-sulfate or organo-sulfonate additive compound, the amount of additive being a minor molar percentage, relative to the molar amount of silver sulfate precipitated, and effective to result in precipitation of particles comprising primarily silver sulfate having a mean grain size of less than 50 micrometers.

A carbonaceous material that has been loaded with at least one ionic organic species or hydroxide species and at least one metal or alkaline earth metal. The ionic organic species or hydroxide species is at least one selected from the group consisting-of: fatty acids, surfactants, organic carboxyl species, organic sulfonate species, organic hydroxyl species, organic phenolic species, organic lactone species, organic amine species, or hydroxide species.

The invention discloses tin stripping and tin plating liquid, a preparing method of the tin stripping and tin plating liquid and a method for adopting the tin stripping and tin plating liquid for recycling metal tin from tin-containing waste. The tin stripping and tin plating liquid includes various effective components such as organic sulfonic acid tin salt, alkanol group sulfoacid, a stabilizing agent, an accelerating agent, an accelerator, a brightening agent, a grain fining agent, antioxidant and a foaming agent, and all the components are in synergy. The defect of traditionally recycling tin from tin stripping waste liquid is overcome, interference of other metal impurities is avoided, and high-purity metal tin can be efficiently recycled from the waste liquid. In addition, the operation steps for adopting the tin stripping and tin plating liquid for recycling the metal tin from the tin-containing waste are simple and convenient and fast to implement, the high-quality metal tin can be recycled, furthermore, the tin stripping liquid can be regenerated at the same time to be repeatedly utilized, and the problems that traditional tin stripping waste liquid is large in amount, resources are wasted, and the environment is seriously polluted are solved.

An electrolytic membrane comprising a porous membrane substrate containing a cross-linked polymer electrolyte having at least a structural component shown by following chemical formula 1: wherein A represents a repeating unit having an aromatic hydrocarbon group substituted by at least a sulfonic acid group, B represents a repeating unit having one of a nitrogen-containing hetero ring compound residue, and the sulfate, hydrochloride or organic sulfonate thereof, C represents a repeating unit having a cross-linked group, and X, Y and Z represent mol fractions of respective repeating units in the chemical formula 1, with 0.34≦X≦0.985, 0.005≦Y≦0.49, 0.01≦Z≦0.495 and Y≦X and Z≦X, provided that, in the repeating unit A, a ratio of the aromatic hydrocarbon group substituted by at least a sulfonic acid group is 0.3 to 1.0, and the number of the sulfonic acid group in the aromatic hydrocarbon group is 1 to 3.

Provided are a polycarbonate-based resin composition that brings together an excellent impact strength and excellent flame retardancy and a molded article thereof. The polycarbonate-based resin composition is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of (A-1) a polycarbonate-polyorganosiloxane copolymer which has a constituent unit represented by a general formula (I) and a constituent unit represented by a general formula (II), and in which an average number of repetitions of the constituent unit represented by the general formula (II) is 30 to 500, and 70 to 0 mass % of (A-2) an aromatic polycarbonate resin except the polycarbonate-polyorganosiloxane copolymer, 0.01 to 0.15 part by mass of (B) an alkali metal salt and / or alkaline earth metal salt of an organosulfonic acid, and 0.1 to 1 part by mass of (C) a mixed powder formed of polytetrafluoroethylene particles and organic polymer particles, in which: a content of a polyorganosiloxane block moiety formed of the constituent unit represented by the general formula (II) in the resin mixture (A) is 2 to 30 mass %; and the composition is free of an organohalogen-based flame retardant and an organophosphate-based flame retardant.

The invention discloses preparation methods of an oxidized graphene / polyaniline / titanium dioxide nanocomposite and polyaniline nanometer anticorrosive paint. The preparation method of the nanocomposite comprises the steps that 1, a sodium hydroxide solution or a hartshorn is adopted as a dispersing agent, and ultrasonic exfoliation is performed on oxidized graphite to obtain oxidized graphene; 2, the oxidized graphene is added into an aniline organic sulfonic acid solution, and stirring is performed for 10-16 h to obtain an oxidized graphene / polyaniline nanocomposite; 3, nanometer titania is added into the organic sulfonic acid solution of the oxidized graphene / polyaniline nanocomposite obtained in the step 2, stirring is performed for 10-16 h, and centrifuging, washing and drying are performed in sequence to obtain the oxidized graphene / polyaniline / titanium dioxide nanocomposite. The raw materials are cheap and easy to obtain, the technology is simple and easy to control, and the obtained polyaniline nanometer anticorrosive paint is excellent in anticorrosive performance and environmentally friendly.

