6630 results about "Potassium permanganate" patented technology

The invention discloses a grapheme / silicon composite material for a lithium ion battery cathode material and a preparation method thereof, belonging to the fields of electrochemistry and new energy materials. The method comprises the following steps of: using graphite as a raw material; oxidizing the graphite into oxidized graphite by adopting oxidants of concentrated sulfuric acid and potassium permanganate; then, ultrasonically stripping the oxidized graphite to prepare oxidized graphene; mixing oxidized graphene in different proportions with nano silicon powder; ultrasonically dispersing, filtering or directly drying into a cake / film; and roasting under a reduction atmosphere to prepare self-support graphene / silicon composite film materials in different proportions. Proved by electrochemistry tests, the graphene / silicon composite film material prepared by the method has higher specific capacity and cycle stability, simple preparation method and easy mass production and consequently is an ideal high-energy lithium ion battery cathode material.

The invention discloses a preparation method of a graphene material. The preparation method comprises the following steps of: with graphite carbon as a raw material, adding potassium hypermanganate and concentrated sulfuric acid in batches in different stages to control an oxidation process of graphite; adjusting the pH value of the oxidized solution to obtain graphene oxide colloidal dispersing solutions (GOS) with different concentrations; dropwise adding the GOS on the surface of a carrier or spreading out the GOS on a non-intersolubility liquid / liquid interface and drawing into a grapheneoxide thin-film (GOF); carrying out high-speed centrifugation and drying treatment on the GOS to obtain graphene oxide solid powder (GOP); reducing the GOS by selecting an appropriate reducing agent,and centrifugally drying to obtain reduced graphene solid powder (GRP); dispersing a proper amount of GRP in an organic solvent to prepare a reduced graphene oxide colloidal dispersing solution (GRS); and dropwise adding the GRS on the surface of the carrier or spreading out on the non-intersolubility liquid / liquid interface and drawing into the reduced graphene thin-film (GRF). Various graphene materials prepared by the invention are easy to mutually transform; and the concentration of the colloidal solution and the thickness of the thin-film can be controlled in a certain range.

The invention discloses a wet method smoke gas denitration technology of two segments of liquid phase oxidation and absorption, which adopts solution or mixtures of one or more of potassium permanganate, sodium chlorite, sodium hypochlorite, calcium hypochlorite, oxyful and chlorine dioxide as oxidizing agents to ensure nitrogen oxide in smoke gas contact and react with the oxidizing agents. After the nitrogen oxide is partially oxidized into nitrogen dioxide, oxidized nitrogen oxide in the smoke gas is absorbed by alkali liquid to generate corresponding nitrite. The technology adopts liquid phase oxidation to replace gas phase oxidation so as to reduce the investment and the running cost, simplify the technical process and the system structure, and enhance the operability. Compared with a method that oxidation and absorption are simultaneously carried out in the liquid phase, the two-segment technology not only can increase the removal efficiency, avoid secondary pollution caused by incomplete absorption of NO2, but also can achieve the purposes of selectively generating and recovering the nitrite in the absorption stage by controlling the oxidation degree of the oxidation stage.

The invention discloses a preparation method for preparing manganese dioxides in various crystal forms, comprising the following steps of: with divalent manganese salt as a reducing agent and potassium permanganate as an oxidant, adjusting the ratio of raw materials, and reacting in a reaction kettle at 160 DEG C for 1-12h to synthesize both one-dimensional alpha-MnO2 nano fibers and beta-MnO2 nano bars and gamma-MnO2 flower-like structures. The preparation method is simple in preparation process and low in cost; and the product can be used for the research in fields such as super capacitor direction, catalysis and the like.

The present invention relates to the preparation of nano material. One-dimensional monocrystalline nano manganese dioxide wire of different crystal form is synthesized selectively via controlling thetemperature, period and material control of the hydrothermal reaction of two-valent manganese salt and ammohnium persulfate as raw material and ammonium sulfate as additive at 100-220 deg.c inside one sealed reactor. The process may be widely used in basic theory research in lithium ion cell, molecular sieve and relevant fields.

