2110 results about "Refinery" patented technology

The present invention relates to methods for separating and recovering ethane, propane and heavier components from a feed gas, e.g. raw natural gas or a refinery or petroleum plant gas stream or a petrochemical plant gas stream. These methods employ a common new concept which is the use of the turbo-expander shaft compressor to generate the reflux requirement for the cryogenic absorber or distillation columns. The power of the turbo-expander which is absorbed by the shaft compressor is always high enough so that reflux generation by a specific gas compression through the expander shaft compressor and subsequent cooling, condensation and sub-cooling can always be easily maintained. The present invention allows for higher cryogenic absorber pressure and a lower demethanizer / de-ethanizer column pressure thus eliminating the common cryogenic pump at absorber bottom. The present invention ultimately results in a lower residue compression and utilities consumption. The present invention as such allows for a higher 99+% recovery of NGL from the feed gas stream.

An integrated refining process for the production of high quality gasoline blending components from low value components is disclosed. In addition there is disclosed a method of improving the operating efficiency of a refinery by reducing fuel gas production and simultaneously producing high quality gasoline blending components of low volatility. The processes involve the alkylation of a refinery stream containing pentane with ethylene using an ionic liquid catalyst.

A novel clostridia bacterial species (Clostridium ragsdalei, ATCC BAA-622, “P11”) is provided. P11 is capable of synthesizing, from waste gases, products which are useful as biofuel. In particular, P11 can convert CO to ethanol. Thus, this novel bacterium transforms waste gases (e.g. syngas and refinery wastes) into useful products. P11 also catalyzes the production of acetate.

Production of biological diesel oil by integrated hydrogenation is carried out by mixing straight-run diesel oil with soya-bean, hydrogenation refinery reacting at 3.0-8.0MPa and 250-400degree and under existence of catalyst and converting vegetable oil into biological diesel oil. It's simple and cheap.

Systems, methods and devices are provided for detecting airborne particulates and / or gases at remote oil and natural gas sites, such as wells, and / or processing and refinery plants. One such system comprises an unmanned aerial vehicle (UAV), such as a drone aircraft, configured for aerial dispatch to the remote site and wireless connection to an external processor, cloud apparatus or the like. The UAV includes one or more on-board sensors configured to detect airborne particulates or gases, such as methane gas, hydrogen sulfide, hydrocarbons, weather conditions, ground-based elements or compounds or the like. The on-board sensors may comprise light transmitters, such as lasers, configured for transmitting light or laser pulses into the ambient environment around the remote site and detecting backscatter to detect the concentration and / or velocity vector(s) of the airborne particulates or gases. The UAV is further configured to wirelessly transmit data associated with the airborne particulates or gases to the external processor or cloud apparatus in real-time.

The invention discloses a separating refinery catalytic dry gas method with middle cold oil absorptive method in separating refinery catalytic dry gas technical domain, which comprises the following steps: compressing; stripping acid gas; drying; purifying; absorbing; desorbing; reclaiming cold energy; crude-separating. This invention possesses cheap cost, low lost, simple operation, little investment and low energy consumption, which can get C2 fraction and ethane.

Thousands of process and equipment measurements are gathered by the modern digital process control systems that are deployed in refineries and chemical plants. Several years of these data are historized in databases for analysis and reporting. These databases can be mined for the data patterns that occur during normal operation and those patterns used to determine when the process is behaving abnormally. These normal operating patterns are represented by sets of models. These models include simple engineering equations, which express known relationships that should be true during normal operations and multivariate statistical models based on a variation of principle component analysis. Equipment and process problems can be detected by comparing the data gathered on a minute by minute basis to predictions from these models of normal operation. The deviation between the expected pattern in the process operating data and the actual data pattern are interpreted by fuzzy Petri nets to determine the normality of the process operations. This is then used to help the operator localize and diagnose the root cause of the problem.

Methods of making glucose and / or furfural from biomass require one or more supercritical fluids that may be used to process biomass, cellulose from the biomass, and / or xylose from the biomass. Examples of supercritical fluids for use in processing biomass include ethanol, water, and carbon dioxide at a temperature and pressure above the critical points for ethanol and carbon dioxide but at a temperature and / or pressure below that of the critical point for water. A supercritical fluid containing carbon dioxide and water may be used to convert cellulose to glucose or convert xylose to furfural. The fluid has a temperature and pressure above the critical point of carbon dioxide, but at least one of the temperature and pressure is below the critical point for water.

