1579 results about "Partial oxidation" patented technology

The invention forms an epitaxial silicon-containing layer on a silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface and avoids creating a rough surface upon which the epitaxial silicon-containing layer is grown. In order to avoid creating the rough surface, the invention first performs a hydrofluoric acid etching process on the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. This etching process removes most of oxide from the surface, and leaves only a sub-monolayer of oxygen (typically 1×1013-1×1015 / cm2 of oxygen) at the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. The invention then performs a hydrogen pre-bake process in a chlorine containing environment which heats the silicon germanium, strained silicon, or thin silicon-on-insulator surface sufficiently to remove the remaining oxygen from the surface. By introducing a small amount of chlorine containing gases, the heating processes avoid changing the roughness of the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. Then the process of epitaxially growing the epitaxial silicon-containing layer on the silicon germanium, patterned strained silicon, or patterned silicon-on-insulator surface is performed.

The present invention provides systems and methods to improve the performance and emission control of internal combustion engines equipped with nitrogen oxides storage-reduction (“NSR”) emission control systems. The system generally includes a NSR catalyst, a fuel processor located upstream of the NSR catalyst, and at least one fuel injection port. The fuel processor converts a fuel into a reducing gas mixture comprising CO and H2. The reducing gas mixture is then fed into the NSR catalyst, where it regenerates the NSR adsorbent, reduces the NOx to nitrogen, and optionally periodically desulfates the NSR catalyst. The fuel processor generally includes one or more catalysts, which facilitate reactions such as combustion, partial oxidation, and / or reforming and help consume excess oxygen present in an engine exhaust stream. The methods of the present invention provide for NSR catalyst adsorbent regeneration using pulsed fuel flow. Control strategies are also provided.

A catalyst for treating the exhaust gas from internal combustion engines is provided, wherein the catalyst contains two catalytically active layers supported on a support. The first catalytically active layer contains a platinum group metal in close contact with all of the constituents of the first catalytically active layer, wherein the constituents of the first catalytically active layer include particulate aluminum oxide; particulate oxygen storage material, such as cerium oxide, cerium / zirconium and zirconium / cerium mixed oxides, and alkaline earth metal oxides. The second catalytically active layer, which is in direct contact with the exhaust gas, contains particulate aluminum oxide and at least one particulate oxygen storage material, such as cerium oxide, cerium / zirconium and zirconium / cerium mixed oxides. Rhodium is supported on part of the aluminum oxides in the second catalytically active layer or on the particulate oxygen storage material in the second catalytically active layer. By providing the platinum group metal in close contact with all of the constituents of the first catalytically active layer, improved conversion efficiency of the impurities in the exhaust gas can be achieved.

A process for the partial catalytic oxidation of a hydrocarbon containing feed comprising contacting the feed with an oxygen-containing gas in the presence of a catalyst retained within a reaction zone in a fixed arrangement, wherein the catalyst comprises at least one catalytically active metal selected from the group consisting of silver and Group VIII elements supported on a porous ceramic carrier. The porous ceramic carrier has a distribution of total pores wherein about 70% of the total pores (1) have a volume-to-surface area (V / S) ration that is within about 20% of the mean V / S value for the total pores and no pores have a V / S ration that is greater than twice the mean V / S value for the total pores; (2) have a pore-to-pore distance between neighboring pores that is within about 25% of the mean pore-to-pore distance between neighboring pores; and (3) have a pore throat area that is within about 50% of the mean pore throat are for the pores. Additionally, about 50% of the total pores have a coordination number between neighboring pores that is within about 25% of the mean coordination number between neighboring pores. Preferably, the oxidation process comprises a multistage, staged oxygen, catalytic partial oxidation process having fewer than or equal to about five stages and including a first stage preheat temperature of greater than about 550° C., and wherein the temperature of the product mixture in each stage following the first stage is at least about 700° C.

A steam methane reforming method in which a feed stream is treated in a reactor containing a catalyst that is capable of promoting both hydrogenation and partial oxidation reactions. The reactor is either operated in a catalytic hydrogenation mode to convert olefins into saturated hydrocarbons and / or to chemically reduce sulfur species to hydrogen sulfide or a catalytic oxidative mode utilizing oxygen and steam to prereform the feed and thus, increase the hydrogen content of a synthesis gas produced by a steam methane reformer. The method is applicable to the treatment of feed streams containing at least 15% by volume of hydrocarbons with two or more carbon atoms and / or 3% by volume of olefins, such as a refinery off-gas. In such case, the catalytic oxidative mode is conducted with a steam to carbon ratio of less than 0.5, an oxygen to carbon ratio of less than 0.25 and a reaction temperature of between about 500° C. and about 860° C. to limit the feed to the steam methane reformer to volumetric dry concentrations of less than about 0.5% for the olefins and less than about 10% for alkanes with two or more carbon atoms.

