2717 results about "Silver particles" patented technology

A process for producing a fine silver particle colloidal dispersion which can simply form conductive silver layers and antimicrobial coatings by screen printing or the like. The process is characterized by having a reaction step of allowing an aqueous silver nitrate solution to react with a mixed solution of an aqueous iron(II) sulfate solution and an aqueous sodium citrate solution to form an agglomerate of fine silver particles, a filtration step of filtering the resultant agglomerate of fine silver particles to obtain a cake of the agglomerate of fine silver particles, a dispersion step of adding pure water to the cake to obtain a first fine silver particle colloidal dispersion of a water system in which dispersion the fine silver particles have been dispersed in the pure water, and a concentration and washing step of concentrating and washing the first fine silver particle colloidal dispersion of a water system.

Disclosed is a paste for a back contact-type solar cell that includes: (a) electrically conductive particles containing silver particle and added particles selected from the group consisting of (i) metal particles selected from the group consisting of Mo, Tc, Ru, Rh, Pd, W, Re, Os, Ir and Pt particles, (ii) a metal alloy containing the metal particles, and (iii) particles loaded with the metal particles, (b) glass frit, and (c) a resin binder.

The present invention discloses the preparation process of nanometer silver solution and nanometer silver powder with polymer as stabilizer. Water soluble polymer as stabilizer in solution of 0.001-0.05 g / ml solution and silver nitrate in solution of 0.001-0.1 mol / L are compounded and reduced with water soluble reductant in solution of 0.001-0.2 mol / L to obtain nanometer silver particle of 5-100 nm size. The nanometer silver particle in solution may be further deposited and washed with sodium hydroxide solution, dried and crushed to obtain nanometer silver particle of 5-100 nm size. The prepared solution may be used in medical article, and prepared nanometer silver powder may be used widely in household appliance, plastic product, paint, etc. The present invention is environment friendly, low in cost and simple in operation, and the prepared nanometer silver particle has extremely powerful antibiotic capacity and wide antibiotic spectrum.

The invention is related to compositions which can be used as dermal formulations for supporting the skin to restore normal conditions in case of e.g. irritated skin, or to support medical therapy of skin with atopic dermatitis symptoms, atopic dermatitis, psoriasis or related diseases (e.g. accompanied by distorted barrier function of the skin and microbial load). The compositions of the invention can be used for dermo-cosmetic products but also for pharmaceutical / -medical products, depending on the composition and the additional actives incorporated (cosmetic actives or drugs). The invention is based on the synergistic effect of metallic particles, in particular silver particles (such as microsilver, nanosilver) and lipid particles (lipid nanoparticles or lipid microparticles). As alternatives to silver particles, other metallic particles (e.g. zinc, copper) or nanocrystalline actives can be incorporated (e.g. replacing the anti-oxidative silver by anti-oxidative nanocrystals of plant molecules such as hesperitin). This leads to combinations of lipid particles with nanocrystals for dermal use.

We disclose a colorless composition comprising silver particles and water, wherein said particles comprise an interior of elemental silver and an exterior of ionic silver oxide, wherein the silver particles are present in the water at a level of about 5-40 ppm, and wherein the composition manifests significant antimicrobial properties. Methods of use of the composition are described. The composition can be incorporated into a hydrogel with essentially no loss of antimicrobial properties.

It is to provide a process for preparing a conductive material in which transparency and conductivity are both high, and storage stability is high, and further, in a process for preparing a conductive material utilizing ultra fine silver particles, to provide a process for preparing a conductive material having high conductivity without requiring a calcination step which has conventionally been required.A process for preparing a conductive material having a conductive pattern containing silver on a support, which process for preparing a conductive material comprises acting at least one of the following mentioned (I) to (IV) on the pattern portion containing silver provided on the support:(I) a reducing substance,(II) a water-soluble phosphorus oxo acid compound,(III) a water-soluble halogen compound,(IV) warm water of 55° C. or higher.

