1647 results about "Persulfate" patented technology

Application of spinel ferrite catalyst and a method for urging persulfate to generate free radicals to catalytically degrade organic matters relate to application of spinel ferrite catalyst and a method for degrading organic matters. The invention aims to solve the problems of high probabilities of oxygenolysis and breakage, low strength, impurity dissolution, low catalytic efficiency and difficulty in recovering in the existing catalyst as catalyst generated by sulfate free radicals and complex reaction system, rigor reaction conditions and higher cost in the existing activating technology. The spinel ferrite catalyst, as catalyst for urging the generation of persulfate free radicals, for urging persulfate or mono-persulfate to generate free radicals is applied; and the method comprises the following steps: the spinel ferrite catalyst is adopted as catalyst for urging the generation of persulfate free radicals to urge persulfate or mono-persulfate to generate free radicals; and then sulfuric acid free radicals are used for degrading the organic matters. The application and the method are mainly applied in catalytic degradation of the organic matters.

The invention discloses an acrylamide modified graft copolymer and a preparation method and usage thereof. The invention is characterized in that 20 parts of acrylamide, 1-20 anionic monomer and/or cationic monomer, 0.1-15 macromonomer, 0.05-10 ionic lyophobic monomer and 50-1000 deionized water are added into a three-necked reaction bottle, the pH value is adjusted to be 3-9, N2 is introduced for 30min, then 0.002-0.5 part of initiator persulfate is added at 30-75 DEG C, the reaction lasts 8-36h, then copolymer PAB is obtained, and finally water is used for dilution to obtain strong PAB solution. During polymerization, no surfactant is used, and the macromonomer with a long chain and the ionic lyophobic monomer with intermolecular association function are introduced into the copolymer PAB, so the capabilities of cooperative tackification and salt-resistance between the rigid conformation of a molecular chain and the intermolecular association can be played optimally, the PAB exhibits unique solution property and has higher colloidal viscosity in high saline solution than in fresh water, and the PAB obtains the capabilities of tackification, salt resistance, low surface tension and strong molecular association and can be used for the oil-displacing acrylamide modified graft copolymer. The copolymer is prepared into water solution with mass concentration of 0.2-3.0g/L and surfactant concentration of 0.01-2 mmol/L, then the water solution is added into a mixing vessel by a stirring device, and then a polymer oil-displacing agent with tackification, salt resistance and cutting resistance is obtained. The PAB has the functions of both a tackifier and a macromolecule surfactant. The copolymer PAB is prepared into water solution which has mass concentration of 0.05-7%, so the macromolecule surfactant with excellent surface activeness can be obtained and then applicable to an emulsifier, an emulsion splitter, a solubilizer and a wetting agent.

The invention relates to a synthesis and surface modification method of a lithium rich anode material Li1+xM1-xO2 (M is one or more of Ni, Co and Mn, and X is more than or equal to 0 and less than or equal to 1/3) for a lithium ion battery. The method comprises the following steps of: synthesizing a precursor by using a carbonate precipitation method, mixing the precursor and a lithium salt, and calcining for 2 to 20 hours at the temperature of between 800 and 1,100 EG C to obtain a lithium rich material, wherein the prepared lithium rich material has controllable particle size and higher reversible capacity; and dissolving persulfate or sulfate in an amount which is 5 to 80 mass percent of the lithium rich material into deionized water, adding the lithium rich material, stirring for 2 to 100 hours at the temperature of between 25 and 80 DEG C, heating the materials to the temperature of between 100 and 500 DEG C in a muffle furnace, calcining the materials for 2 to 20 hours, fully filtering the obtained materials, and washing off impurities to obtain the surface modified anode material Li1+x-yM1-xO2. The synthesized lithium rich material has controllable particle size; the first charge/discharge efficiency of the lithium rich material and the discharge specific capacity and the cyclical stability under high magnification can be improved; and the method is simple, low in cost, convenient for operation and suitable for industrialized production.

The invention relates to a method for combined restoration of organic-contaminated soil, comprising the following steps: (1) adding an aqueous solution of a surfactant to the organic-contaminated soil for solubilization treatment; (2) adding persulfate and an activator, Reaction, after the reaction is completed, separate and dry to obtain the repaired organic matter-contaminated soil. Compared with the prior art, the invention has the advantages of high removal rate of adsorbed organic pollutants, low cost, simple and easy method, and environmental friendliness.

