The invention provides a compound blockage relieving agent, which comprises an A agent, a B agent and a C agent. The A agent is
chlorine dioxide solution, and is
chlorite or
chlorate; the B agent is in a non-acid
solid active agent system, and comprises organic oisocyanuric
acid salt,
inorganic sulfate and
chlorate; and the C agent is an organic inhibitor for resisting oxidation
corrosion of
chlorine dioxide, and is organic
phosphine. A using method comprises the following steps: the compound blockage relieving agent which is generated through fast activation aboveground and is based on the
chlorine dioxide is wholly injected into an
oil well formation fin one step through a
bushing, then water is injected through the
bushing, the
chlorine dioxide compound blockage relieving agent with higher concentration after being activated is extruded into a perforation section,
polymer of an oil layer is in
oxidative degradation, and various bacterial microorganisms bred by raw oil and
sulfide are oxidized and completely killed, thereby the invention achieves the purpose of eliminating blockage, has the characteristic that faint yellow
liquid based on the
chlorine dioxide of
high concentration is generated through the fast activation, has no large quantity of
chlorine dioxide gas escape, and can be widely used for fields such as
oil well blockage relieving,
water well blockage relieving, and the like.