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4957results about "Granular/pulverulent flues gasification" patented technology
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Mild catalytic steam gasification process
InactiveUS20070000177A1Great carbon conversionLittle additional treatmentGasification processes detailsCombined combustion mitigationMaceralAlkali metal
The present invention provides an improved alkali metal catalyzed steam gasification process that utilizes a CO2 trap material and / or a mineral binder material within the gasifier. The process optimally achieves over 90% carbon conversion with over 80% yield of methane. The raw gas product can be used directly as fuel. The catalyst can be recovered from the solid purge and recycled to the gasifier and / or the CO2 trap can be regenerated and recycled to the gasifier.
Owner:SURE CHAMPION INVESTMENT LTD
Biomass Char Compositions for Catalytic Gasification
InactiveUS20090217575A1Efficient utilization of carbonEfficient comprehensive utilizationProductsReagentsParticulatesHydrogen
Particulate compositions are described comprising an intimate mixture of a biomass char producedfrom the combustion of a biomass, such as switchgrass or hybrid poplar, with at least a second carbonaceous material, such as petroleum coke or coal, and, optionally a gasification catalyst, for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
Hydrogen production from carbonaceous material
InactiveUS6790430B1Avoid the needCalcium/strontium/barium carbonatesGas turbine plantsCalcinationExothermic reaction
Owner:BOARD OF SUPERVISORS OF LOUISIANA STATE UNIV & AGRI & MECHANICAL COLLEGE +1
Combustion looping using composite oxygen carriers
ActiveUS20050175533A1Increase surface areaImprove energy conversion efficiencyHydrogen productionIndirect carbon-dioxide mitigationHydrogenCombustion
A method for producing hydrogen gas is provided and comprises reducing a metal oxide in a reduction reaction between a carbon-based fuel and a metal oxide to provide a reduced metal or metal oxide having a lower oxidation state, and oxidizing the reduced metal or metal oxide to produce hydrogen and a metal oxide having a higher oxidation state. The metal or metal oxide is provided in the form of a porous composite of a ceramic material containing the metal or metal oxide. The porous composite may comprise either a monolith, pellets, or particles.
Owner:OHIO STATE INNOVATION FOUND
Catalyst-Loaded Coal Compositions, Methods of Making and Use
ActiveUS20090048476A1Efficient and high-yielding gasificationHigh yield productionCatalyst regeneration/reactivationSolid fuelsPtru catalystCoal matrix
The present invention relates to catalyst-loaded coal compositions having a moisture content of less than about 6 wt %, a process for the preparation of catalyst-loaded coal compositions, and an integrated process for the gasification of the catalyst-loaded coal compositions. The catalyst-loaded coal compositions can be prepared by a diffusive catalyst loading process that provides for a highly dispersed catalyst that is predominantly associated with the coal matrix, such as by ion-exchange.
Owner:SURE CHAMPION INVESTMENT LTD
Apparatus for converting coal to hydrocarbons
InactiveUS6013158ALess producedLow costCombustible gas coke oven heatingDirect heating destructive distillationParticulatesSuspended particles
An apparatus for forming liquid hydrocarbons from solid coal. The coal is pulverized to provide a particulate coal feed, which is then extruded to provide a hollow tube of compressed coal supported inside of a support tube. A clay feed is extruded to provide a hollow tube of compressed clay supported inside of the coal tube and a combustible fuel is burned inside of the clay tube. The temperature of combustion is sufficient to fire the extruded clay and pyrolyze the extruded coal to produce hydrocarbon gases and coal char. The support tube has holes for releasing the hydrocarbon gases, which contain suspended particles formed during combustion. The suspended particles are removed from the hydrocarbon gases to provide clean gases, which are passed through an ionizing chamber to ionize at least a portion thereof. The ionized gases are then passed through a magnetic field to separate them from each other according to their molecular weight. Selected portions of at least some of the separated gases are mixed, and the mixed gases are cooled to provide at least one liquid hydrocarbon product of predetermined composition. Portions of the separated gases may also be mixed with the coal char and other input streams, such as waste plastics, and further treated to provide other hydrocarbon products.