The invention discloses a method for selectively recycling lithium from lithium iron phosphate waste through a direct oxidization method. The method is characterized by comprising the steps that the lithium iron phosphate waste is added into a water solution, meanwhile, an oxidizing agent is added, stirring is carried out, lithium iron phosphate and the oxidizing agent react to generate iron phosphate, lithium ions enter the solution, and therefore a pure lithium-containing solution and iron phosphate solids are obtained. The adopted oxidizing agent comprises one or a mixture of persulfate, ozone, oxygen, pypocholoride and hydrogen peroxide. The molar weight of the oxidizing agent is 0.6-20 times that of lithium iron phosphate. The lithium-containing solution can be directly used for preparing a high-purity lithium product. According to the method, efficient and selective leaching of lithium can be achieved simply by adding a certain amount of oxidizing agent, and the method is mild in reaction condition, short in process and simple in equipment.

This invention discloses a high-density ball ferric phosphate lithium and manganous phosphate iron lithium process method used in lithium ion battery positive electrode material in energy material process technique field. The process method comprises the following steps: to use ferric persulfate, phosphor or complex builder or manganese sulfate to process the mixture liquid; to react with the hartshorn solution to generate ball ferrous phosphate ammonium or manganese phosphate ferrous front driver; to mix it with lithium carbonate with mole proportion of one to one after washing and drying; under protection of nitrogen gas and after 600 to 900 degrees for 8 to 48 hours to get the ferric phosphate lithium or manganese phosphate ferrous.

The invention belongs to the field of chemical materials, and particularly relates to a FeS and Fe0 composite and a preparation method and application thereof. The FeS and Fe0 composite is formed by compositing nano FeS and nano Fe0, the surface of the nano Fe0 is coated with the nano FeS, and the molar ratio of the nano FeS to the nano Fe0 is 2:1 to 15:1. According to the FeS and Fe0 composite and the preparation method and application thereof, the preparation process is simple, convenient, environmentally friendly and feasible, the prepared FeS and Fe0 composite is high in reaction activity, capable of efficiently and rapidly reducing and adsorbing heavy metal ions in waste water within a wider temperature range, a pH value range and a dissolved oxygen content range and further capable of rapidly and efficiently activating hydrogen peroxide and persulfate to make a system generate hydroxyl free radicals and sulfate free radicals to degrade and mineralize organic pollutants, and therefore the FeS and Fe0 composite can be widely applied to degradation of the organic pollutants in surface water and underground water.

The invention provides an electric complex-strengthening repairing method and device of heavy metal-organic co-contaminated soil. The method provided by the invention comprises the following steps of: filling contaminated soil into an electric repairing device, and then adding an oxidant into a cathode electrolyte and an anode electrolyte or directly spraying the oxidant on the contaminated soil, wherein the oxidant comprises hydrogen peroxide, pypocholoride and persulfate; applying a direct-current electric field on a cathode and an anode, wherein the strength of the electric field is 0.5-2 V/cm; and controlling the pH values of the cathode electrolyte and the anode electrolyte to be 3-11. By selecting the suitable for oxidant and controlling the pH value of the electrolyte, the migration of the heavy metal can be effectively increased and the removing efficiency is improved; and meanwhile, the oxidant is used for effectively degrading organic pollutants when the pollutants are migrated, thereby relieving the post-treatment and simultaneously removing the heavy metal and the organic pollutants.

A process for synthesizing the phase-change energy-accumulating microcapsules by emulsion polymerizing method features that the liposoluble organic phase-change material, vinyl or bivinyl monomers, water, non-ionic or anionic surfactant and the persulfate, percarbonate, perborate, hydrogen peroxide, or their redox pair take part is core-shell polymerizing reaction in emulsion to obtain said microcapsules.

The invention discloses a transforming solution for preparing anti-corrosion compound oxidation film on an aluminum alloy surface and a using method for the oxidation film. The invention is characterized in that, the transforming solution is a film-forming promoter containing rare-earth salt (nitrate or sulfate and compound salt of cerium, praseodymium, and neodymium), such compound oxidant as radical of permanganate, nitrate and perchlorate, etc., film-forming promoter of vanadium salt and strontium salt, etc.; the transforming solution contains no sexavalent chromium, is environmental friendly; the reaction speed is improved by the compound oxidant and the film-forming promoter, no heating is needed for the chemical transforming, the treating time is 1-5 min. The invention can rapidly prepare under room temperature compound oxidation film comprising compound rare-earth oxide, alumina and manganese oxide with good resistance to corrosion on aluminum alloy surface. The treating solution from the invention is of rapid film-forming speed, simple process, even film layer, high resistance to corrosion, and low environmental pollution, etc.