The invention discloses a method for electrochemically preparing graphene, which preferably comprises the steps of pressing a high-purity graphite raw material to form a graphite electrode, carrying out anodization through the graphite electrode by using sulfuric acid aqueous solution or acetic acid and the like mixed acid solution as an electrolyte to prepare a graphite intercalation product, and obtaining expanded graphite by high temperature or microwave and other methods; and then pressing the expanded graphite to prepare a reaction electrode, and carrying out secondary electrochemical intercalation and expansion to finally obtain laminar graphene. According to the invention, in the preparing process, potassium permanganate and other strong oxidizers are not used, and the damage of the strong oxidizers to the structure and performance of graphene are avoided; alkali metal, fuming sulfuric acid oxydol and other inflammable and explosive dangerous substances are not used, and toxic or harmful substances are not introduced, so that the production is safe and environment friendly; and at the same time, the method is simple in process flow, easy to operate, low in cost, high in yield, mild in reaction conditions and low in energy consumption, and is suitable for industrialized large-scale production.

The invention relates to an oxygen delignification processing method of grass unbleached chemical pulp. The oxygen delignification of the pulp is processed after cooking and before bleaching. Its rigidity before the oxygen delignification is potassium permanganate value 16-28 (equals to karber value 26-50). After pumping into the oxygen delignification reaction tower and inflating sodium hydroxide, magnesium salt and oxygen, the chemical pulp happen the oxygen delignification in the reaction tower. The chemical pulp with rigidity of potassium permanganate value 10-14 (equals to karber value 14-18) is achieved after the oxygen delignification. The invention can remove the lignin in the pulp effectively and the removal rate is 86-98%. It reduces the degradation of the cellulose to simplify the bleaching process and cut down the dosage of the chemicals. The bleached pulp has good rigidity and drainability. The breaking length of the pulp can reach 4500-8000m and its fold-resistant times can reach 20-70.

The invention relates to a high-efficient combined inhabitor for pyrite in complex sulfide ores and the application method of the inhabitor. The inhabitor comprises calcium superoxide and HA-Na. The inhabitor of the invention can inhibit complex vulcanized iron-bearing minerals selectively, has better inhibition properties for magnetic pyrite, pyrite and arsonopyrite, and is an inhabitor of high selectivity. Compared with the prior inhibitors such as lime, cyanide, bichrome, potassium permanganate, sodium sulfide, sulphite, zinc sulphate and trisodium phosphate, the invention has the advantages of lower use level, good effects, no pollution, and other advantages.

The invention relates to a preparation method of a graphene and manganese dioxide nanocomposite material, comprising: (1) stirring and mixing graphite, potassium nitrate and concentrated sulfur evenly, adding potassium permanganate, and reacting at 30-40° C. for 20-40 minutes , add deionized water at room temperature, add hydrogen peroxide after reacting for 15 to 30 minutes to obtain graphite oxide; (2) disperse the above graphite oxide in water, add hydrazine hydrate, and react at 95°C for 1 to 24 hours to obtain graphene (3) ultrasonically disperse the graphene in a saturated potassium permanganate solution, add acid, and react at 60-80° C. for 1-5 hours to obtain graphene and manganese dioxide nanocomposite material. The invention has the advantages of simple reaction, easy control, convenient operation and simple process; the obtained composite material has broad application prospects and can be used for catalysts, biosensing materials, electrode materials of lithium ion batteries and supercapacitor electrode materials, and the like.

The invention discloses a short-spike and root-grafting rapid propagation method for camellia azalea. The short-spike and root-grafting rapid propagation method comprises the following steps: selecting general camellia oleifera seeds, sterilizing the general camellia oleifera seeds with potassium permanganate solution and then carrying out stratification, sprouting and anvil culture; after radicles are 3-4 cm in length, grafting the radicles; selecting one-year branches with strongly-grown crown peripheries, full sprout eyes, no pest and disease damage and half lignification to lignification as scions with the length of 2-3 cm; soaking base parts with a plant growth regulator solution; after the scions are grafted, planting the grafted scions in a container bag filled with nutrient-rich substrate on a seed bed in a sunshelter for culturing; and covering, humidifying, shielding and carrying out standard management to form a high-quality grafted container seedling of the camellia azalea. According to the short-spike and root-grafting rapid propagation method, the grafting is realized at the smooth parts of radicles and the root systems of plants are developed, so that the survival rate and the growth amount of nursery stock can be effectively increased and the culture time of the stock is greatly shortened; and the scions are short, and thus the utilization rate and the propagation coefficient of the scions are improved. The short-spike and root-grafting rapid propagation method has the advantages of convenience for operation, high work efficiency and better economic benefit and social benefit; and according to the method, the scale propagation effect of the camellia azalea stock is ensured.