The present invention provides several variations for converting biomass, and other carbon-containing feedstocks, into syngas. Some variations include pyrolyzing or torrefying biomass in a devolatilization unit to form a gas stream and char, and gasifying the char. Other variations include introducing biomass into a fluid-bed gasifier to generate a solid stream and a gas stream, followed by a partial-oxidation or reforming reactor to generate additional syngas from either, or both, of the solid or gas stream from the fluid-bed gasifier. Hot syngas is preferably subjected to heat recovery. The syngas produced by the disclosed methods may be used in any desired manner, such as conversion to liquid fuels (e.g., ethanol).

Disclosed is a process for the preparation of superheated of steam by transferring heat from at least a fraction of a high pressure steam to a lower pressure steam to produce a superheated, lower pressure steam. The high pressure steam can be generated by recovering heat from a heat producing chemical process such as, for example, the partial oxidation of carbonaceous materials. The lower pressure steam can be generated by reducing the pressure of a portion of the high pressure steam or by recovering heat from one or more chemical processes. The superheated, lower pressure steam may used to generate electricity in a steam turbine, operate a steam turbine drive, or as a heat source. Also disclosed is a process for driving a steam turbine using superheated steam produced by the process of the invention.

A catalyst has a base catalyst layer containing platinum and barium as precious metal supported by alumina and an over catalyst layer containing platinum and rhodium as precious metal supported by zeolitr. The platinum and rhodium in the over catalyst layer activate NOx and HC so as to make them more reactive in terms of energy, and the barium in the base catalyst layer makes the platinum be more dispersive in the base catalyst layer. Under the existence of dispersive platinum, NOx in exhaust gas is decomposed and purified by reaction with reactive NO2 and partially oxidized HC generated in the over catalyst layer.

Process for the production of liquid hydrocarbons from a feedstock that comprises at least one elementary feedstock from the group of biomass, coal, lignite, petroleum residues, methane, and natural gas, comprising: at least one stage a) for gasification of the feedstock by partial oxidation and / or steam reforming to produce a synthesis gas SG; a stage b) for separating CO2 from SG and a portion of the effluent of the subsequent stage c); the mixing of a portion of the CO2 that is separated with a gas of an H2 / CO ratio of more than 3; a stage c) for partial conversion with hydrogen, thermal or thermocatalytic, of the CO2 that is present in said first mixture according to the reaction: CO2+H2→CO+H2O in a specific reaction zone that is separated from said gasification zone or zones; a stage d) for Fisher-Tropsch synthesis on a synthesis gas that comprises at least a portion of SG and at least a portion of the CO that is produced by the conversion of CO2 into hydrogen.

A method of operating a gas turbine power plant and gas turbine power plant are disclosed wherein hydrogen for the combusting process is produced by feeding natural gas mixed with steam through a membrane / partial oxidation reactor and converting the natural gas at least to H2 and CO. Thereby oxygen is transferred from the compressed air through the membrane of the membrane / partial oxidation reactor and the oxygen is used for the partial oxidation process of the natural gas. The process is followed by converting the syngas in a CO shift reactor and a CO shift reactor to a CO2 removal equipment to mainly hydrogen.

A photoelectrochemical assay apparatus for determining chemical oxygen demand (COD) of a water sample which consists of a) a measuring cell for holding a sample to be analysed b) a titanium dioxide nanoparticle photoelectric working electrode and a counter electrode disposed in said cell, c) a UV light source adapted to illuminate the photoelectric working electrode d) control means to control the illumination of the working electrode e) potential measuring means to measure the electrical potential at the working and counter electrodes f) analysis means to derive a measure of oxygen demand from the measurements made by the potential measuring means. The method of determining chemical oxygen demand of a water sample, comprises the steps of a) applying a constant potential bias to a photoelectrochemical cell, containing a supporting electrolyte solution; b) illuminating the working electrode with a UV light source and recording the background photocurrent produced at the working electrode from the supporting electrolyte solution; c) adding a water sample, to be analysed, to the photoelectrochemical cell; d) illuminating the working electrode with a UV light source and recording the total photocurrent produced; e) determining the chemical oxygen demand of the water sample according to the type of degradation conditions employed. The determination may be under exhaustive degradation conditions, in which all organics present in the water sample are oxidised or under non-exhaustive degradation conditions, in which the organics present in the water sample are partially oxidised.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with complete carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor. The resulting partially oxidized stream that comprises a fuel gas is quenched, filtered, cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream is scrubbed to provide the recycle CO2 stream, which is compressed and passed through the recuperator heat exchanger and the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

The invention is directed to a process wherein a feedstock or stream comprising steam cracker tar is passed to a vacuum pipestill. A deasphalted cut of tar is obtained as an overhead (or sidestream) and a heavy tar asphaltenic product is obtained as bottoms. In preferred embodiments, at least a portion of the bottoms product is sent to a partial oxidation unit (POX) wherein syn gas may be obtained as a product, and / or at least a portion of the bottoms product is used to produce a light product stream in a coker unit, such as coker naphtha and / or or coker gas oil. In another preferred embodiment at least a portion of the overheads product is added to refinery fuel oil pools and in yet another preferred embodiment at least a portion of the overheads product is mixed with locally combusted materials to lower soot make. Two or more of the aforementioned preferred embodiments may be combined.