A conductive paste for grid electrodes in solar cells includes a conductive component, glass frit, and resin binder, wherein the conductive component is selected from the group consisting of (i) silver particles and metal particles selected from the group consisting of Pd, Ir, Pt, Ru, Ti, and Co, (ii) alloy particles comprising silver and metal selected from the group consisting of Pd, Ir, Pt, Ru, Ti, and Co, and (iii) silver particles and core-shell particles in which a metal selected from the group consisting of Pd, Ir, Pt, Ru, Ti, and Co is coated on the surface of silver or copper.

Provided are silver-containing powders and a method and apparatus for manufacturing the silver-containing particles of high quality, of a small size and narrow size distribution. An aerosol is generated from liquid feed and sent to a furnace, where liquid in droplets in the aerosol is vaporized to permit formation of the desired particles, which are then collected in a particle collector. The aerosol generation involves preparation of a high quality aerosol, with a narrow droplet size distribution, with close control over droplet size and with a high droplet loading suitable for commercial applications.

The invention discloses a cellulose fiber-supported nano silver antibacterial material and a preparation method thereof. The preparation method comprises the steps of: conducting chemical pretreatment on cellulose fibers, then conducting TEMPO (2, 2, 6, 6-tetramethylpiperidine-1-oxyl) selective oxidization on the cellulose fibers, and finally on the premise that not any reducing agent is added, enabling the oxidized cellulose fibers to react with silver nitrate in silver nitrate water solution through a short-time microwave heating method to prepare the cellulose fiber-supported nano silver antibacterial material with small-diameter and even-structure nano silver particles. By adopting the preparation method, on the premise that not any reducing agent is added, in-situ reduction and growth of nano silver on carboxylated cellulose fiber supporters are realized. The prepared cellulose fiber-supported nano silver antibacterial material has the advantages of small nano grain size and even size, and can be widely applied to the fields of antibacterial operation clothes, wound dressing, drug controlled release, textile coating and the like.

A dental implant assembly is disclosed. The dental implant assembly comprises an implant. The dental implant assembly further comprises an abutment coupled to a top portion of the implant. The dental implant assembly further comprises a screw for securing the abutment to the implant. The dental implant assembly further comprises silver nanoparticles positioned on at least one interior surface of at least one of the implant and the abutment.

The invention provides a preparation for the in-situ compounding simple-substance nano silvery bacteria cellulose membrane, and relates to the biological medical material field, characterized in that the bacteria cellulose membrane has special three-dimensional nano network structure, the silver-ammonia solution reacts with the chemical agent containing aldehyde group to generate silver simple-substance nano particle in situ in the network structure. In addition, in the invention, the special drying method is adopted to improve the defect of big fragility of the prepared silver-contained nano bacteria cellulose dry membrane. The bacteria cellulose membrane containing simple-substance nano silver particle provided by the invention has excellent antibacterial performance and simple preparation technique, and can be widely used in the biological medical field such as large-area wound dressing, bundling belt and the like, also can be used in the industry field such as the preparation of nano silver particle and silver catalyst, and the like.

A thermal interface material (40) includes a silver colloid base (32), and an array of carbon nanotubes (22) disposed in the silver colloid base uniformly. The silver colloid base includes silver particles, boron nitride particles and polysynthetic oils. The silver colloid base has a first surface (42), and a second surface (44) opposite to the first surface. The carbon nanotubes are substantially parallel to each other, and extend from the first surface to the second surface. A method for manufacturing the thermal interface material includes the steps of: (a) forming an array of carbon nanotubes on a substrate; (b) immersing the carbon nanotubes in a silver colloid base; (c) solidifying the silver colloid base; and (d) peeling the solidified silver colloid base with the carbon nanotubes secured therein off from the substrate.