The invention discloses a water-preserving nutrient soil for indoor flowers, which comprises pond sludge, chaff ash, bean curd dross, Attapulgite clay, alta-mud, quartz sand, potassium permanganate, ferrous sulfate, copper sulfate, sulphur, 45% content of azophoska composite fertilizer and high water absorbent resin.

A composite Mn-Ce oxide catalyst for oxidizing the form-aldehyde into CO2 and H2O is prepared through adding soluble manganese nitrate in the solution of potassium permanganate and cerium ammonium nitrate while stirring, adding potassium hydroxide, stirring to obtain deposit, filtering, washing, drying at 80-120 deg.C and calcining.

The invention discloses a method for preparing a graphene oxide. The method comprises the following steps of: a) adding concentrated inorganic acid into a sealed reactor, adding graphite powder with stirring, reducing the temperature to the temperature of between 0 and 4 DEG C, and adding potassium permanganate to react for 0.5 to 2 hours; b) heating the obtained reaction system to the temperature of between 60 and 70 DEG C, and standing for 12 to 24 hours; c) adding hydrogen peroxide into distilled water in a volume ratio of 1:10, freezing to obtain ice, transferring the graphite oxide to the distilled water containing the hydrogen peroxide until the ice is completely dissolved, uniformly stirring, performing suction filtration, washing and drying to obtain the graphene oxide. The graphite powder, the concentrated acid and the potassium permanganate serve as raw materials, and the raw materials are low in cost and readily available; NO, NO2 and other toxic gases are prevented from being produced; the reaction temperature is as low as 60-70 DEG C; and the product has high dye adsorption capacity and high industrial application value.

This invention relates to a method for fabricating solid-state alkaline polymer Zn-air battery, which consists of a zinc-gel anode, an air cathode electrode, and alkaline polymer electrolyte. The formulation of said zinc gel anode is similar to that of alkaline Zn-MnO2 battery. The zinc gel anode contains a mixture of electrolytic dendritic zinc powders, KOH electrolyte, gelling agent and small amount of additives. The air cathode electrode is made by carbon gas diffusion electrode, which comprises two layers, namely gas diffusion layer and active layer. The active layer on the electrolyte side uses a high surface area carbon for oxygen reduction reaction and potassium permanganate and MnO2 as catalysts for oxygen reduction. The diffusion layer on the air side has high PTFE content to prevent KOH electrolyte from weeping or climbing. Due to adequate amount of fresh air and oxygen supply, the air cathode electrode can run continuously. Theoretically, the polymer zinc-air battery is an accumulator if the cell has sufficient zinc powder and electrolyte, and the air cathode plays the role of energy transfer.

The invention relates to a formaldehyde purificatory absorbent and a preparation method thereof, which belongs to the technical field of a purificant and a preparation method thereof. The formaldehyde purificatory absorbent uses a porous material as a carrier and the carrier is one or more of activated alumina, sea-foam and zeolite molecular sieve. The preparation method relates to that a steeping fluid is placed into a beaker, added with carrier powders at a steeping temperature ranging from 20 DEG C to 60 DEG C, stirred for 2 through 6 hours, dried at the temperature ranging from 100 DEG C to 140 DEG C after being filtrated and then porphyrized with a mortar. The steeping fluid adopts a strong oxidizer potassium permanganate and is diluted to an acid solution and an organic amine solution of 3 to 8 percent by de-ionized water. The method of the invention adopts the strong oxidizer as an active component and carries out the steeping of the carrier after the active component is coordinated with the solution, when the active component is of even load bearing, thus being able to oxidize the adsorbed formaldehyde molecule to be carbon dioxide desorption and forming the cycle adsorption to enlarge the adsorption capacity thereof. Besides, the method of the invention adopts the acid solution and the organic amine to carry out the steeping modification of the carrier, which improves the characteristics of the carrier, like the structure in the pores or on the surface, the polarity and so on, and enhances the adsorption ability to formaldehyde.

