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82 results about "Methane reformer" patented technology

A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. There are multiple types of reformers in development but the most common in industry are autothermal reforming (ATR) and steam methane reforming (SMR). Most methods work by exposing methane to a catalyst (usually nickel) at high temperature and pressure.

Reforming system for combined cycle plant with partial CO2 capture

A combined cycle system includes, a pre-steam-methane-reformer operating at a temperature of less than about 800 degrees Celsius to reform a mixed fuel stream to generate a first reformate stream, a water-gas-shift reactor to convert carbon monoxide in the first reformate stream to carbon dioxide and form a second reformate stream, a carbon dioxide removal unit for removing carbon dioxide from the second reformate stream and form a carbon dioxide stream and a third reformate stream; wherein less than about 50 percent of the carbon contained in the mixed fuel stream is recovered as carbon dioxide by the removal unit, a gas turbine unit for generating power and an exhaust stream, and a steam generator unit configured to receive the exhaust stream, wherein the heat of the exhaust stream is transferred to a water stream to generate the steam for the mixed fuel stream and for a steam turbine.
Owner:GENERAL ELECTRIC CO

Steam methane reforming method

A steam methane reforming method in which a feed stream is treated in a reactor containing a catalyst that is capable of promoting both hydrogenation and partial oxidation reactions. The reactor is either operated in a catalytic hydrogenation mode to convert olefins into saturated hydrocarbons and / or to chemically reduce sulfur species to hydrogen sulfide or a catalytic oxidative mode utilizing oxygen and steam to prereform the feed and thus, increase the hydrogen content of a synthesis gas produced by a steam methane reformer. The method is applicable to the treatment of feed streams containing at least 15% by volume of hydrocarbons with two or more carbon atoms and / or 3% by volume of olefins, such as a refinery off-gas. In such case, the catalytic oxidative mode is conducted with a steam to carbon ratio of less than 0.5, an oxygen to carbon ratio of less than 0.25 and a reaction temperature of between about 500° C. and about 860° C. to limit the feed to the steam methane reformer to volumetric dry concentrations of less than about 0.5% for the olefins and less than about 10% for alkanes with two or more carbon atoms.
Owner:PRAXAIR TECH INC

Controlling the synthesis gas composition of a steam methane reformer

A method for controlling the synthesis gas composition obtained from a steam methane reformer (SMR) that obtains its feedstock as product gas directly from a steam hydro-gasification reactor SHR). The method allows control of the H2 / CO syngas ratio by adjusting the hydrogen feed and the water content of feedstock into a steam hydro-gasification reactor that supplies the SMR. The steam and methane rich product gas of the SHR is generated by means of hydro-gasification of a slurry of carbonaceous material and water. The mass percentages of the product stream at each stage of the process are calculated using a modeling program, such as the ASPEN PLUS™ equilibrium process. By varying the parameters of solid to water ratio and hydrogen to carbon ratio, a sensitivity analysis can be performed that enables one determine the optimum composition of the slurry feedstock to the SHR to obtain a desired syngas ratio output of the SMR. Thus one can adjust the hydrogen feed and the water content of feedstock into the SHR that supplies the SMR to determine the syngas ratio output of the SMR.
Owner:RGT UNIV OF CALIFORNIA

Autothermal reformer-reforming exchanger arrangement for hydrogen production

Low-energy, low-capital hydrogen production is disclosed. A reforming exchanger 14 is placed in parallel with an autothermal reformer (ATR) 10 to which are supplied a preheated steam-hydrocarbon mixture. An air-steam mixture is supplied to the burner / mixer of the ATR 10 to obtain a syngas effluent at 650°-1050° C. The effluent from the ATR is used to heat the reforming exchanger, and combined reformer effluent is shift converted and separated into a mixed gas stream and a hydrogen-rich product stream. High capital cost equipment such as steam-methane reformer and air separation plant are not required.
Owner:KELLOGG BROWN & ROOT LLC