A method of producing a hydrogen product stream in which a steam stream is reacted with a hydrocarbon containing stream within a steam methane reformer. The resulting product stream is subjected to a water gas shift reaction and then to pressure swing adsorption to produce the hydrogen product stream. The hydrocarbon stream is alternatively formed from a first type of feed stream made up of natural gas, refinery off-gas, naphtha or synthetic natural gas or combinations thereof and a second type that is additionally made up of a hydrogen and carbon monoxide containing gas. During use of both of the types of feed streams, the flow rate of the steam stream is not substantially changed and reformer exit temperatures of both the reactant and the flue gas side are held essentially constant.

A process for the production of a high quality gasoline blending components from refinery process streams by the alkylation of light isoparaffins with olefins using an ionic liquid catalyst is disclosed. The process includes reacting a refinery stream containing isopentane and / or isobutane with a refinery stream containing ethylene and / or propylene and butylenes under alkylation conditions in the presence of a chloroaluminate ionic liquid catalyst comprising a hydrocarbyl substituted pyridinium halide or a hydrocarbyl substituted imidazolium halide of the general formulas A and B, respectively. Where R=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a halide and preferably a chloride, and R1 and R2=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and where R1 and R2 may or may not be the same.

Porous-material-supported polymer sorbents and process for removal of undesirable gases such as H2S, COS, CO2, N2O, NO, NO2, SO2, SO3, HCl, HF, HCN, NH3, H2O, C2H5OH, CH3OH, HCHO, CHCl3, CH2Cl2, CH3Cl, CS2, C4H4S, CH3SH, and CH3—S—CH3 from various gas streams such as natural gas, coal / biomass gasification gas, biogas, landfill gas, coal mine gas, ammonia syngas, H2 and oxo-syngas, Fe ore reduction gas, reformate gas, refinery process gases, indoor air, fuel cell anode fuel gas and cathode air are disclosed. The sorbents have numerous advantages such as high breakthrough capacity, high sorption / desorption rates, little or no corrosive effect and are easily regenerated. The sorbents may be prepared by loading H2S—, COS—, CO2—, N2O, NO—, NO2—, SO2—, SO3—, HCl—, HF—, HCN—, NH3—, H2O—, C2H5OH—, CH3OH—, HCHO—, CHCl3—, CH2Cl2—, CH3Cl—, CS2—, C4H4S—, CH3SH—, CH3—S—CH3-philic polymer(s) or mixtures thereof, as well as any one or more of H2S—, COS—, CO2—, N2O, NO—, NO2—, SO2—, SO3—, HCl—, HF—, HCN—, NH3—, H2O—, C2H5OH—, CH3OH—, HCHO—, CHCl3—, CH2Cl2—, CH3Cl—, CS2—, C4H4S—, CH3SH—, CH3—S—CH3-philic compound(s) or mixtures thereof on to porous materials such as mesoporous, microporous or macroporous materials. The sorbents may be employed in processes such as one-stage and multi-stage processes to remove and recover H2S, COS, CO2, N2O, NO, NO2, SO2, SO3, HCl, HF, HCN, NH3, H2O, C2H5OH, CH3OH, HCHO, CHCl3, CH2Cl2, CH3Cl, CS2, C4H4S, CH3SH and CH3—S—CH3 from gas streams by use of, such as, fixed-bed sorbers, fluidized-bed sorbers, moving-bed sorbers, and rotating-bed sorbers.

An integrated refining process for the production of high quality gasoline blending components from low value components is disclosed. In addition there is disclosed a method of improving the operating efficiency of a refinery by reducing fuel gas production and simultaneously producing high quality gasoline blending components of low volatility. The processes involve the alkylation of a refinery stream containing pentane with ethylene using an ionic liquid catalyst.

A method and system to produce biodiesel from a combination of corn (maize) and other agro feedstock may be simarouba, mahua, rice, pongamia etc. Germ is separated (either by wet process or dry process) from corn, crude corn oil extracted from germ and corn starch milk / slurry is heated and cooked in jet cooker to about 105 degree Celsius, enzymes added to convert starch into fermentable sugars in liquification and saccharification process and rapidly cooled down to about 30 degree Celsius. Simarouba fruits syrup, mahua syrup is mixed with corn starch milk (after saccharification). When yeast is added the fermentation takes place for about 72 hours. Thereafter the fermented wash is distilled to produce ethanol. Water consumed in dry process is very less compared to traditional wet process system. Corn oil and mixture of other oils is fed into transesterification (reaction) vessels where ethanol with catalyst, usually sodium hydroxide is added and reaction takes place for about a period of 2-8 hours. Crude biodiesel and crude glycerin as by-products is produced. Excess ethanol removed by distillation process. Crude biodiesel washed with warm water to remove residual soaps or unused catalyst, dried and biodiesel stored for commercial use. Oil extracted from spent bleach mud (used sodium bentonite), a waste product of edible oil refineries may also be utilized for economical production of biodiesel in combination of corn oil and ethanol.

