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382results about "Gas modification by gas mixing" patented technology

Catalytic steam gasification process with recovery and recycle of alkali metal compounds

A high efficiency gasification process for converting carbonaceous solids to methane and apparatus for its practice are described. The process includes reacting steam and carbonaceous solids comprising ash in the presence of alkali metal catalyst in a gasification reactor to produce combustible gases and char particles comprising ash and alkali metal catalyst constituents, treating a stream of such char particles in an alkali metal catalyst recovery system to recover the catalyst constituents as alkali metal compounds, and recycling such recovered compounds. Within the alkali metal catalyst recovery system the process includes quenching the stream of char particles with water whereby such particles are cooled and fractured, dissolving soluble alkali metal catalyst constituents from the fractured solids to form a first alkali metal catalyst solution and washed solids, optionally reacting the washed solids in alkaline solution to form a second alkali metal catalyst solution, upgrading said first and optional second alkali solution to recover the alkali metal catalyst constituents as said alkali metal compounds.
Owner:SURE CHAMPION INVESTMENT LTD

Steam Generating Slurry Gasifier for the Catalytic Gasification of a Carbonaceous Feedstock

Steam generating gasification reactors for providing high-pressure and high-temperature steam for catalytic gasification of a carbonaceous feedstock can be based on oxygen blown gasification reactors adapted for processing a slurry feedstock comprising at least 40% water. The exhaust from the slurry gasifier comprises at least steam, carbon monoxide and hydrogen. The slurry composition and the oxygen to fuel ratio can be varied to control the ratio of carbonaceous gases in the generator exhaust. By directing substantially all of exhaust gases produced from the slurry gasification reactor through the catalytic gasifier and subsequent gas separation and sequestration processes, a greatly higher energy efficiency and decreased carbon footprint can be realized.
Owner:SURE CHAMPION INVESTMENT LTD

Conversion of petroleum residua to methane

This invention discloses improvements on previous inventions for catalytic conversion of coal and steam to methane. The disclosed improvements permit conversion of petroleum residua or heavy crude petroleum to methane and carbon dioxide such that nearly all of the heating value of the converted hydrocarbons is recovered as heating value of the product methane. The liquid feed is distributed over a fluidized solid particulate catalyst containing alkali metal and carbon as petroleum coke at elevated temperature and pressure from the lower stage and transported to the upper stage of a two-stage reactor. Particulate solids containing carbon and alkali metal are circulated between the two stages. Superheated steam and recycled hydrogen and carbon monoxide are fed to the lower stage, fluidizing the particulate solids and gasifying some of the carbon. The gas phase from the lower stage passes through the upper stage, completing the reaction of the gas phase.
Owner:PETRO2020

Petroleum Coke Compositions for Catalytic Gasification

Particulate compositions are described comprising an intimate mixture of a petroleum coke, coal and a gasification catalyst, where the gasification catalyst is loaded onto at least the coal for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

Co-Feed of Biomass as Source of Makeup Catalysts for Catalytic Coal Gasification

ActiveUS20090217588A1HydrogenProductsHydrogenMetal
Continuous processes are provided for converting a carbonaceous feedstock comprising biomass containing alkali metal, non-biomass components, and at least one gasification catalyst including an alkali metal recovered from solid char, into a plurality of gaseous products including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons.
Owner:SURE CHAMPION INVESTMENT LTD

Catalytic Gasification Particulate Compositions

Particulate compositions are described comprising a carbonaceous material, such as petroleum coke and / or coal, treated or otherwise associated with a gasification catalyst, where the catalyst is at least in part derived from a leachate from a biomass char, for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

System and process for producing synthetic liquid hydrocarbon

Production of synthetic liquid hydrocarbon fuel from carbon containing moieties such as biomass, coal, methane, naphtha as a carbon source and hydrogen from a carbon-free energy source is disclosed. The biomass can be fed to a gasifier along with hydrogen, oxygen, steam and recycled carbon dioxide. The synthesis gas from the gasifier exhaust is sent to a liquid hydrocarbon conversion reactor to form liquid hydrocarbon molecules. Unreacted CO & H2 can be recycled to the gasifier along with CO2 from the liquid hydrocarbon conversion reactor system. Hydrogen can be obtained from electrolysis of water, thermo-chemical cycles or directly by using energy from carbon-free energy sources.
Owner:PURDUE RES FOUND INC

Method and Apparatus for Automated, Modular, Biomass Power Generation

Method and apparatus for generating a low tar, renewable fuel gas from biomass and using it in other energy conversion devices, many of which were designed for use with gaseous and liquid fossil fuels. An automated, downdraft gasifier incorporates extensive air injection into the char bed to maintain the conditions that promote the destruction of residual tars. The resulting fuel gas and entrained char and ash are cooled in a special heat exchanger, and then continuously cleaned in a filter prior to usage in standalone as well as networked power systems.
Owner:COMMUNITY POWER CORP