The present invention provides a bonding material and a method of bonding for metal bonding at a bonding interface capable of a higher bonding strength at a lower temperature without application of pressure, compared to a bonding material of metal particles having an average particle size of not greater than 100 nm. An electrically conductive bonding material including (A) silver particles, (B) silver oxide, and (C) a dispersant including organic material containing not more than 30 carbon atoms as essential components, wherein a total amount of (A) the silver powder, (B) the silver oxide powder, and (C) the dispersant including an organic material containing not more than 30 carbon atoms is in a range of 99.0% to 100% by weight, is provided. In other words, no resin binder is contained.

The electroconductive thick film paste of the present invention is a silver electroconductive paste, which includes silver particles, glass particles, and an organic vehicle, and is used in an electrode for connecting a back face terminal on the silicon substrate of a solar cell, and is characterized by the fact that the average particle diameter of said silver particles is 3.0-15.0 μm. The present invention is further directed to an electrode formed from the composition as detailed above and a solar cell comprising said electrode.

A process for preparing the antibacterial activated carbon fibres containing nano silver particles includes preparing the activated carbon fibres by using phosphoric acid as activator, and dipping for adsorbing the silver particles by said fibres. It can kill all the Escherichia coli and staphylococlus aureus in water. Its advantages are less consumption, and high, fost and durable antibacterial effect.

The invention provides a nano conductive adhesive. The conductive adhesive is a uniform mixture of one of or two, three or four of micron-grade silver powder, submicron-grade silver powder, nano silver powder or a nano silver wire, and a high molecular material, solvent and a curing agent. The invention also provides a preparation method of the nano conductive adhesive, which comprises the following steps: 1. preparing the micron-grade silver powder, the submicron-grade silver powder, the nano silver powder and the nano silver wire by a microwave method; and 2. mixing the components in different proportions with the high molecular material, the solvent and the curing agent. The invention has the advantages of even diameter of a conductive silver particle obtained by the microwave method and simple preparation. The conductive adhesive performance can be improved by the optimal design of the particle proportion. The conductive adhesive with high conductive performance is prepared by three silver powder particles and one nano silver wire in certain size selection and proportion. The prepared conductive adhesive has stable performance and high rheological property.

The invention discloses a method for preparing nano silver particles by using plant extract for reduction, and application of the method. In the method, the extract of natural plants such as chrysanthemum, honeysuckle flower, or bud of Japanese pagoda tree which serves as a reducing agent reacts with Ag<+> in aqueous solution of silver nitrate to ensure that Ag<+> is reduced into elementary substance silver nano particles. The method is simple, reaction conditions are mild, additives except for silver nitrate are not needed, the plant extract which is low in cost and can be easily obtained is used as the reducing agent, and the method is environment-friendly; the nano silver particles obtained by the method have smaller diameters, and high dispersibility and stability in aqueous solution; and Chinese herbal medicine components which have the effects of antibiosis and antiphlogosis are added, and the method has the characteristics of disinfection and sterilization, bacteriostasis, safety, no toxicity or irritation and the like and can be directly applied to multiple kinds of dermatological and surgical bacterial infection or medical equipment and cosmetics.

The invention provides a novel nanometer silver particle / graphene conductive compound material, which belongs to the technical field of compound materials. The preparation method of the material comprises the following steps of: ultrasonically dispersing oxidized graphite in water for 1 to 2 hours, adding silver nitrate solid, keeping ultrasonically dispersing for 25 to 30 minutes, raising the temperature to 70 to 80 DEG C, adding sodium borohydride for reflux reaction for 1 to 2 hours, thermally filtering, washing, drying and grinding to obtain the Ag / graphene nanometer conductive compound material. The Ag / graphene nanometer conductive compound material can be prepared by a one-step reduction method, which is simple in process, convenient in operation, mild in reaction and high in production efficiency; in the prepared conductive compound material, the nanometer silver particles are uniformly absorbed on the edge of the graphene so as to form a conductive network where Ag and the graphene are staggered mutually; therefore, the dispersion of the nanometer silver particles is improved, and the thermal stability and the conductivity of the graphene are enhanced; and the Ag / graphene nanometer conductive compound material has a good industrial production prospect.