The present invention provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding at least one polyalkyl succinic anhydride derivative additive disclosed herein. The additive can be complexed with a boronating agent, such as boric acid, to yield a boron-containing polyalkyl succinic anhydride derivative.

Methods, enzymes, recombinant microorganism, and microbial systems are provided for converting polysaccharides, such as those derived from biomass, into suitable monosaccharides or oligosaccharides, as well as for converting suitable monosaccharides or oligosaccharides into commodity chemicals, such as biofuels. Commodity chemicals produced by the methods described herein are also provided. Commodity chemical enriched refinery-produced petroleum products are also provided, as well as methods for producing the same.

A method processing a liquid crude and / or natural gas condensate feed comprising subjecting the feed to a vaporization step to form a vaporous product and a liquid product, subjecting the vaporous product to severe thermal cracking, and subjecting the liquid product to crude oil refinery processing.

A Waste to Liquid Hydrocarbon Refinery System that transforms any municipal solid wastes and hazardous industrial wastes, Biomass or any carbon containing feedstock into synthetic hydrocarbon, particularly, but not exclusively, diesel and gasoline and / or electricity and co-generated heat, comprising three major subsystems: i) the Pyro-Electric Thermal Converter (PETC) (10) and Plasma Arc (PA) waste and biomass gasification subsystem (1); ii) the hydrocarbon synthesis subsystem (2); and iii) the electricity generation and heat co-generation subsystem (3).

In the methods for treatment of caustic effluents described in the specification, a spent caustic refinery effluent is supplied to a submerged combustion gas evaporator in which hot combustion gas containing carbon dioxide is injected into the caustic liquid to concentrate the liquid and convert a hydroxide constituent to a carbonate. Where the caustic effluent is from a petroleum refinery, oil in the waste liquid is separated from the aqueous constituent before, during or after concentration.

The invention relates to an isotropic graphite product and a preparation method thereof. The materials consist of caking agent and skeletal material. The mass ratio of the caking agent and the skeletal material is (0.30-0.70) to 1, wherein the weight of the rarefied natural crystallite graphite is 30 to 100% of that of the skeletal material, and the other materials are one or more than two of thegraphite returning charge, the pitch coke, the refinery coke, the secondary coke and the intermediate carbon sphere. The preparation method comprises the steps of uniformly mixing the caking agent andthe skeletal material, molding, baking, dipping, secondarily baking, and graphitizing. With rich materials, low cost, small limitation for molding, high capability of prepared isotropic graphite product, the invention can be widely applied in the field of preparing graphite product.

The present invention relates to a thermo catalytic process to produce diesel oil from vegetable oils, in refineries which have two or more Catalytic Cracking (FCC) reactors. At least one reactor processes heavy petroleum or residue in conventional operation conditions while at least one reactor processes vegetable oils in proper operation conditions to produce diesel oil. This process employs the same catalyst employed in the FCC process, which processes conventional feedstocks simultaneously. This process transforms high heat content raw materials into fuel hydrocarbons. It may improve efficiency for the obtainment of highly pure products and may not yield glycerin, one by-product of the transesterification process. The diesel oil produced by said process may have superior qualities and / or a cetane number higher than 40. Once cracking conditions occur at lower temperatures, it may form a less oxidized product, which is consequently purer than those obtained by existent technology.

Thousands of process and equipment measurements are gathered by the modern digital process control systems that are deployed in refineries and chemical plants. Several years of these data are historized in databases for analysis and reporting. These databases can be mined for the data patterns that occur during normal operation and those patterns used to determine when the process is behaving abnormally.These normal operating patterns are represented by sets of models. These models include simple engineering equations, which express known relationships that should be true during normal operations and multivariate statistical models based on a variation of principle component analysis. Equipment and process problems can be detected by comparing the data gathered on a minute by minute basis to predictions from these models of normal operation. The deviation between the expected pattern in the process operating data and the actual data pattern are interpreted by fuzzy Petri nets to determine the normality of the process operations. This is then used to help the operator localize and diagnose the root cause of the problem.

A method has been invented for separating components of a wastewater stream, the stream containing water, oil (e.g. heavy oil and / or light oil), undesirable organic material (solid and / or liquid), and contaminating solids, the method including feeding a wastewater stream to a first pre-treatment unit producing a first pretreated stream, feeding the first pretreated stream to a first centrifuge for centrifugal separation, producing a first liquid centrifuged stream, and a second liquid stream, and feeding the first liquid centrifuged stream to a second centrifuge producing a resultant centrifuged stream of recoverable oil and a water phase centrifuged stream which can be treated further or fed back to a source for re-use. The source may be a facility from the group including refineries, chemical plants, paper mill plants, and oil and gas processing facilities.