System For the Conversion of Carbonaceous Fbedstocks to a Gas of a Specified Composition

The present invention provides a carbonaceous feedstock gasification system with integrated control subsystem. The system generally comprises, in various combinations, a gasification reactor vessel (or converter) having one or more processing zones and one or more plasma heat sources, a solid residue handling subsystem, a gas quality conditioning subsystem, as well as an integrated control subsystem for managing the overall energetics of the conversion of the carbonaceous feedstock to energy, as well as maintaining all aspects of the gasification processes at an optimal set point. The gasification system may also optionally comprise a heat recovery subsystem and / or a product gas regulating subsystem.
Owner:PLASCO ENERGY GROUP INC

Process for pyrolytic heat recovery enhanced with gasification of organic material

This invention is a reactor and a process for the conversion of organic waste material such as municipal trash, sewage, post-consumer refuse, and biomass to commercially salable materials.The invention produces the following:1. Maximum energy conversion from the organic material2. High volume consumption of the organic feed material3. Less pollution of gaseous products than prior art systems4. Solid residuals for disposal are minimal and non-hazardous.The conversion is accomplished by combining anaerobic gasification and pyrolysis of the feed organic material and making it into synthetic gas. The synthetic gas is a mixture of hydrocarbons (CxHy), hydrogen, and carbon monoxide with small amounts of carbon dioxide and nitrogen. An essential feature of the invention is a hot driver gas, devoid of free oxygen and rich in water, which supplies the entire thermal and chemical energy needed for the reactions. This hot driver gas is produced by complete sub-stoichiometric combustion of the fuel (CxHy) before it enters the reactor.
Owner:NICK PETER A +4

Gas Reformulating System Using Plasma Torch Heat

A method and apparatus is described for reformulating of an input gas from a gasification reaction into a reformulated gas. More specifically, a gas reformulating system having a gas reformulating chamber, one or more plasma torches, one or more oxygen source(s) inputs and control system is provided thereby allowing for the conversion of an input gas from a gasification reaction into a gas of desired composition.
Owner:PLASCO CONVERSION TECH INC

Multi-faceted gasifier and related methods

A gasifier is disclosed combining a fixed bed gasification section where coarse fuel is gasified and an entrained flow gasification section where fine fuel is gasified. The fixed bed section includes upper and lower sections. Coarse fuel is devolatilized in the upper fixed bed section and subjected to elevated temperatures sufficient to crack and destroy tars and oils in the effluent gases. The entrained flow gasification section is disposed in a lower plenum adjacent the lower fixed bed section. A plurality of injection ports are configured to introduce oxygen, steam, or air into different sections of the gasifier to control temperature and operating conditions. Activated carbon may be formed in the upper fixed bed section and in the entrained flow section. The activated carbon may be used as a sorbent to remove pollutants from the effluent gases. The gasifier may be used with various coarse and fine fuel feedstocks.
Owner:EMERY ENERGY

Gasification and steam methane reforming integrated polygeneration method and system

This invention is a process and system for providing hydrogen at a high level of reliability from a gasification system by integrating it with SMR. Carbonaceous feedstock such as petroleum coke or coal or biomass is gasified to co-produce SNG, fuel gas, hydrogen, power and steam in conjunction with hydrogen production through steam methane reforming. Carbon dioxide may also be recovered in this process. The integrated schemes are designed in a way that maximizes the reliability of production of high value products such as hydrogen through gasification and minimizes the impact of high natural gas prices on hydrogen production by SMR.
Owner:PRAXAIR TECH INC

Catalytic steam gasification process with recovery and recycle of alkali metal compounds

A high efficiency gasification process for converting carbonaceous solids to methane and apparatus for its practice are described. The process includes reacting steam and carbonaceous solids comprising ash in the presence of alkali metal catalyst in a gasification reactor to produce combustible gases and char particles comprising ash and alkali metal catalyst constituents, treating a stream of such char particles in an alkali metal catalyst recovery system to recover the catalyst constituents as alkali metal compounds, and recycling such recovered compounds. Within the alkali metal catalyst recovery system the process includes quenching the stream of char particles with water whereby such particles are cooled and fractured, dissolving soluble alkali metal catalyst constituents from the fractured solids to form a first alkali metal catalyst solution and washed solids, optionally reacting the washed solids in alkaline solution to form a second alkali metal catalyst solution, upgrading said first and optional second alkali solution to recover the alkali metal catalyst constituents as said alkali metal compounds.
Owner:SURE CHAMPION INVESTMENT LTD

Hot solids gasifier with CO2 removal and hydrogen production

A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction. The hot CaCO3 is discharged to the calciner 42, the heat content of the CaCO3 being used to strip the CO2 from the CaO in an endothermic reaction in the calciner, with the CaO being discharged from the calciner 42 to the shift reactor 54.
Owner:AIR PROD & CHEM INC +1