The present exemplary embodiment provides a conductive polymer having high conductivity and a method for producing the same, and a conductive polymer dispersion, and further provides a solid electrolytic capacitor having low ESR and a method for producing the same. A conductive polymer is produced by a method including the steps of dissolving a sulfonic acid group-containing resin having a weight average molecular weight of 2,000 or more and 50,000 or less and a compound represented by the following formula (1) in a solvent; mixing at least one monomer selected from pyrrole, thiophene, and derivatives thereof in an obtained solution; subjecting the monomer to chemical oxidative polymerization, using a persulfate, to obtain a conductive polymer; and washing the conductive polymer to remove the compound represented by the formula (1) contained in the conductive polymer.

C_nH_n+2(OH)_n  (1)

wherein n represents an integer of 3 to 6.

The invention relates to an inverse emulsion polymer thickener for a fracturing fluid and a preparation method thereof. The thickener is polymerized by water, 2-acrylamidyl-2-methyl sodium proparesulfonic acid liquid with mass fraction of 50%, alkyl acrylamide, acrylamide, a cationic monomer, N, N-methylene bisacrylamide, a tween-80 emulsifier, ethylene diamine tetraacetic acid disodium salt, 30% sodium hydroxide, white oil, acrylic ester, a span-80 emulsifier, sulfite, a peroxysulphate initiator, a water-soluble azo initiator and OP-15. According to the invention, raw materials are industrial products, and purification is not needed before reaction; polymerization is initiated by initiators by adding a complexing agent, and the preparation process is simple; the thickener provided by the invention is fast in dispersing, easy to prepare, free from pollution and harm, small in use level and good in stability, in particular resists high temperature of 220 DEG C, and is suitable for fracturing a high-temperature stratum; and the thickener is higher in shear resistance, can meet the fracturing construction of high flow, has high sand carrying performance, and is free from residue and is not harmful to the reservoir.

The invention relates to a technology for removing and controlling arsenic which has very high toxicity in water, and discloses a water treatment method for removing arsenic by strengthening zero-valent iron, which can be used for groundwater repair, drinking water treatment, industrial arsenic-containing wastewater treatment, sewage deep treatment and integrated small-scale water treatment systems. The water treatment method specifically comprises the following steps of: adding persulfate and zero-valent iron into water containing arsenic, wherein the persulfate is added in a molar ratio of the persulfate to arsenic of (5:1)-(100:1), and the molar ratio of the zero-valent iron to the persulfate in the water is (1:1)-(10:1); and when the mixed solution is fully mixed, filtering or depositing to finish the removal of arsenic. The water treatment method is very simple to operate, easy to popularize and apply and safe to use, and can be used for ensuring the water quality safety.

The invention discloses a method for degrading organic substances or ammonia nitrogen by catalyzing persulfate through sludge biochar. The method includes the following steps that firstly, sludge is dried to obtain dried sludge, then the dried sludge is subjected to pyrolysis treatment for at least 2 h in the ammonia environment at 300-500 DEG C, and then sludge biochar is obtained after cooling; secondly, the sludge biochar and persulfate are put into sewage to degrade the organic substances or ammonia nitrogen in the sewage. By improving key preparation conditions of sludge biochar and increasing the application ratio of the sludge biochar and persulfate, under the catalytic function of the sludge biochar, persulfate can efficiently degrade the organic substances and ammonia nitrogen in sewage on the basis of catalysis and oxidization of sulfate free radicals, the problem of organic pollutant and the ammonia nitrogen pollution problem in sewage are effectively solved, and the degradation effect is good.

The invention discloses a preparation method of a back lining material used as the back lining of carpets, more particularly relates to a preparation method of the carpets and carboxylic styrene butadiene latex. Butadiene and cinnamene are taken as main monomers, then functional monomers and auxiliary monomers are added, anion emulsifier and non-ionic emulsifier are used complexly, pyrolysis type persulfates of potassium peroxydisulfate water solution or ammonium persulfate water solution, etc. are used as activator, n-dodecylmercaptan is used as molecular weight regulator, a batch feeding or dropwise feeding way is adopted, and vacuum flashing desaeration is used for composing the environment protection carboxylic styrene butadiene latex used as the backing lining of carpets. The carboxylic styrene butadiene latex prepared by the method has good elasticity and enduring performance, high adhesion strength and low volatility harmful substances after being used in woven carpets and tufted carpets, thereby being a green environment protection product upon meeting the requirements of environment protection.