The invention discloses a preparation method of a composite heat conduction graphene membrane and the composite heat conduction graphene film. The preparation method comprises the following steps: S1, putting crystalline flake graphite or graphite powder into a mixed solution of concentrated sulfuric acid, potassium persulfate and phosphorus pentoxide, soaking for a day and a night, then carrying out suction filtration, drying, and carrying out pre-oxidizing; S2, oxidizing pre-oxidized graphite further by adopting a Hummers method, that is, oxidizing fully in concentrated sulfuric acid and potassium permanganate, then adding deionized water for diluting, and carrying out repeated washing and suction filtration, so as to obtain an oxidized graphene aqueous solution; S3, spraying the oxidized graphene aqueous solution on a substrate by adopting a thermal spray method, and depositing, so as to obtain an oxidized graphene film; S4, reducing the oxidized graphene film, so as to obtain the graphene film; and S5, laminating the graphene film, so as to obtain the composite heat conduction graphene film. Compared with the prior art, the preparation method is simple, the cost is low, and the prepared composite heat conduction graphene film has a favorable heat conduction performance.

The invention discloses an in-situ composite system based on a carbon quantum dot / manganese dioxide nanometer sheet layer and a using method of the in-situ composite system. The using method comprises the following steps: firstly, completely quenching fluorescence by using a manner that carbon quantum dots are adsorbed on a manganese dioxide nanometer sheet layer prepared by reducing potassium permanganate in situ, and then quantitatively analyzing and determining the content of the GSH in a GSH to-be-tested sample based on a principle of causing digestion of the manganese dioxide nanometer sheet layer, releasing the carbon quantum dots and recovering the fluorescence thereof by virtue of a redox reaction between glutathione (GSH) and manganese dioxide. According to the in-situ composite system, the detection method is high in precision, the repeatability is good, a used carbon material is low in price, easily available, and free from polluting the environment, and has relatively good biological safety; meanwhile, the in-situ composite system is simple and convenient to operate, relatively strong in practicability, high in sensitivity, and excellent in selectivity of the GSH.

The invention discloses a graphene / titanium dioxide lithium ion battery cathode material and a preparation method, and belongs to the field of electrochemistry and new energy materials. The method comprises the following steps of: oxidizing graphite powder into graphite oxide by using concentrated sulfuric acid or potassium permanganate as an oxidant, peeling the graphite oxide to form graphene oxide by adopting an ultrasonic peeling method, mixing the graphite oxide and a titanium source, preparing a graphite oxide / titanium dioxide composite material by liquid phase reaction, and then reducing the graphite oxide / titanium dioxide composite material into the graphene / titanium dioxide composite material by adopting liquid phase reduction. Electrochemical tests show that the graphene / titanium dioxide composite material prepared by the method has high specific capacity and cyclical stability, and is an ideal lithium ion battery cathode material. The material has relatively high specific capacity and cyclical stability, and can exert respective advantages of graphene and titanium dioxide. The preparation method is relatively simple, has low cost, and is suitable for industrialized production.

The invention discloses a bunker coal environment-friendly synergist, which comprises the following components by weight percent: 1 to 10 percent of ammonium bicarbonate, 1 to 8 percent of sodium bicarbonate, 1 to 10 percent of sodium carbonate, 1 to 5 percent of sodium nitrate, 1 to 10 percent of potassium nitrate, 1 to 15 percent of calcium carbonate, 1 to 10 percent of sodium hydroxide, 2 to 10 percent of calcium hydroxide, 1 to 10 percent of potassium permanganate, 3 to 15 percent of potassium chloride, 10 to 35 percent of sodium chloride, 1 to 10 percent of ammonium chloride, 1 to 15 percent of calcium chloride, 1 to 10 percent of borax, 1 to 10 percent of macaroni, 1 to 5 percent of potassium carbonate, 1 to 5 percent of calcium nitrate, 1 to 5 percent of iron oxide, and the balance being micro turpentine, sulfur and paraffin wax. The bunker coal environment-friendly synergist makes flame of combustion be more rampant and denser, the furnace temperature rise to a higher level, the hearth be brighter and cleaner and tail gas be cleaner.