Hydrogen product method and apparatus

A method and apparatus for producing a hydrogen containing product in which hydrocarbon containing feed gas streams are reacted in a steam methane reformer of an existing hydrogen plant and a catalytic reactor that reacts hydrocarbons, oxygen and steam. The catalytic reactor is a retrofit to the existing hydrogen plant to increase hydrogen production. The resulting synthesis gas streams are combined, cooled, subjected to water-gas shift and then introduced into a production apparatus that can be a pressure swing adsorption unit. The amount of synthesis gas contained in a shifted stream made available to the production apparatus is increased by virtue of the combination of the synthesis gas streams to increase production of the hydrogen containing product. The catalytic reactor is operated such that the synthesis gas stream produced by such reactor is similar to that produced by the steam methane reformer and at a temperature that will reduce oxygen consumption within the catalytic reactor.
Owner:PRAXAIR TECH INC

Integrated Coal To Liquids Process And System With Co2 Mitigation Using Algal Biomass

An ICBTL system having a low GHG footprint for converting coal or coal and biomass to liquid fuels in which a carbon-based feed is converted to liquids by direct liquefaction and optionally by indirect liquefaction and the liquids are upgraded to produce premium fuels. CO2 produced by the process is used to produce algal biomass and photosynthetic microorganisms in a photobioreactor. Optionally, lipids extracted from the some or all of the algal biomass is hydroprocessed to produce fuel components and biomass residues and the carbon-based feed our gasified to produce hydrogen and syngas for the direct and indirect liquefaction processes. Some or all of the algal biomass and photosynthetic microorganisms are used to produce a natural biofertilizer. CO2 may also be produced by a steam methane reformer for supplying CO2 to produce the algal biomass and photosynthetic microorganisms.
Owner:ACCELERGY CORP

Controlling the synthesis gas composition of a steam methane reformer

An improved, economical alternative method to supply steam and methane to a steam methane reformer (SMR) is accomplished by a combination of procedures, wherein product gas from a steam hydro-gasification reactor (SHR) is used as the feedstock for the SMR by removing impurities from the product stream from the SHR with a combination of autothermal reforming, condensation removal and gas cleanup procedures that operates substantially at process pressures and at a temperature above the boiling point of water at the process pressure, is located between the SHR and SMR. In another embodiment, a method is provided for controlling the H2 / CO syngas ratio obtained from a steam methane reformer (SMR) by adjusting the hydrogen feed and the water content of feedstock into a steam hydro-gasification reactor that supplies the SMR.
Owner:RGT UNIV OF CALIFORNIA

Process for heavy oil and bitumen upgrading

ActiveUS20120270957A1Improved heavy oil and bitumen upgradingIncrease productionHydrogenOrganic compound preparationMethane reformerSyngas
A bitumen and heavy oil upgrading process and system is disclosed for the synthesis of hydrocarbons, an example of which is synthetic crude oil (SCO). The process advantageously avoids the waste attributed to residuum and / or petcoke formation which has a dramatic effect on the yield of hydrocarbon material generated. The process integrates Fischer-Tropsch technology with gasification and hydrogen rich gas stream generation. The hydrogen rich gas generation is conveniently effected using singly or in combination a hydrogen source, a hydrogen rich vapour from hydroprocessing and the Fischer-Tropsch process, a steam methane reformer (SMR) and autothermal reformer (ATR) or a combination of SMR / ATR. The feedstock for upgrading is distilled and the bottoms fraction is gasified and converted in a Fischer-Tropsch reactor. A resultant hydrogen lean syngas is then exposed to the hydrogen rich gas stream to optimize the formation of, for example, the synthetic crude oil. The hydrogen lean gas stream may also be effected by a water gas shift reaction, singly or in combination or in addition with the hydrogen rich gas stream generation. A system for effecting the process is also characterized in the specification.
Owner:EXPANDER ENERGY