The present invention is a composition for removal of multi-layer photoresist layers on an electronic device substrate for rework of the photoresist on the substrate, comprising; (i) a solvent blend of at least three discrete solvents, (ii) at least one organic sulfonic acid, and (iii) at least one corrosion inhibitor. The present invention is also a method for using the composition. This composition and method succeed in removing such multi-layer photoresist at temperatures less than 65° C. and in contact times under three minutes, allowing high throughput on single wafer tools.

The conductive polymer of the present invention is prepared by means of oxidation polymerization. On the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is coated. Alternatively, in the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is included. The conductive polymer of the present invention is excellent in the conductivity, heat resistance and moisture resistance. By using it as a solid electrolyte, a reliable solid electrolytic capacitor can be prepared which is unlikely to decrease the properties when being kept in a hot and humid condition.

[Object] To provide a polycarbonate resin composition that is thin but has high flame retardancy and surface hardness for which a hard coating layer is not required, causes less gas generation in molding, has excellent heat resistance, preservation stability, and recyclability, and does not contain bromine and phosphate flame retardants, and to provide a molded product thereof.[Solving Means] A polycarbonate resin composition includes, as a main resin material, an aromatic polycarbonate resin occupying 85 to 95 mass % of the main resin material and having a weight-average molecular weight of 37000 to 55000 in polystyrene equivalent molecular weight, and a polystyrene resin occupying 15 to 5 mass % of the main resin material and containing no rubber component. A resin component other than the above may be contained resulting from recycled materials as long as the characteristics of the resin composition are not impaired. A polyfluoroolefin resin, an organic sulfonate flame retardant, and a silicon flame retardant are added to the resin material. The aromatic polycarbonate resin composition is molded into a predetermined shape.

A corrosion inhibitor composition and method of inhibiting corrosion on a surface in an oil or gas application is disclosed and claimed. The corrosion inhibitor includes at least one fatty acid; at least one alkanolamine; at least one alkylamine; and at least one organic sulfonic acid. The method of inhibiting corrosion includes on a surface in an oil or gas application comprises contacting an effective dosage of the corrosion inhibitor with the surface.

The present invention provides a composition for photoresist stripping solution which shows a superior stripping property of photoresists and damaged photoresist layers remained after dry etching in the fabrication process of semiconductor circuit devices, without attacking new wiring materials and interlayer insulating film materials, as well as a process of stripping of photoresists and damaged photoresist layers. The composition for photoresist stripping solution which contains at least one of acetylene alcohol compounds and organic sulfonic acid compounds, and at least one of polyvalent alcohols and their derivatives is used.

A composition containing titanic oxide grain encapsulated by pyrolytic monox and its productionby organic additive treatment are disclosed. The material consists of organic silane, organic siloxane, fluoro-silane, organic phosphate, organic acid phosphate, organic pyrophosphate, organic poly-phosphate, organic metaphosphate, organic hypophosphite, organic sulfonic acid compound, sulfcarboxylic acid, hydrocarbyl carboxylic acid ester, hydrocarbyl carboxylic acid derivatives, hydrocarbyl amide, low-molecular-weight hydrocarbon wax, low-molecular-weight polyolefine, low-molecular-weight polyolefine multi-polymer, hydrocarbyl polyol, hydrocarbyl polyol derivative, alkanolamine, alkanolamine derivative, organic dispersant or their mixtures.