Owner:WOOTTEN WILLIAM A
Method and apparatus for producing synthesis gas from carbonaceous materials
A method of producing syn gas from biomass or other carbonaceous material utilizes a controlled devolatilization reaction in which the temperature of the feed material is maintained at less than 450° F. until most available oxygen is consumed. This minimizes pyrolysis of the feed material. The method and apparatus utilizes the formed synthesis gas to provide the energy for the necessary gasification. This provides for a high purity syn gas and avoids production of slag.
Owner:JBK EXTRACTIONS
Catalytic steam gasification process with recovery and recycle of alkali metal compounds
ActiveUS20070277437A1Promote leachingLarge specific surface areaHydrogenGas modification by gas mixingCompound aAlkali metal
A high efficiency gasification process for converting carbonaceous solids to methane and apparatus for its practice are described. The process includes reacting steam and carbonaceous solids comprising ash in the presence of alkali metal catalyst in a gasification reactor to produce combustible gases and char particles comprising ash and alkali metal catalyst constituents, treating a stream of such char particles in an alkali metal catalyst recovery system to recover the catalyst constituents as alkali metal compounds, and recycling such recovered compounds. Within the alkali metal catalyst recovery system the process includes quenching the stream of char particles with water whereby such particles are cooled and fractured, dissolving soluble alkali metal catalyst constituents from the fractured solids to form a first alkali metal catalyst solution and washed solids, optionally reacting the washed solids in alkaline solution to form a second alkali metal catalyst solution, upgrading said first and optional second alkali solution to recover the alkali metal catalyst constituents as said alkali metal compounds.
Owner:SURE CHAMPION INVESTMENT LTD
Pressure swing reforming
Synthesis gas is produced though a cyclic method where the first step of the cycle includes reforming a hydrocarbon feed over a catalyst to synthesis gas in a first zone of a bed and the second step reheats this first zone. A hydrocarbon feed is introduced to a bed along with CO2 and optionally steam where it is reformed into synthesis gas. The synthesis gas is collected at a second zone of the bed and an oxygen-containing gas is then introduced to this second zone of the bed and combusted with a fuel, thereby reheating the first zone to sufficient reforming temperatures. Additionally, a non-combusting gas can also be introduced to the second zone to move heat from the second zone to the first zone.
Owner:EXXON RES & ENG CO
Steam Generating Slurry Gasifier for the Catalytic Gasification of a Carbonaceous Feedstock
Steam generating gasification reactors for providing high-pressure and high-temperature steam for catalytic gasification of a carbonaceous feedstock can be based on oxygen blown gasification reactors adapted for processing a slurry feedstock comprising at least 40% water. The exhaust from the slurry gasifier comprises at least steam, carbon monoxide and hydrogen. The slurry composition and the oxygen to fuel ratio can be varied to control the ratio of carbonaceous gases in the generator exhaust. By directing substantially all of exhaust gases produced from the slurry gasification reactor through the catalytic gasifier and subsequent gas separation and sequestration processes, a greatly higher energy efficiency and decreased carbon footprint can be realized.
Owner:SURE CHAMPION INVESTMENT LTD
Carbonaceous Fuels and Processes for Making and Using Them
The present invention provides carbonaceous fuels and processes for making them. Moreover, the invention also relates to processes using the carbonaceous fuels in the production of cement products. One embodiment of the invention is a carbonaceous fuel comprising (a) unconverted fines of a carbonaceous feedstock, the carbonaceous feedstock having an ash content of greater than 1%, the fines having an average particle size less than about 45 μm; and (b) a char residue formed by catalytic gasification of the carbonaceous feedstock, the char residue having an ash content of greater than about 30%, wherein the ash includes at least one aluminum-containing compound or silicon-containing compound; and having a weight ratio of fines to char residue in the range of about 4:1 to about 1:4, and a total dry basis wt % of carbon of least about 40%. Another embodiment of the invention is a process of making a cement product comprising: (a) providing a carbonaceous fuel as described above; (b) passing the carbonaceous fuel into a cement-making zone; and (c) at least partially combusting the carbonaceous fuel to provide heat for a cement producing reaction within the cement-making zone.
