The invention belongs to the technical field of treatment of
high concentration organic waste water, and particularly relates to a method for degrading
nitrobenzene waste water by a polyphase electrocatalytic
oxidation process. The invention solves the problems of high cost and long time consumption in the traditional
nitrobenzene waste water methods, low efficiency and
high energy consumption in the
electrolytic process, high oxidant consumption, high cost and the like in the Fenton process in the prior art for treating
high concentration nitrobenzene water waste. The invention mainly adopts the
catalytic oxidation action of
transition metal catalysts in the
electric field, and combines the Fenton process, thereby effectively degrading the
high concentration nitrobenzene waste water. The method comprises the following steps that: (1) heterocatalytic reagents (
solid catalysts) and particle electrodes, mainly including
active carbon, and
transition metal oxides and salts, are used for avoiding economic loss and secondary
pollution to the environment, which are caused by catalyst loss in heterocatalytic oxidation; (2) under the condition of low pH value of the waste water in cooperation with Fe2+ with strong reducibility, a
coupling reactor composed of an
electrolysis field and oxidation reaction is used for generating
chain reaction for generating an OH hydroxyl free radical, and the OH hydroxyl free radical can carrying out nonselective oxidization on organic substances, thereby finally oxidizing organic pollutants into
carbon dioxide and water; (3) by using
electric energy as an excitation energy and using cheap air as
raw material, nitrobenzene substances in waste water are efficiently degraded under the
coupling action of the polyphase electrocatalytic
oxidation process and the Fenton process; (4) and the reactor is composed of a
direct current regulated power supply, a feed
electrode and an electrolytic bath.