The invention provides a boiler coal combustion-improving desulfurizing and denitrifying agent composition. The composition comprises the following raw materials in parts by weight: 2-7 parts of sodium carbonate, 1-3 parts of alumina, 2-8 parts of aluminium hydroxide, 2-5 parts of ferric trichloride, 2-6 parts of ferric oxide, 3-10 parts of potassium permanganate, 3-10 parts of potassium chlorate, 10-35 parts of activated attapulgite clay, 15-30 parts of urea, 2-4 parts of ammonium formate, 2-4 parts of ammonium chloride, 6-23 parts of ammonium acetate, 3-9 parts of manganese oxide, 9-12 parts of copper chloride, 1-3 parts of copper oxide, 2-4 parts of zinc sulfate, 1-3 parts of zinc nitrate, 7-18 parts of potassium dichromate, 1.0-1.5 parts of titanium dioxide, 0.5-1.0 part of barium molybdate, 0.5-1.5 parts of cobalt sulfate, 0.5-1.5 parts of vanadium pentoxide, 0.3-0.7 part of cerium oxide, 0.1-0.2 part of sodium dodecyl benzene sulfonate and 0.1-0.2 part of alkyl glyceryl ether. The composition is convenient to use, has stable properties, plays roles of combustion improving, desulfurization and denitrification, has coal saving rate of 8-25% and can remove fixed sulfur by 50-70%.

This invention relates to a refine means of epsilon - caprolactam by separation and purification. The feature of the invention lay in that it includes the step of crystallize epsilon - caprolactam from ethereal solution containing crude epsilon - caprolactam.The product purity can reach 99.98%upwards, absorption value of potassium permanganate is greater than 10000 or more, the extinction value of epsilon - caprolactam at 290nm wavelength is 0.05 or smaller. The invention wholly meet the require of industrial product.

The invention discloses a biomass curing-forming fuel. The biomass curing-forming fuel consists of straws, saw dust, coal dust, a combustion improver, a sulfur-fixing agent and a dust-falling agent according to parts by weight, wherein the straw is one or combination of the straw of crops such as rice, wheat, soybean, corn, sorghum, cotton, rape and tobacco, a branch and a bark of trees and shrubs, rice hull, chaff and peanut coat; the combustion improver is one or more of table salt, sodium nitrate, potassium permanganate, potassium oxide, sodium nitrite and sodium hypochlorite and capable of realizing decomposition and combustion supporting at different temperatures; the sulfur-fixing agent is in a manner that sodium carbonate, calcium hydroxide and alkyl alcohol amine compounds are synergistically used and is capable of reducing discharging of sulfur dioxide; and the dust-falling agent is selected from iron sesquioxide and capable of lowering a melting point of ash and reducing dust volume. The biomass curing-forming fuel has the advantages that the combustion efficiency is high, the slag bonding and the soot formation are not generated, the black smoke is little, the fire power strong, the combustion is sufficient, the ash does not fly, the biomass curing-forming fuel is clean and sanitary and the like. The invention further discloses a preparation method of the biomass curing-forming fuel.

The invention relates to a tazobactam synthesis method which comprises the steps of: with 6-APA(Amino Penicillanic Acid) as raw material, preparing a key intermediate 6,6-dihydro penam sulphoxide acid diphenylcarbinol ester through successive reactions of esterification, oxidation, reduetive debromination and the like without separation; then, reacting with 2-triphenyl silicon-1,2,3-triazole; introducing a triazole ring; and finally obtaining the final product of tazobactam through potassium permanganate oxidation and metacresol deprotection. The tazobactam synthesis method is mainly characterized in that a phase transfer catalyst is introduced in the first step, therefore, the reaction rate and the product purity are improved; since an environment-friendly hydrogen peroxide-cobalt acetate catalytic oxidation system is adopted in the third step, the characteristics of good reaction selectivity, high yield, catalyst recyclability and the like are achieved; a method for synthesizing 2 alpha-methyl-2 beta-(1,2,3- triazole-1- radical) methyl penam-3 alpha-carboxylic acid diphenylcarbinol ester by using 2-triphenyl silicon-1,2,3-triazole is adopted in the fifth step, and the tazobactamsynthesis method is simple and convenient to operate, is safe and reliable, shortens the reaction route and improves the total yield. Compared with the traditional process, the tazobactam synthesis method greatly reduces the production cost and the environment pollution and has greater implementation value and economic benefits.