A transparent and flame-retardant aromatic polycarbonate resin composite is provided. A transparent and flame-retardant aromatic polycarbonate resin composite includes (A) 100 parts by mass of a transparent aromatic polycarbonate resin composed of 99 percent by mass to 50 percent by mass of an aromatic polycarbonate resin-A with a viscosity-average molecular weight (Mv) of 3×103 to 2.5×104, and 1 percent by mass to 50 percent by mass of an aromatic polycarbonate resin-B with a viscosity-average molecular weight (Mv) of 5×104 to 9×104, and, (B) 5×10−3 parts by mass to 9×10−2 parts by mass of a flame retardant composed of an alkali metal salt of an organic sulfonic acid, wherein a Q-value is 0.1 cm3 / sec or smaller, a test piece for UL testing of 2.0 mm thickness molded using the aromatic polycarbonate resin composite satisfies UL94V-0, and, a molded article of 3.0 mm thickness shows a haze value of 2% or smaller.

A process for the preparation of high surface area, low-swelling macroporous polymeric adsorbents is disclosed. The use of organic sulfonic acids to provide postcrosslinking of macroporous copolymers eliminates the need for traditional organic swelling solvents and Lewis-acid catalysts used to provide conventional macronetted polymers. In particular, methanesulfonic acid provides macroporous polymeric adsorbents having high surface area and porosity, low levels of residual vinyl groups, and free of residual contaminants from conventional Lewis-acid / Friedel-Crafts reactions.

A flame retardant aromatic polycarbonate resin composition comprising 100 parts by weight of an aromatic polycarbonate (A), 0.01 to 0.5 part by weight of branched metal oxide particles (branched metal oxide aggregates and / or branched metal oxide agglomerates) (B), 0.0001 to 0.2 part by weight of an alkali metal salt (C) of an organic sulfonic acid, and 0.01 to 0.5 part by weight of a fluoropolymer (D), the branched metal oxide particles (B) being dispersed in a mixture of components (A), (C) and (D), wherein at least 70% of the branched metal oxide particles (B) have a diameter within the range of from 10 to 200 nm.

A tin / copper alloy electroplating solution capable of forming a bright plating film in a wide electric current density range is provided. The electroplating solution is a cyanide-free aqueous solution containing an organosulfonic acid, divalent tin and copper salts, as metal salts, of the organosulfonic acid, a dispersant, and a brightener.

The invention belongs to the technical fields of organic chemistry and catalytic chemistry, and relates to an organic acid-base catalyst which is used for carboxylic acid aryl-ester groups which are compounded by ester exchanges. The organic base in the organic acid-base catalyst refers to an organic compound which contains nitrogen, phosphorus and halogen elements and solid-carrying organic base of the organic base, while the organic acid mainly refers to organic sulfonic acid, organic phosphorus acid, organic carboxyl acid, urea and the like and solid-carrying organic acid of the organic acid. The invention can be used as organic matters such as amino acid and the like which has double functions of organic acid and base and as catalysts which can be used to solid support the organic acid base on a same carrier. The catalyst of the invention has good catalytic performance and is easy to be separated from reaction systems, ester exchange conditions are temperate, the invention is convenient to continue, the conversion rate of oxalic dim-ethyl ester can reach over 90%, the selectivity to phenyloxalate can reach over 70%, and the invention is suitable for industry applications.

A toner including: a binder resin; and a colorant, wherein the toner is obtained by dispersing or emulsifying an oil phase in an aqueous solvent containing an organic sulfonic acid salt and an inorganic salt, the oil phase including the binder resin and the colorant dissolved or dispersed in an organic solvent, wherein the binder resin comprises a crystalline resin in an amount of 50% by mass or more relative to the binder resin, and wherein the toner has an average circularity of 0.980 or less.

The present invention provides a process for the preparation of highly pure 2-acrylamido-2-methyl-1-propanesulfonic acid in high yield, with improved appearance, by the reaction of acrylonitrile with more than 98% sulfuric acid or oleum and liquefied isobutylene in presence of weak inorganic acids or organic sulfonic acids.

Disclosed are: a polycarbonate resin composition having excellent flame retardancy, excellent impact resistance and excellent surface appearance; and a molded article produced by molding the composition. The composition comprises 100 parts by mass of a polycarbonate resin (A), 0.001 to 2 parts by mass of an organic sulfonic acid metal salt (B), 0.001 to 1 part by mass of a fluoropolymer (C), 0.5 to 5 parts by mass of polyalkylsilsesquioxane particles (D) having an average particle diameter of 0.6 to 5 [mu]m, and 0.5 to 8 parts by mass of a graft copolymer (E) having a butadiene content of 50 to 95%.