Carbon dioxide emission reduction method

Carbon dioxide emissions within a refinery are reduced by reforming a hydrocarbon containing feed at low pressure to enhance the conversion of methane to hydrogen and carbon monoxide and thereby reduce methane slip. The hydrocarbon containing feed is composed entirely or at least in part of a refinery off gas. The resulting reformed stream is then subjected to water-gas shift conversion to form a shifted stream from which carbon dioxide is separated. As a result of the separation and the low pressure reforming, hydrogen containing fuel gas streams, that are thereby necessary lean in carbon dioxide and methane, are used in firing the steam methane reformer and other fuel uses within the refinery to reduce carbon dioxide emissions. The carbon dioxide that is separated can be sequestered or used in other processes such as enhanced oil recovery.
Owner:PRAXAIR TECH INC

Hydrogen production method

A method of producing a hydrogen product stream in which a steam stream is reacted with a hydrocarbon containing stream within a steam methane reformer. The resulting product stream is subjected to a water gas shift reaction and then to pressure swing adsorption to produce the hydrogen product stream. The hydrocarbon stream is alternatively formed from a first type of feed stream made up of natural gas, refinery off-gas, naphtha or synthetic natural gas or combinations thereof and a second type that is additionally made up of a hydrogen and carbon monoxide containing gas. During use of both of the types of feed streams, the flow rate of the steam stream is not substantially changed and reformer exit temperatures of both the reactant and the flue gas side are held essentially constant.
Owner:PRAXAIR TECH INC

Controlling the synthesis gas composition of a steam methane reformer

InactiveUS20080021121A1Improved and economicalGas modification by gas mixingWaste based fuelMethane reformerSyngas
A method for controlling the synthesis gas composition obtained from a steam methane reformer (SMR) that obtains its feedstock as product gas directly from a steam hydro-gasification reactor SHR). The method allows control of the H2 / CO syngas ratio by adjusting the hydrogen feed and the water content of feedstock into a steam hydro-gasification reactor that supplies the SMR. The steam and methane rich product gas of the SHR is generated by means of hydro-gasification of a slurry of carbonaceous material and water. The mass percentages of the product stream at each stage of the process are calculated using a modeling program, such as the ASPEN PLUS™ equilibrium process. By varying the parameters of solid to water ratio and hydrogen to carbon ratio, a sensitivity analysis can be performed that enables one determine the optimum composition of the slurry feedstock to the SHR to obtain a desired syngas ratio output of the SMR. Thus one can adjust the hydrogen feed and the water content of feedstock into the SHR that supplies the SMR to determine the syngas ratio output of the SMR.
Owner:RGT UNIV OF CALIFORNIA

Carbon dioxide emission reduction method

InactiveUS8007761B2Less carbonLess carbon dioxide contentSolidificationLiquefactionMethane reformerMethane
Carbon dioxide emissions within a refinery are reduced by reforming a hydrocarbon containing feed at low pressure to enhance the conversion of methane to hydrogen and carbon monoxide and thereby reduce methane slip. The hydrocarbon containing feed is composed entirely or at least in part of a refinery off gas. The resulting reformed stream is then subjected to water-gas shift conversion to form a shifted stream from which carbon dioxide is separated. As a result of the separation and the low pressure reforming, hydrogen containing fuel gas streams, that are thereby necessary lean in carbon dioxide and methane, are used in firing the steam methane reformer and other fuel uses within the refinery to reduce carbon dioxide emissions. The carbon dioxide that is separated can be sequestered or used in other processes such as enhanced oil recovery.
Owner:PRAXAIR TECH INC

Operation of a steam methane reformer by direct feeding of steam rich producer gas from steam hydro-gasification

InactiveUS20080021119A1Improved and economical alternativeWaste based fuelLiquid hydrocarbon mixture productionMethane reformerProduct gas
An improved, economical alternative method to supply steam and methane to a steam methane reformer (SMR) is accomplished by a combination of procedures, wherein product gas from a steam hydro-gasification reactor (SHR) is used as the feedstock for the SMR by removing impurities from the product stream from the SHR with a gas cleanup unit that operates substantially at process temperatures and pressures and is located between the SHR and SMR.
Owner:RGT UNIV OF CALIFORNIA

