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Process for producing nano graphene reinforced composite particles for lithium battery electrodes

A process for producing solid nanocomposite particles for lithium metal or lithium ion battery electrode applications is provided. In one preferred embodiment, the process comprises: (A) Preparing an electrode active material in a form of fine particles, rods, wires, fibers, or tubes with a dimension smaller than 1 μm; (B) Preparing separated or isolated nano graphene platelets with a thickness less than 50 nm; (C) Dispersing the nano graphene platelets and the electrode active material in a precursor fluid medium to form a suspension wherein the fluid medium contains a precursor matrix material dispersed or dissolved therein; and (D) Converting the suspension to the solid nanocomposite particles, wherein the precursor matrix material is converted into a protective matrix material reinforced by the nano graphene platelets and the electrode active material is substantially dispersed in the protective matrix material. For a lithium ion battery anode application, the matrix material is preferably amorphous carbon, polymeric carbon, or meso-phase carbon. Such solid nanocomposite particles provide a high anode capacity and good cycling stability. For a cathode application, the resulting lithium metal or lithium ion battery exhibits an exceptionally high cycle life.
Owner:SAMSUNG ELECTRONICS CO LTD

Polymer-wrapped single wall carbon nanotubes

The present invention relates to new compositions of matter and articles of manufacture comprising SWNTs as nanometer scale conducting rods dispersed in an electrically-insulating matrix. These compositions of matter have novel and useful electrical, mechanical, and chemical properties including applications in antennas, electromagnetic and electro-optic devices, and high-toughness materials. Other compositions of matter and articles of manufacture are disclosed, including polymer-coated and polymer wrapped single-wall nanotubes (SWNTs), small ropes of polymer-coated and polymer-wrapped SWNTs and materials comprising same. This composition provides one embodiment of the SWNT conducting-rod composite mentioned above, and also enables creation of high-concentration suspensions of SWNTs and compatibilization of SWNTs with polymeric matrices in composite materials. This solubilization and compatibilization, in turn, enables chemical manipulation of SWNT and production of composite fibers, films, and solids comprising SWNTs.
Owner:RICE UNIV

Preparation method of high-strength hydrogel

InactiveCN103739861AThe preparation process takes a short timeReduce energy consumptionPolymer chemistryDouble network
The invention relates to a high-strength hydrogel and a preparation method thereof. The preparation method comprises the steps of directly mixing a polymer, a monomer, an initiator, a cross-linking agent and water once, dissolving all the substances to form a homogeneous solution under a certain simulation condition, and then initiating and polymerizing by using heat or light to obtain the high-strength hydrogel, wherein the polymer is needed for preparation of the hydrogel and used for forming a first double network of a dual-network hydrogel; the monomer is used for polymerizing and forming a second double network of the dual-network hydrogel; the initiator is used for initiating the monomer to be polymerized; the cross-linking agent is used for performing cross-linking reaction in a monomer polymerizing process so as to form the second double network. According to the preparation method, a one-pot method is used for preparing the high-strength hydrogel, so that the method is simple and practicable; the prepared high-strength hydrogel has the characteristics of high strength and high toughness; a tensile strength of the gel is 0.6-1.2MPa, a tensile modulus is 100-200 KPa and a tensile strain reaches 1000-2680%; the prepared high-strength hydrogel can be widely applied to the fields of tissue repair, artificial organ, drug sustained release, sensors and the like.
Owner:HENAN POLYTECHNIC UNIV
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