The invention discloses a microcapsule-fabric-finishing-technology-based nano silver antibacterial fabric and a preparation method thereof. Nano silver particle microcapsules using alginate as capsule walls are prepared by using an alginate microcapsule technology and added into a fabric to form the nano silver antibacterial fabric by after treatment. The antibacterial fabric realizes high dispersion uniformity of the nano silver particles, and well solves the agglomeration problem of nano particles; good impregnation of the degradable natural macromolecular microcapsules in the fabric is realized, and the biocompatibility of the antibacterial fabric is improved; the antibacterial fabric has sustained-release effect, long-acting performance, washing fastness and durability; the color change problem of the antibacterial fabric is solved; and the antibacterial fabric has excellent antibacterial performance and high-temperature resistance. Moreover, the preparation method of the antibacterial fabric is simple, nontoxic and easy for industrialization.

The invention discloses a nanocomposite of silver, chitosan and / or a chitosan derivative and a preparation method thereof. The preparation method comprises the steps of evenly mixing the chitosan and / or the chitosan derivative fine powder with silver nitrate fine powder and fully grinding for 1-3 hours with the weight proportion of the chitosan and / or the chitosan derivative to the silver nitrate of 100: 0.0005-0.5; adding a reducing agent with the reduction equivalence ratio of the reducing agent to the silver nitrate of 1: 1-2: 1 and fully grinding for 2-6 hours, thereby obtaining the nanocomposite of the silver, chitosan and / or the chitosan derivative with the silver particle size of 1-100nm. The nanocomposite has the effects of promoting wound healing, stopping bleeding, alleviating pain, anti-inflammation and sterilization, can be used for treating female vaginitis, cervicitis, cervical erosion, bedsores, skin ulcers, burns, scalds, trauma and other skin inflammation, tinea manus and pedis and the like, and can also be used for preparing a variety of trauma dressings, such as thin films, sponges, gynecological suppositories, patches and the like.

The present invention relates to a high-concentration nanoscale silver colloidal solution and the preparing process thereof. The colloidal solution of the present invention comprises a high content of silver particles, i.e. approximately 1.5 wt %. The mean size of the nanoscale silver is less than 10 nm. In the preparing process, silver salt, ionic chelating agent, stabilizing agent, reducing agent, solvent and reaction accelerator are homogeneously mixed together. The increase of reaction temperature by external heat source accelerates completed reaction. By using the specified reaction accelerator and chelating agent and under the operating condition of the present invention, high-density silver colloidal solution is obtained while inhibiting particle aggregation. Therefore, the resulting nanoscale silver colloidal solution contains very small-sized particles and the stability thereof is satisfactory.

The invention belongs to the technical field of environmental catalytic materials and specifically relates to a preparation method of a silver-carrying titanium dioxide anti-bacterial agent. The anti-bacterial agent comprises titanium dioxide microspheres as carriers with a high length-diameter ratio and silver particles distributed on surfaces or interiors of the titanium dioxide microspheres. The preparation method comprises a titanium dioxide microsphere preparation method and a silver particle carrying method, wherein the silver particle carrying method adopts the following three methods of a complex reaction and photo-reduction combined method, a direct photo-reduction method and an excessive immersion method. The operation of the present preparation method is simple. Titanium dioxide carriers prepared by the present preparation method has a high length-diameter ratio, a high crystallinity and thus can reduce effectively recombination of electrons and holes and enhance titanium dioxide photocatalytical and anti-bacterial effects, and the silver particle carrying method can effectively control a dispersibility of silver and make silver be distributed on surfaces or interiors of titanium dioxide microspheres to realize a slow release of silver, avoid color change, and enhance anti-bacterial effects simultaneously.