The invention relates to a preparation method of a composite electrode material using flap-like manganese dioxide nanocrystal to coat carbon nanotubes, comprising the following steps: (1) dispersing MWCNTs to a saturated potassium permanganate solution, dropwise adding strong acid to adjust the pH value of the solution to 0-1, performing ultrasonic processing at 60-80 DEG C for 3-10h; (2) allowing the solution to react at 120-180 DEG C for 1-10h, naturally cooling; (3) performing repeated washing, suction filtering and vacuum drying the product obtained in step (2); and (4) pressing the composite product on a nickel screen to manufacture the electrode of a super capacitor. In the invention, the types of required chemicals are few, the cost is low, the reaction is easy to control, the operation is convenient and the process is simple. The obtained carbon nanotube coated by flap-like manganese dioxide nanocrystal has a CV curve with obvious rectangular characteristic when being used as the electrode of a superior capacitor, and has higher specific capacitance and good stability of electrochemical performance.

The invention relates to a method for removing heavy metals in a water body, which is characterized in that common oxidizers for water treatment, such as hydrogen peroxide, sodium hypochlorite, potassium permanganate and the like, are utilized for oxidization to activate the zero-valent iron surface and continuously generate fresh iron (III) / (II) (hydro)oxide and other active components, thereby quickly and efficiently removing heavy metals in the water body, including As, Hg, Cd, Pb, Cr, Se, Sb, Cu, Zn and the like, in a mode of adsorption, precipitation, redox or the like.

An adsorption powder useful for the removal of mercury and other metals, as well as furans, dioxins and other organic compounds from gaseous streams. The powder may be characterized as containing a carbon-based powder and an effective amount of cupric chloride suitable for removing metals and organic compounds from high temperature and moisture gaseous streams. The powder may contain calcium hydroxide, sulfur, potassium permanganate, potassium iodide, and combinations thereof.

Consuming water with increased hydrogen content can provide clinical benefits to humans and animals through a non-mitochondria alternative cellular energy (ACE) pathway and also as an antioxidant. This application discloses that the hydrogen content of drinking water can be safely increased by placing into the water a hydrogen generating device, such as a mixture of metallic magnesium and EH-101 (HB-101) containing solution, whereby the device allows for the selective passage of the generated hydrogen but restricts the passage of magnesium and EH-101 (HB-101) components. This partitioning of hydrogen from EH-101 (HB-101) components is achieved by using either reverse osmosis membrane, low density plastic material such as polyvinylidene chloride (PVDC or Saran), or low molecular weight cutoff dialysis membrane to create a sealed container of the magnesium and magnesium chloride, that can be placed into drinkable water. The EH-101 (HB-101) can be initially placed into a breakable inner compartment within the hydrogen permeable container. This compartment can be easily broken by simple squeezing just prior to placing the device into the water that is intended to have its hydrogen content increased. The increased hydrogen content can be assessed by the capacity of the water to decolorize a potassium permanganate test sample.

The invention relates to a porous grapheme / MnO2 composite film and a preparation method and application thereof. The preparation method comprises the following steps of (1), providing a ball-shaped formwork and coating the surface of the ball-shaped formwork with a polymer layer; (2) providing graphene oxide solution, evenly mixing a small formwork ball coated with the polymer layer obtained in the step (1) with the graphene oxide solution, performing vacuum filtration, and stripping the composite film from a filter membrane after drying; (3) performing high temperature annealing on the composite film obtained in the step (2) to obtain a film of a porous structure; (4) putting the film obtained in the step (3) into potassium permanganate solution to perform hydrothermal reaction to obtain the porous grapheme / MnO2 composite film. No any binder or conductive agent is needed to be added to the porous composite film prepared by the method, and the porous composite film is good mechanical property and super capacitive performance, has the advantages of being good in high-rate charge and discharge performance, long in circle life and the like, and can be applied to preparing super-capacitors and improve performance of super-capacitors greatly.

The present invention relates to a paper pulp prepared by using rice straw and wheat straw as raw material. The breaking length of said paper pulp is 4500-8100 km. and its tearing strength is 180-280 mN. Besides, said invention also provides its preparation method and concrete steps.