Coatings applicable to a variety of substrate articles, structures, materials, and equipment are described. In various applications, the substrate includes
metal surface susceptible to formation of
oxide,
nitride,
fluoride, or
chloride of such
metal thereon, wherein the
metal surface is configured to be contacted in use with gas,
solid, or liquid that is reactive therewith to form a
reaction product that is deleterious to the substrate article, structure, material, or equipment. The metal surface is coated with a protective
coating preventing reaction of the
coated surface with the
reactive gas, and / or otherwise improving the electrical, chemical, thermal, or structural properties of the substrate article or equipment. Various methods of
coating the metal surface are described, and for selecting the
coating material that is utilized.