Disclosed is a method suitable for large-scale producing silver nanostructures including nanoparticles and nanowires with high crystallization and purity in a short period of time. In this method, silver particles with mean diameter less than 200 nm and silver nanowires with length in micrometers are produced through a microwave-assisted wet chemistry method. Tens to hundreds grams of silver nanoparticles and nanowires are obtained in minutes by microwave irradiation treatment to a precursor pre-made by highly concentrated silver salt solution and other additives. These silver nanoparticles and nanowires have good dispersibility and are ideal for forming conductive adhesives.

The invention discloses high-temperature resistant epoxy resin conductive adhesives, which are characterized by comprising the following compositions by weight portion: 10 to 25 portions of modified epoxy resins, 0.05 to 0.5 portions of organosilicon coupling agent, 0.1 to 2 portions of imidazole curing agent, 60 to 80 portions of micron silver powder, 0.05 to 5 portions of nano silver particles and 0 to 5 portions of carbon nanotube. The modified epoxy resins simultaneously use a proper amount of coupling agent to replace epoxy resins which are generally adopted in the market, thereby the high-temperature resistance of the adhesives is greatly improved; due to addition of the micro silver powder and the nano silver particles or the carbon nanotube, the conductivity of the adhesives is greatly improved; and due to addition of the electricity and heat conducting carbon nanotube, the electroconductibility and the thermal conductivility of the adhesives are improved.

A thermal interface material (40) includes a silver colloid base (32), and an array of carbon nanotubes (22) disposed in the silver colloid base uniformly. The silver colloid base includes silver particles, boron nitride particles and polysynthetic oils. The silver colloid base has a first surface (42), and a second surface (44) opposite to the first surface. The carbon nanotubes are substantially parallel to each other, and extend from the first surface to the second surface. A method for manufacturing the thermal interface material includes the steps of: (a) forming an array of carbon nanotubes on a substrate; (b) immersing the carbon nanotubes in a silver colloid base; (c) solidifying the silver colloid base; and (d) peeling the solidified silver colloid base with the carbon nanotubes secured therein off from the substrate.

The invention discloses an agranular transparent conductive ink which can sinter at low temperature and has good stability, and a preparation method thereof. The conductive ink mainly consists of a solvent organic amine or ammonia water and an organic silver salt. During preparation, one of the solvent organic amine or ammonia water or more than one of other solvents are only needed to be mixed well, then an effective quantity of the organic silver salt is added, and after complete dissolution and dispersion, the conductive ink can be obtained. The conductive ink can form a pattern or a wet film by means of printing or coating, wherein, the organic silver part can be reduced to silver particles in the following heat treatment process so as to form a conductive pattern or conductive film. The conductive ink obtained through the method of the invention can has high stability without adding an extra protective agent. The preparation method put forward in the method has the advantages of simple process, mild reaction condition, short reaction time and low preparation cost.

The invention relates to a preparation method of antimicrobial, and aims at providing a preparation method of mesoporous hollow spherical silver-loaded silicon dioxide antimicrobial, which comprises the following steps that polystyrene microspheres are added into mixed solution of ethanol with dissolved hexadecyl trimethyl ammonium bromide and de-ionized water to be uniformly mixed, then ammonia is added, ethyl orthosilicate is gradually dropped, the obtained solution is filtered, washed and dried to obtain compound powder with polystyrene being wrapped by silicon dioxide microspheres; the powder is subjected to heat preservation at the temperature of 550 DEG C to obtain hollow silicon dioxide microspheres; and under a light-resistant condition, the hollow silicon dioxide microspheres are soaked inside silver nitrate solution, and then the solution is filtered, dried and heated to the temperature of 300 to 500 DEG C so as to obtain the mesoporous hollow spherical silver-loaded silicon dioxide antimicrobial. The dispersivity and the stability of silver particles are improved, so that the agglomeration problem of traditional nano antimicrobial powder can be effectively solved. Meanwhile, the antimicrobial can be slowly released through mesoporous, the releasing of silver particles can be effectively maintained for a long time so as to realize the lasting antibacterial effect.