System for hot solids combustion and gasification

In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS / gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4 / gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS / gas outlet 26 and includes a product gas and a CaS / gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4 / gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66. The chemical looping system is in fluid communication with at least a portion of an existing power generation system.
Owner:AIR PROD & CHEM INC +1

Reduced-Emission Gasification and Oxidation of Hydrocarbon Materials for Liquid Fuel Production

A system and process are disclosed for the controlled combustion of a wide variety of hydrocarbon feedstocks to produce thermal energy, liquid fuels, and other valuable products with little or no emissions. The hydrocarbon feeds, such as coal and biomass, are first gasified and then oxidized in a two-chamber system / process using pure oxygen rather than ambient air. A portion of the intermediate gases generated in the system / process are sent to a Fischer-Tropsch synthesis process for conversion into diesel fuel and other desired liquid hydrocarbons. The remaining intermediate gases are circulated and recycled through each of the gasification / oxidation chambers in order to maximize energy production. The energy produced through the system / process is used to generate steam and produce power through conventional steam turbine technology. In addition to the release of heat energy, the hydrocarbon fuels are oxidized to the pure product compounds of water and carbon dioxide, which are subsequently purified and marketed. The system / process minimizes environmental emissions.
Owner:CLARK STEVE L

Producing Liquid Fuel from Organic Material such as Biomass and Waste Residues

A process for producing liquid fuel from biomass feed stock comprising feeding a biomass feedstock into a one stage atmospheric pressure thermo-catalytic plasma gasifier, contacting the feedstock with oxygen or steam or both to obtain a syngas stream; splitting the syngas stream into first and second streams; conveying the first stream to a water gas shift reactor for producing a modified syngas stream containing CO and hydrogen; the second stream bypassing the water gas shift reactor and being added to the modified syngas steam; optionally reforming natural gas by steam methane reforming to produce a synthetic gas and optionally adding the synthetic gas to the water gas shift reactor; thereby obtaining a syngas having a H2:CO ratio of about 1:1 to about 2:1; subjecting the syngas to a Fischer Tropsch reaction thereby producing a wax product; and subjecting the product to a hydrogen cracking process to produce liquid fuel; and apparatus therefore.
Owner:SOLENA FUELS CORP

Gasification reactor

A gasification reactor comprising a vessel (1), provided at its upper end with a downwardly directed burner (2), and provided with supply conduits for an oxidizer gas (3), a carbonaceous feed (4) and a moderator gas (5), a combustion chamber (6) in the upper half of the vessel provided with a product gas outlet (7) at its bottom end and an opening for the outlet of the burner (2) at its top end, wherein between the wall of the combustion chamber (6) and the wall of the vessel (1) an annular space (9) is provided, and wherein the wall of the combustion chamber (6) comprises an arrangement of interconnected parallel arranged tubes (10) resulting in a substantially gas-tight wall running from a common lower arranged distributor (12) to a higher arranged common header (11), said distributor (12) provided with a cooling water supply conduit (14) and said header (11) provided with a steam discharge conduit (13) and wherein the steam discharge conduit (13) and the water supply conduit (14) are fluidly connected to a steam drum (29) and wherein the steam drum (29) is provided with a supply conduit (32) for fresh water and wherein the steam drum (29) is positioned at a higher elevation than the common header (11).
Owner:AIR PROD & CHEM INC

Method and device for pyrolyzing and gasifying organic substances or substance mixtures

An apparatus for pyrolysis and gasification of organic substances and mixtures thereof is provided with a pyrolysis reactor (1), a fluidized-bed firing (3) for pyrolysis residue, a reaction zone (2) for the pyrolysis gases (13) and circulating fluidized-bed material (35). The pyrolysis reactor (1) has a sluice for introducing application material (10) thereinto. An inlet for the fluidized-bed material (35) is disposed next to the combustion fluidized bed (3). Transport apparatus (14) for mixture of solid pyrolysis residue and circulating fluidized bed material (35) is disposed at or near a bottom of the fluidized bed (3) and lower end of the pyrolysis reactor (1). An overflow is situated at or near the top of the fluidized bed (3) while a heat transfer member is positioned within the reaction zone (2).
Owner:HERHOF UMWELTTECHN

Efficiency of gasification processes

Systems and processes for producing syngas and power therefrom are provided. One or more feedstocks and one or more oxidants can be combined in a fluidized reaction zone operated at a temperature from 550° C. to 1,050° C. to provide a syngas. Heat can be indirectly exchanged in a first zone from the syngas to a condensate to provide steam. Heat can also be indirectly exchanged in a second zone from the syngas to the steam to provide superheated steam. Heat can then be indirectly exchanged in a third zone from the syngas to provide a cooled syngas and the condensate for the first zone. At least a portion of the superheated steam can be directly supplied to one or more steam turbines to produce power.
Owner:KELLOGG BROWN & ROOT LLC