A method and device for the gasification of pulverized fuels from solid fuels such as bituminous coals, lignite coals, and their cokes, petroleum cokes, coke from peat or biomass, in entrained flow, with an oxidizing medium containing free oxygen, by partial oxidation at pressures between atmospheric pressure and 80 bar, and at temperatures between 1,200 and 1,900° C., at high reactor capacities between 1,000 and 1,500 MW. The method uses the following steps: metering of the fuel, gasification reaction in a gasification reactor with cooled reaction chamber contour, quench-cooling, crude gas scrubbing, and partial condensation.

This invention relates to methods for reacting a hydrocarbon, molecular oxygen, and optionally water and / or carbon dioxide, to form synthesis gas. The preferred embodiments are characterized by delivering a substochiometric amount of oxygen to each of a multitude of reaction zones, which allows for optimum design of the catalytic packed bed and the gas distribution system, and for the optimization and control of the temperature profile of the reaction zones. The multitude of reaction zones may include a series of successive fixed beds, or a continuous zone housed within an internal structure having porous, or perforated, walls, through which an oxygen-containing stream can permeate. By controlling the oxygen supply, the temperatures, conversion, and product selectivity of the reaction can be in turn controlled and optimized. Furthermore the potential risks of explosion associated with mixing hydrocarbon and molecular oxygen is minimized with increased feed carbon-to-oxygen molar ratios.

A process for the removal of organosulfur compounds from hydrocarbon materials is disclosed. The process includes contacting an ionic liquid with a hydrocarbon material to extract sulfur-containing compounds into the ionic liquid. The sulfur-containing compounds can be partially oxidized to sulfoxides and / or sulfones prior to or during the extraction step.

By using catalytic partial oxidation or autothermal reforming process, a catalytic oxidizer installed in the engine's Exhaust Gas Recycle (EGR) line can be used to produce from fossil fuels or bio-fuels a reformate gas containing H2 and CO for an IC engine or a gas turbine. Thus, a system consisting of an EGR Oxidizer and an IC engine / gas turbine can be used by itself as a driving device, or can be combined with an electric generator and a battery bank to produce, store and transmit electricity to be used in stationary or mobile power generation, transportation and utility etc.The Oxidizer can also be used to provide reducing gases to regenerate the NOx or diesel particulate traps, so that the traps can continuously be used for reducing emissions from IC engine, diesel truck, gas turbine, power plant etc.

Systems and methods for producing syngas are provided. A first hydrocarbon can be partially oxidized in the presence of an oxidant and one or more first catalysts at conditions sufficient to partially combust a portion of the first hydrocarbon to provide carbon dioxide, non-combusted first hydrocarbon, and heat. The non-combusted first hydrocarbon can be reformed in the presence of the heat generated in the partial oxidation step and the one or more first catalysts to provide a first syngas. Heat can be indirectly exchanged from the first syngas to a second hydrocarbon to reform at least a portion of the second hydrocarbon in the presence of steam and one or more second catalysts to provide a second syngas. A syngas, which can include the at least a portion of the first syngas, at least a portion of the second syngas, or a mixture thereof can be converted to provide one or more Fischer-Tropsch products, methanol, derivatives thereof, or combinations thereof.

Method of preparing and introducing fuel into the combustors of a gas turbine in which a hydrocarbon containing feed, oxygen and steam are introduced into a catalytic partial oxidation reactor to produce a product stream. The hydrocarbon containing feed contains no less than about 15 percent by volume on a dry basis of hydrocarbons with at least two carbon atoms and / or at least about 3 percent by volume of olefins. The reactant mixture formed of the hydrocarbon containing feed, oxygen and steam has an oxygen to carbon ratio of between about 0.08 and about 0.25 and a water to carbon ratio of between about 0.05 to about 0.5. The hydrocarbon containing feed is introduced into the reactor alone or with a steam at a temperature no greater than 600° C. and the product stream is produced at a temperature of between about 600° C. and 860° C. and contains less than about 0.5 percent of olefins and less than 10 percent of hydrocarbons with two or more carbon atoms on a dry basis. After cooling the product stream the product stream is introduced into the combustors of the gas turbine to form part or all of the fuel required to support combustion.