Aerial dispersion systems that may be employed to allow rapid and temporary conversion of aircraft for aerial dispersion purposes, such as aerial fire-fighting. The aerial dispersion systems may be implemented using modular components that may be configured for compatibility with conventional cargo loading and unloading systems of modern aircraft, including side-loading cargo systems of wide body passenger and cargo aircraft having high lift capacities. The aerial dispersion systems may be rapidly installed in a large fleet of high capacity aircraft in response to a wildfire or other rapidly-developing emergency such as an oil spill, chemical or biological contamination incident, building or refinery fire, etc. After use, the aircraft of the fleet may be rapidly de-modified and returned to original condition. The aerial dispersion systems may be operated with a fleet of aircraft in a coordinated manner, for example, as part of an aerial firefighting formation having multiple aircraft sharing information and / or common control.

The invention provides compositions comprising bauxite refinery residues that have been reacted with sufficient calcium and magnesium ions that they have a reaction pH of less than 10.5, and one or more water treating additives. The invention also provides processes for treatment of water containing dissolved inorganic substances involving stepwise treatment of the water in which the reacted bauxite refinery residues are added after the addition of a pH-raising additive. The invention also provides processes for treatment of water containing dissolved inorganic substances in which the reacted bauxite refinery residues are added stepwise, with one or more water treating additives also being added in at least one of the steps. The invention also provides a process for the neutralisation of bauxite refinery residue by reacting it with a base amount and a treating amount of calcium ions and a base amount and a treating amount of magnesium ions for a time sufficient to produce an at least partially-neutralized residue exhibiting a reaction pH of less than 10.5.

The present invention is directed to methods for improving the efficiency of processes for the recovery of natural gas liquids from a gas feed, e.g., raw natural gas or a refinery or petrochemical plant gas stream. These methods may be employed with most, if not all, conventional separation methods using distillation towers, e.g., a demethanizer and / or deethanizer column. The methods of the present invention involve installing an internal refrigeration system consisting of an open cycle refrigerant withdrawn from a distillation column and a closed cycle refrigerant derived from the open cycle refrigeration system. A separator is installed downstream of the recycle compressor discharge cooler in the open cycle refrigeration scheme. At least a portion of liquid withdrawn from this separator is used as a closed cycle refrigerant by indirect heat exchange with the inlet gas or other process streams. Thus a closed refrigeration cycle enhances the performance of the open refrigeration cycle.

Systems, methods and devices are provided for collecting operational data at remote oil and natural gas sites, such as wells, and or processing and refinery plants. One such system comprises a remote transmitter and / or controller at the site and an unmanned aerial vehicle (UAV), such as a drone aircraft, configured for aerial dispatch to the remote site and wireless connection to the remote transmitter for subsequent relay or upload of data to an external processor. The UAV may include still or video cameras for collecting images around the well site that can be uploaded and transmitted to the external processor. The system may also include logic-based applications allowing for feedback control of the well site to change operational parameters based on the received data. The system may also include a variety of sophisticated sensor devices on the UAV or located at the remote site to collect additional operational data, such as airborne particulate and / or toxic gas concentrations, audio files of pumps or other equipment and levels and properties of produced water and other fluids.

A process for the production of biodiesel is disclosed. In a preferred embodiment, the process is based on the production of biodiesel using refinery soapstock where the process is performed in an alcoholic medium resulting in the insolubility of certain byproducts. Other valuable products can also be obtained from the process.

A porous particulate material for treating a fluid containing a contaminant is disclosed. The particulate material comprises a cementitious matrix or binder and treated bauxite refinery residue or red mud. At least a portion of the pores in the particulate material is open cell or interconnected pores. The invention also relates to the use of a reactive permeable barrier comprising porous material, for treating a contaminated fluid. Also disclosed is a method for producing porous particulate material for treating a contaminated fluid and a method for treating a contaminated fluid, in which the porous material is used. The invention furthermore relates to a cementitious composition comprising partially neutralised red mud and cement, wherein the partially neutralised red mud has been pre-treated by contacting it with water having a total hardness supplied by calcium, magnesium or a combination thereof, of at least 3.5 millimoles per litre calcium carbonate equivalent. The cementitious composition is useful as a building and construction material.

A method and process is described for producing negative carbon fuel. In its broadest form, a carbon-containing input is converted to combustible fuels, refinery feedstock, or chemicals and a carbonaceous solid concurrently in separate and substantially uncontaminated form. In an embodiment of the invention, biomass is converted via discrete increasing temperatures under pressure to blendable combustible fuels and a carbonaceous solid. The carbonaceous solid may be reacted to synthesis gas, sold as charcoal product, carbon credits, used for carbon offsets, or sequestered.