Catalytic partial oxidation processor with heat exchanger for converting hydrocarbon fuels to syngas for use in fuel cells and method

InactiveUS20050081444A1Reduce the possibilitySafe, reliable and efficient operationCatalytic gas-gas reactionHydrogenPartial oxidationHydrogen
A catalytic partial oxidation processor comprising at least one catalytic partial oxidation reactor disposed in a shell having an inlet and outlet such that heat from partial oxidation in the reactor transfers from the reactor to heat exchange fluid in the shell. The heat transfer serves to keep the precatalyst zone of the partial oxidation reactor cool and the post catalyst section of the partial oxidation reactor hot while also providing an efficient heat recovery system. A system for producing electric power comprises such a catalytic partial oxidation processor and a fuel cell disposed for receiving the exit gas stream and consuming the hydrogen to produce electric power. Corresponding methods are also disclosed.
Owner:GENERAL ELECTRIC CO

Reduced-emission gasification and oxidation of hydrocarbon materials for hydrogen and oxygen extraction

A system and process for maximizing the generation of marketable products from a variety of hydrocarbon feedstocks. The hydrocarbon feedstocks are first gasified and then oxidized in a two-chamber system and process using oxygen gas rather than ambient air. Intermediate gases generated in the system and process are recirculated and recycled to the gasification and oxidation chambers in order to maximize both energy generation and the resulting stoichiometric reaction products. The energy produced through the system and process is used to generate steam and produce power through conventional steam turbine technology. In addition to the release of heat energy, the hydrocarbon feedstocks are oxidized to the pure product compounds of water and carbon dioxide. The carbon dioxide is subsequently purified and marketed. The water recovered from the system and process is collected and electrolyzed to generate oxygen and hydrogen gases. These gases are separated using conventional gas separation technologies and also marketed. The system and process minimizes environmental emissions.
Owner:CLARK STEVE L

Methods and Apparatus for Solid Carbonaceous Materials Synthesis Gas Generation

Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas (9), and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas (9), and recycled contaminants. Synthesis gas generation may involve predetermining a desired synthesis gas for output and creating high yields of such a predetermined desired synthesis gas.
Owner:THERMOTEK

Process for humidifying synthesis gas

Disclosed is a process for humidifying syngas to achieve a water to carbon monoxide molar ratio in the product syngas within a desired range and in which the molar ratio which can be varied over time in response to changes in downstream syngas requirements. The raw syngas is produced by reacting a carbonaceous material with oxygen, water, or carbon dioxide and can be combined with a diluent to produce a diluted syngas stream which can be cooled and contacted with liquid water to give a humidified syngas. The H2O:CO molar ratio of the humidified syngas may be adjusted in response to time-varying downstream syngas requirements by changing the amount and / or temperature of the diluent that is combined with the raw syngas stream, by adjusting quench and heat exchange conditions, or a combination thereof. The application of the process to the coproduction of chemicals and power are also disclosed.
Owner:EASTMAN CHEM CO

Production of stable biomass pyrolysis oils using fractional catalytic pyrolysis

Methods for fractional catalytic pyrolysis which allow for conversion of biomass into a slate of desired products without the need for post-pyrolysis separation are described. The methods involve use of a fluid catalytic bed which is maintained at a suitable pyrolysis temperature. Biomass is added to the catalytic bed, preferably while entrained in a non-reactive gas such as nitrogen, causing the biomass to become pyrolyzed and forming the desired products in vapor and gas forms, allowing the desired products to be easily separated.
Owner:VIRGINIA TECH INTPROP INC

Energy efficient system and process for the continuous production of fuels and energy from syngas

InactiveUS20100175320A1Maximizes carbon conversionMaximize efficiencyEngine fuctionsBiofuelsChilled waterLiquid fuel
A system and apparatus is provided that maximizes mass and energy conversion efficiencies in an integrated thermochemical process for the conversion of fossil fuel or renewable biomass to synthesis gas. The system combines gasification, catalytic conversion of gas to liquid, electricity generation, steam and chilled water generation with a system controller to maximize the conversion efficiency from syngas to merchantable products over the efficiency of syngas alone burned as a fuel. A clean synthesis gas stream is introduced into a catalytic reactor that utilizes specially formulated catalysts to generate liquid fuel from CO and H2 while concentrating CH4 and other combustible, but non-reactive gases in the syngas product stream. The methane rich stream is introduced into an engine for the production of electricity and heat while the unreacted CO and H2 can be recycled to produce additional liquid fuel. Excess heat can be used for other co-located processes and facilities.
Owner:GREYROCK ENERGY INC
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