The invention relates to a method for preparing nanometer hollow bar-shaped
silicon dioxide materials by using nanometer
crystal cellulose as templates. According to the method, the
cellulose and the tetraethoxysilane are adopted as raw materials. Firstly, the
cellulose raw materials are hydrolyzed by
sulfuric acid with the weight concentration being 64 percent to obtain nanometer
crystal cellulose with negative charges on the surface, then, cetyl trimethyl
ammonium bromide is used so that the charges on the surface of the cellulose nanometer crystals are changed into positive charges, then,
sol obtained through tetraethoxysilane
hydrolysis is absorbed onto the surface of the cellulose nanometer crystals under the alkaline condition, and finally,
silicon dioxide gel is formed through condensation
polymerization, so the nanometer
crystal cellulose compounds covered by the
silicon dioxide is obtained through the preparation. After the compounds are subjected to freezing
drying,
powder is obtained, the
powder is roasted in a
Muffle furnace to remove the cellulose
nucleus, and the nanometer hollow bar-shaped
silicon dioxide materials are obtained. The cellulose nanometer crystals adopted by the method are used as the templates, raw materials are rich, the preparation is simple, in addition, the dimension and the shape of the templates can be regulated and controlled through the
hydrolysis time and the intensity, the hollow bar-shaped
silicon dioxide materials with the inner
diameter being dozens of nanometers can be prepared, in addition, the whole experiment process is safe, and the obtained products are uniform.