Owner:SURE CHAMPION INVESTMENT LTD
Conversion of petroleum residua to methane
InactiveUS6955695B2Eliminate needReduce usageThermal non-catalytic crackingElectrolysis componentsParticulatesGas phase
This invention discloses improvements on previous inventions for catalytic conversion of coal and steam to methane. The disclosed improvements permit conversion of petroleum residua or heavy crude petroleum to methane and carbon dioxide such that nearly all of the heating value of the converted hydrocarbons is recovered as heating value of the product methane. The liquid feed is distributed over a fluidized solid particulate catalyst containing alkali metal and carbon as petroleum coke at elevated temperature and pressure from the lower stage and transported to the upper stage of a two-stage reactor. Particulate solids containing carbon and alkali metal are circulated between the two stages. Superheated steam and recycled hydrogen and carbon monoxide are fed to the lower stage, fluidizing the particulate solids and gasifying some of the carbon. The gas phase from the lower stage passes through the upper stage, completing the reaction of the gas phase.
Owner:PETRO2020
Petroleum Coke Compositions for Catalytic Gasification
InactiveUS20090166588A1Improve efficiencyReduce moisture contentOther chemical processesMixing methodsPtru catalystThermodynamics
Particulate compositions are described comprising an intimate mixture of a petroleum coke, coal and a gasification catalyst, where the gasification catalyst is loaded onto at least the coal for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
ActiveUS20070099038A1High hydrogen contentFuel cells groupingHydrogen separation using solid contactPetroleum cokePetroleum
The process of the invention converts carbonaceous feedstock such as coal, hydrocarbon oil, natural gas, petroleum coke, oil shale, carbonaceous-containing waste oil, carbonaceous-containing medical waste, carbonaceous-containing military waste, carbonaceous-containing industrial waste, carbonaceous-containing medical waste, carbonaceous-containing sewage sludge and municipal solid waste, carbonaceous-containing agricultural waste, carbonaceous-containing biomass, biological and biochemical waste, and mixtures thereof into electrical energy without the production of unwanted greenhouse emissions. The process uses a steam / CO2 reformer operating in the exit range of at least 700° to about 1600° C. (1300-2900°0 F.) to convert the carbonaceous feedstock and a greenhouse gas stream into a synthesis gas comprising mostly carbon monoxide and hydrogen that contains poisons and the compounds that poison fuel cells. The syngas is sent to an interface zone to remove these poisons and other fouling compounds that are electrochemically oxidized in an electricity-producing fuel cell into an exit gas comprising carbon dioxide and water.
Owner:RAVEN SR INC
Coal Compositions for Catalytic Gasification
Particulate compositions are described comprising an intimate mixture of a coal and a gasification catalyst. The particulate compositions are gasified in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia and other higher hydrocarbons. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
Processes for Making Syngas-Derived Products
The present invention provides processes for making syngas-derived products. For example, one aspect of the present invention provides a process for making a syngas-derived product, the process comprising (a) providing a carbonaceous feedstock; (b) converting the carbonaceous feedstock in a syngas formation zone at least in part to a synthesis gas stream comprising hydrogen and carbon monoxide; (c) conveying the synthesis gas stream to a syngas reaction zone; (d) reacting the synthesis gas stream in the syngas reaction zone to form the syngas-derived product and heat energy, a combustible tail gas mixture, or both; (e) recovering the syngas-derived product; and (f) recovering the heat energy formed from the reaction of the synthesis gas stream, burning the combustible tail gas mixture to form heat energy, or both.
Owner:SURE CHAMPION INVESTMENT LTD
Biomass Compositions for Catalytic Gasification
Particulate compositions are described comprising an intimate mixture of a biomass, such as switchgrass or hybrid poplar, a non-biomass carbonaceous material, such as petroleum coke or coal, and a gasification catalyst, where the gasification catalyst is loaded onto at least one of the biomass or non-biomass for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
Co-Feed of Biomass as Source of Makeup Catalysts for Catalytic Coal Gasification
Continuous processes are provided for converting a carbonaceous feedstock comprising biomass containing alkali metal, non-biomass components, and at least one gasification catalyst including an alkali metal recovered from solid char, into a plurality of gaseous products including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons.