A process to prepare elemental iron by contacting an iron ore feed with a reducing gas at a pressure of between 1 and 10 bar to obtain iron and an off-gas includes preparing the reducing gas by performing the following steps: (a) partially oxidizing a mixture comprising a solid or liquid carbonaceous fuel and oxygen at a pressure of between 10 and 80 bar, thereby obtaining a gas comprising H2 and CO; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain an intermediate gas comprising H2 and CO; (c) supplying the intermediate gas obtained in step (b) to a H2-selective membrane to obtain a H2-rich permeate gas and a CO-rich retentate; and (d) heating H2-rich permeate to obtain a heated H2-rich permeate as the reducing gas.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with complete carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor. The resulting partially oxidized stream that comprises a fuel gas is quenched, filtered, cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream is scrubbed to provide the recycle CO2 stream, which is compressed and passed through the recuperator heat exchanger and the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

A field effect transistor (FET) is formed as follows. A trench is formed in a silicon region. An oxidation barrier layer is formed over a surface of the silicon region adjacent the trench and along the trench sidewalls and bottom. A protective layer is formed over the oxidation barrier layer inside and outside the trench. The protective layer is partially removed such that a portion of the oxidation barrier layer extending at least along the trench bottom becomes exposed and portions of the oxidation barrier layer extending over the surface of the silicon region adjacent the trench remain covered by remaining portions of the protective layer.

A device and a method for flame stabilization in a burner (10), includes a burner housing at least partially enclosing a burner volume, into which may be introduced via at least one fuel line, fuel, and via at least one air feed means, air, forming an air / fuel mixture spreading in a preferred flow direction, which may be ignited in a combustion chamber (11) connecting downstream of the burner housing to form a stationary flame (13). Upstream of the flame (13), a catalyst arrangement (1) is provided through which an air / pilot fuel mixture (4), separate from the air / fuel mixture, is flowable. The catalyst arrangement (1) has at least two catalyst stages which are located one behind the other in the through-flow direction, of which the catalyst stage (3) located upstream, the so-called POX-catalyst, is flow-washable by the air / pilot fuel mixture (4) with an air / pilot fuel mixture ratio λ<1, by which catalyst stage (3) the air / pilot fuel mixture (4) is partially oxidized, and of which catalyst stages the downstream catalyst stage (8), the so-called FOX-catalyst, is flow-washable by a leaned air / pilot fuel mixture (7) with a mixture ratio λ>1, by which the leaned air / pilot fuel mixture is completely oxidized forming an inert hot gas flow (9).

The present invention provides several variations for converting biomass, and other carbon-containing feedstocks, into syngas. Some variations include pyrolyzing or torrefying biomass in a devolatilization unit to form a gas stream and char, and gasifying the char. Other variations include introducing biomass into a fluid-bed gasifier to generate a solid stream and a gas stream, followed by a partial-oxidation or reforming reactor to generate additional syngas from either, or both, of the solid or gas stream from the fluid-bed gasifier. Hot syngas is preferably subjected to heat recovery. The syngas produced by the disclosed methods may be used in any desired manner, such as conversion to liquid fuels (e.g., ethanol).

The invention discloses a wet method smoke gas denitration technology of two segments of liquid phase oxidation and absorption, which adopts solution or mixtures of one or more of potassium permanganate, sodium chlorite, sodium hypochlorite, calcium hypochlorite, oxyful and chlorine dioxide as oxidizing agents to ensure nitrogen oxide in smoke gas contact and react with the oxidizing agents. After the nitrogen oxide is partially oxidized into nitrogen dioxide, oxidized nitrogen oxide in the smoke gas is absorbed by alkali liquid to generate corresponding nitrite. The technology adopts liquid phase oxidation to replace gas phase oxidation so as to reduce the investment and the running cost, simplify the technical process and the system structure, and enhance the operability. Compared with a method that oxidation and absorption are simultaneously carried out in the liquid phase, the two-segment technology not only can increase the removal efficiency, avoid secondary pollution caused by incomplete absorption of NO2, but also can achieve the purposes of selectively generating and recovering the nitrite in the absorption stage by controlling the oxidation degree of the oxidation stage.

A power generation system and method in which a fuel gas is introduced into a combustor and at least a portion of the fuel gas is combusted in the combustor, producing an exhaust gas having no appreciable available oxygen. The exhaust gas is introduced as a working fluid into a gas turbine, thereby generating power. Cooling of the power generation system is accomplished using a cooling fluid selected from the group consisting of synthesis gas, natural gas, natural gas / steam mixture, flue gas, flue gas / steam mixture, and mixtures thereof.