Steam Methane Reformer and Hydrogen Station Having it Using High Performing Metal Fiber Burner

The steam methane reformer using a premixed metal fiber burner which has a short flame length as well as a high temperature to thereby provide a high efficiency and also reduce a size, and a hydrogen station having the same. The steam methane reformer using a high performing metal fiber burner comprises a reforming part (110a) in which a catalyst for steam-reforming hydrocarbon materials and producing hydrogen is disposed; a combustion part (120) which is provided with a premixed metal fiber burner (120a) for generating heat required for the steam reforming reaction of the reaction tubes (110a); a raw material supplying part (130) for supplying hydrocarbon materials to the reaction tube (110a); and a hydrogen discharging part (140) for discharging hydrogen produced through the steam reforming reaction by the catalyst of the reaction tube (110a).
Owner:SK INNOVATION CO LTD

Partial upgrading process for heavy oil and bitumen

A bitumen and heavy oil upgrading process and system is disclosed for the synthesis of hydrocarbons, an example of which is synthetic crude oil (SCO). The process integrates Fischer-Tropsch technology with gasification and hydrogen rich gas stream generation. The hydrogen rich gas generation is conveniently effected using singly or in combination a hydrogen source, a hydrogen rich vapour from hydroprocessing and the Fischer-Tropsch process, a steam methane reformer (SMR) and autothermal reformer (ATR) or a combination of SMR / ATR. The feedstock for upgrading is distilled and the bottoms fraction is gasified and converted in a Fischer-Tropsch reactor. A resultant hydrogen lean syngas is then exposed to the hydrogen rich gas stream to optimize the formation of, for example, the synthetic crude oil. Partial upgrading and the commensurate benefits is detailed as well. A system for effecting the processes is also characterized in the specification.
Owner:EXPANDER ENERGY

Coal liquefaction complex with minimal carbon dioxide emissions

The invention described herein relates to a novel process for reducing the carbon dioxide emissions from a coal and / or biomass liquefaction facility by utilizing a steam methane reformer unit in the complex designed to produce additional hydrogen which can be thereafter utilized in the process, as required for the plant fired heaters (including the SMR furnace), and for the production of plant steam. The plant light ends (C1, C2, etc.), which are normally utilized as fuel gas streams are the primary feeds to the SMR Unit along with the tail gas purge from a gasification complex within the facility.
Owner:INST FR DU PETROLE

Hydrocarbon treatment method and apparatus

The present invention provides a method and apparatus for producing a treated hydrocarbon containing stream for use as a feed to a steam methane reformer of a hydrogen plant. In accordance with such method, amounts of olefins and organic sulfur species within an untreated feed are decreased in a reactor that is operated in either a hydrogenation mode to hydrogenate the olefins into saturated hydrocarbons or a pre-reforming mode in which hydrocarbon containing two or more carbon atoms including the olefins are reacted with oxygen and steam to form saturated hydrocarbons, methane, additional hydrogen and carbon monoxide. The reactor is configured and operates at a sufficiently high space velocity that olefin and organic species slip occurs that is further treated in a hydrotreater. The reactor contains a catalyst capable of promoting both hydrogenation and oxidation reactions and the hydrotreater contains a catalyst that is capable of only promoting hydrogenation reactions.
Owner:PRAXAIR TECH INC

Conversion of waste co2 into useful transport fuels using steam methane reformer in a gas to liquids plant

A method of producing fuel from CO2 comprising introducing natural gas, steam, and recovered CO2 to a reformer to produce unshifted syngas characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1; introducing the unshifted syngas to a water gas shift unit to produce a shifted syngas, wherein an amount of CO2 in the shifted syngas is greater than in the unshifted syngas; separating the CO2 from the shifted syngas to produce recycle CO2 and a hydrogen-enriched syngas; recycling the recycle CO2 to the reformer, introducing the unshifted syngas to a Fischer-Tropsch (FT) unit to produce an FT product, FT water, and FT tail gas, wherein the FT product comprises FT liquids and FT wax; and separating the FT liquids from the FT product to produce a fuel.
Owner:FLUOR TECH CORP