Owner:SURE CHAMPION INVESTMENT LTD
Catalytic Gasification Particulate Compositions
ActiveUS20090229182A1Efficient use ofBiofuelsGas modification by gas mixingPtru catalystPetroleum coke
Particulate compositions are described comprising a carbonaceous material, such as petroleum coke and / or coal, treated or otherwise associated with a gasification catalyst, where the catalyst is at least in part derived from a leachate from a biomass char, for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
Carbonaceous Fines Recycle
ActiveUS20090217589A1Sufficient amountHydrogen productionCarbon monoxideParticulatesParticle composition
Owner:SURE CHAMPION INVESTMENT LTD
Low Temperature Gasification Facility with a Horizontally Oriented Gasifier
A low-temperature gasification system comprising a horizontally oriented gasifier is provided that optimizes the extraction of gaseous molecules from carbonaceous feedstock while minimizing waste heat. The system comprises a plurality of integrated subsystems that work together to convert municipal solid waste (MSW) into electricity. The subsystems comprised by the low-temperature gasification system are: a Municipal Solid Waste Handling System; a Plastics Handling System; a Horizontally Oriented Gasifier with Lateral Transfer Units System; a Gas Reformulating System; a Heat Recycling System; a Gas Conditioning System; a Residue Conditioning System; a Gas Homogenization System and a Control System.
Owner:PLASCO CONVERSION TECH INC
System and methods for improved emission control of internal combustion engines using pulsed fuel flow
InactiveUS7082753B2Save oilReducing greenhouse gas emissionExhaust apparatusCombustion enginesPartial oxidationExternal combustion engine
The present invention provides systems and methods to improve the performance and emission control of internal combustion engines equipped with nitrogen oxides storage-reduction (“NSR”) emission control systems. The system generally includes a NSR catalyst, a fuel processor located upstream of the NSR catalyst, and at least one fuel injection port. The fuel processor converts a fuel into a reducing gas mixture comprising CO and H2. The reducing gas mixture is then fed into the NSR catalyst, where it regenerates the NSR adsorbent, reduces the NOx to nitrogen, and optionally periodically desulfates the NSR catalyst. The fuel processor generally includes one or more catalysts, which facilitate reactions such as combustion, partial oxidation, and / or reforming and help consume excess oxygen present in an engine exhaust stream. The methods of the present invention provide for NSR catalyst adsorbent regeneration using pulsed fuel flow. Control strategies are also provided.
Owner:INT ENGINE INTPROP CO LLC
System and process for producing synthetic liquid hydrocarbon
ActiveUS20080115415A1Improve carbon efficiencyReduce area requirementsMuffle furnacesCarbon compoundsOxygenElectrolysis of water
Production of synthetic liquid hydrocarbon fuel from carbon containing moieties such as biomass, coal, methane, naphtha as a carbon source and hydrogen from a carbon-free energy source is disclosed. The biomass can be fed to a gasifier along with hydrogen, oxygen, steam and recycled carbon dioxide. The synthesis gas from the gasifier exhaust is sent to a liquid hydrocarbon conversion reactor to form liquid hydrocarbon molecules. Unreacted CO & H2 can be recycled to the gasifier along with CO2 from the liquid hydrocarbon conversion reactor system. Hydrogen can be obtained from electrolysis of water, thermo-chemical cycles or directly by using energy from carbon-free energy sources.
Owner:PURDUE RES FOUND INC
Method and Apparatus for Automated, Modular, Biomass Power Generation
ActiveUS20070006528A1Increasing fuel-bed bulk densityRestrict movementHydrogenDispersed particle filtrationElectric power systemFossil fuel
Method and apparatus for generating a low tar, renewable fuel gas from biomass and using it in other energy conversion devices, many of which were designed for use with gaseous and liquid fossil fuels. An automated, downdraft gasifier incorporates extensive air injection into the char bed to maintain the conditions that promote the destruction of residual tars. The resulting fuel gas and entrained char and ash are cooled in a special heat exchanger, and then continuously cleaned in a filter prior to usage in standalone as well as networked power systems.
Owner:COMMUNITY POWER CORP
Rapid solar-thermal conversion of biomass to syngas
ActiveUS20080086946A1Improve reaction kineticsWide rangeElectrical coke oven heatingSolar heating energySyngasReactor design
Methods for carrying out high temperature reactions such as biomass pyrolysis or gasification using solar energy. The biomass particles are rapidly heated in a solar thermal entrainment reactor. The residence time of the particles in the reactor can be 5 seconds or less. The biomass particles may be directly or indirectly heated depending on the reactor design. Metal oxide particles can be fed into the reactor concurrently with the biomass particles, allowing carbothermic reduction of the metal oxide particles by biomass pyrolysis products. The reduced metal oxide particles can be reacted with steam to produce hydrogen in a subsequent process step.
Owner:UNIV OF COLORADO THE REGENTS OF
Gasification system with processed feedstock/char conversion and gas reformulation
ActiveUS20110036014A1Gasifier mechanical detailsEnergy based wastewater treatmentVitrificationSyngas
The invention provides a system designed for the complete conversion of carbonaceous feedstock into syngas and slag. The system comprises a primary chamber for the volatilization of feedstock generating a primary chamber gas (an offgas); a secondary chamber for the further conversion of processed feedstock to a secondary chamber gas (a syngas) and a residue; a gas-reformulating zone for processing gas generated within one or more of the chambers; and a melting chamber for vitrifying residue. The primary chamber comprises direct or indirect feedstock additive capabilities in order to adjust the carbon content of the feedstock. The system also comprises a control system for use with the gasification system to monitor and regulate the different stages of the process to ensure the efficient and complete conversion of the carbonaceous feedstock into a syngas product.
Owner:PLASCO CONVERSION TECH INC
Catalytic membrane reactor and method for production of synthesis gas
InactiveUS20080169449A1High oxygen fluxHydrogenSemi-permeable membranesSulfur containingPhotochemistry
A solid state membrane for a reforming reactor is disclosed which comprises at least one oxygen anion-conducting oxide selected from the group consisting of hexaaluminates, cerates, perovskites, and other mixed metal oxides that are able to adsorb and dissociate molecular oxygen. The membrane adsorbs and dissociates molecular oxygen into highly active atomic oxygen and allows oxygen anions to diffuse through the membrane, to provide high local concentration of oxygen to deter formation and deposition of carbon on reformer walls. Embodiments of the membrane also have catalytic activity for reforming a hydrocarbon fuel to synthesis gas. Also disclosed are a reformer having an inner wall containing the new membrane, and a process of reforming a hydrocarbon feed, such as a high sulfur-containing diesel fuel, to produce synthesis gas, suitable for use in fuel cells.
Owner:ELTRON RES
Methods and apparatus for producing syngas and alcohols
The present invention features methods and apparatus for the pyrolysis or torrefaction of a carbon-containing feedstock before it is converted to syngas. In some embodiments, biomass is first pretreated by torrefaction and / or pyrolysis, followed by devolatilization and / or steam reforming to produce syngas. Various mixtures of such pretreated biomass, combined with fresh biomass, can be employed to produce syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.
Owner:RANGE FUELS INC
System integration of a steam reformer and gas turbine
A novel process and apparatus for power generation from biomass and other carbonaceous feedstocks are provided. The process integrates a pulse combustor steam reformer with a gas turbine to generate electricity such that (i) efficiency is higher than those of conventional and current advanced power systems, (ii) emissions are lower than those proposed in the new environmental regulations, and (iii) performance is comparable to that of combined cycle, even though a bottoming cycle is not included here. The pulse combustor steam reformer generates a hydrogen-rich, medium-Btu fuel gas that is fired in a gas turbine to generate electricity. The apparatus may be configured to produce only power or combined heat and power.
Owner:THERMOCHEM RECOVERY INT
Conversion of carbonaceous materials to synthetic natural gas by pyrolysis, reforming, and methanation
InactiveUS20080016769A1Reduce the temperatureCombustible gas chemical modificationProductsSyngasSteam reforming
The production of synthetic natural gas from a carbonaceous material, preferably a biomass material, such as wood. The carbonaceous material is first pyrolyzed, then subjected to steam reforming to produce a syngas, which is then passed to several clean-up steps then to a methanation zone to produce synthetic natural gas.
Owner:CLEAN ENERGY LLC
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