Capture of CO2 from Hydrogen Plants Using A Temperature Swing Adsorption Method

The invention involves the use of a temperature swing adsorption process in steam methane reforming or autothermal reforming H2-production processes to capture CO2 and produce nearly pure off gas streams of CO2 for sequestration or enhanced oil recovery (EOR). The hydrogen stream output is substantially pure and can be recycled as a fuel to the steam methane reformer furnace or used in other petroleum and petrochemical processes.
Owner:CHEVROU USA INC

Autothermal reformer-reforming exchanger arrangement for hydrogen production

Low-energy, low-capital hydrogen production is disclosed. A reforming exchanger 14 is placed in parallel with an autothermal reformer (ATR) 10 to which are supplied a preheated steam-hydrocarbon mixture. An air-steam mixture is supplied to the burner / mixer of the ATR 10 to obtain a syngas effluent at 650°-1050° C. The effluent from the ATR is used to heat the reforming exchanger, and combined reformer effluent is shift converted and separated into a mixed gas stream and a hydrogen-rich product stream. High capital cost equipment such as steam-methane reformer and air separation plant are not required.
Owner:KELLOGG BROWN & ROOT LLC

Process for heavy oil and bitumen upgrading

A bitumen and heavy oil upgrading process and system is disclosed for the synthesis of hydrocarbons, an example of which is synthetic crude oil (SCO). The process advantageously avoids the waste attributed to residuum and / or petcoke formation which has a dramatic effect on the yield ofhydrocarbon material generated. The process integrates Fischer-Tropsch technology with gasification and hydrogen rich gas stream generation. The hydrogen rich gas generation is conveniently effected using singly or in combination a hydrogen source, a hydrogen rich vapour from hydroprocessing and the Fischer-Tropsch process, a steam methane reformer (SMR) and autothermal reformer (ATR) or a combination of SMR / ATR. The feedstock for upgrading is distilled and the bottoms fraction is gasified and converted in a Fischer-Tropsch reactor. A resultant hydrogen lean syngas is then exposed to the hydrogen rich gas stream to optimize the formation of, for example, the synthetic crude oil. The hydrogen lean gas stream may also be effected by a water gas shift reaction, singly or in combination or in addition with the hydrogen rich gas stream generation. A system for effecting the process is also characterized in the specification.
Owner:史蒂夫.克雷斯尼亚克

Process integration of a gas processing unit with liquefaction unit

InactiveUS20180038642A1Efficient and flexible to produceLow costSolidificationLiquefactionMethane reformerPartial oxidation
It is proposed to integrate a gas processing unit with a liquefaction unit. The industrial gas stream may be but is not limited to air gases of oxygen, nitrogen argon, hydrocarbon, LNG, syngas or its components, CO2, or any other molecule or combination of molecules. It is proposed to integrate the underutilized process inefficiencies of a gas processing unit into the liquefaction unit to produce a liquid at a reduced operating cost. The gas processing unit may be any system or apparatus which alters the composition of a feed gas. Examples could be, but are not limited to, a methanol plant, steam methane reformer, cogeneration plant, and partial oxidation unit.
Owner:LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE

Use of by-product carbon dioxide from a steam methane reformer in an algae biofuel production process

Carbon dioxide that is collected as a by-product of hydrogen production from a steam methane reformer (SMR) is used as a feed stock for growth of algae biomass for various purposes, e.g. biofuel production, chemical intermediates, nutraceuticals or pharmaceuticals. This invention helps reduce emissions of carbon dioxide, a known greenhouse gas, and helps to optimize algae growth that is used for the production clean biofuel to reduce the dependence on petroleum and fossil fuels.
Owner:LINDE AG
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