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2908 results about "Phase-transfer catalyst" patented technology

In chemistry, a phase-transfer catalyst or PTC is a catalyst that facilitates the migration of a reactant from one phase into another phase where reaction occurs. Phase-transfer catalysis is a special form of heterogeneous catalysis. Ionic reactants are often soluble in an aqueous phase but insoluble in an organic phase in the absence of the phase-transfer catalyst. The catalyst functions like a detergent for solubilizing the salts into the organic phase. Phase-transfer catalysis refers to the acceleration of the reaction upon the addition of the phase-transfer catalyst.

Preparation of 2,2-bi-[4-(4-aminophenoxy)phenyl]propane

A process for preparing 2,2-bis-[4-(4-aminophenyloxy)phenyl] propane includes such steps as reflux reacting between 4,4'-dihydroxydiphenyl propane (BPA), 1-chloro-4-nitrobenzene (CNB) and salting agent in the mixture of non-protonic transferring polar solvent and dewatering agent at 110-150 deg.C to obtain 2,2-bis-[4-(4-nitrophenyloxy)phenyl] propane (BNPP), and reducing in alcohol as solvent under action of hexahydrated iron chloride, activated carbon and hydrazine hydrate. Its advantages are simple process, low cost and high quality and output rate of product.
Owner:TANSUO SCI & TECH NANTONG CITY

Process for producing fluoroolefins

A process for producing a fluoroolefin of the formula: CF.sub.3CY.dbd.CX.sub.nH.sub.p wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF.sub.3C(R.sup.1.sub.aR.sup.2.sub.b) C(R.sup.3.sub.cR.sup.4.sub.d), wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olefin is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.
Owner:HONEYWELL INT INC

Natural fiber composite material and preparation method thereof

The invention discloses a natural fiber composite material and a preparation method thereof. The natural fiber composite material is mainly prepared from the following components in parts by weight: 14-135 parts of water-based resin, 100-500 parts of natural fiber, 0.3-5 parts of hardener, 0.01-5 parts of phase transfer catalyst, 50-500 parts of filler and 100-200 parts of water. In the invention, the natural fiber can be fully coated only by a small amount of polymer resin to obtain the natural fiber composite material with excellent waterproof performance; and the modified natural fiber can be used as a raw material of waterproof fiber boards, bakelite powder padding and plastic-wood composites (WPC).
Owner:漳州市奈特新型建材有限责任公司

Powder coating fluoropolymer compositions with aromatic materials

InactiveUS20050080210A1CoatingsPolymer scienceCresol
Provided is a composition comprising an aromatic material selected from a polythiol aromatic compound or resin, a hydroxythiophenol compound or resin, a catechol novolak resin, a catechol cresol novolak resin, a polyhydroxy aromatic resin or compound comprising at least one aromatic ring having at least one hydroxyl group attached directly to the aromatic ring wherein at least one hydroxyl group is a phenolate salt, or a combination thereof, and a salt former compound capable of forming a salt with the aromatic material, a fluoropolymer, and optionally a phase transfer catalyst. Also provided are articles comprising powder-coated fluoropolymers with aromatic compounds, and methods for making the compositions and articles.
Owner:3M INNOVATIVE PROPERTIES CO

Phosphaphenanthrene flame-retardant compound containing s-triazine structure, and preparation and use thereof

The invention discloses an oxa-phosphaphenanthrene flame retardant compound containing the sym-triazine structure and a preparation method thereof. The method is characterized in that an intermediate is synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO) and p-hydroxybenzaldehyde as raw material by the solution method, and then reacts with cyanuric chloride in the presence of phase transfer catalyst to obtain a 2,4,6-tri(4-(10-methenyl hydroxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide)phenoxy)-1,3,5-triazine product. The compound is white crystal, and has a melting point of 166 to 169 DEG C, good thermal stability and high flame retardation efficiency, and can be adopted as a reactive flame retardant for the flame retardation of thermosetting resins such as epoxy resin, polyurethane and the like, and also as an additive flame retardant for the flame retardation of engineering plastics such as ABS, nylon and the like.
Owner:SICHUAN DONGFANG INSULATING MATERIAL

Halogen-free ionic liquids

An ionic liquid according to the invention is substantially halogen-free, has a low viscosity and is stable to hydrolytic degradation under test conditions. The ionic liquid is a compound of the formula (cation) (R′—O—SO3), (cation) (R′—SO3), or a mixture of the two compounds. It can be used in processes for the chemical conversion and separation of materials by employing the ionic liquid as a solvent, solvent additive, extraction agent or phase-transfer catalyst. It can also be used in a heat exchange device wherein the ionic liquid serves as a heat carrier or heat carrier additive.
Owner:MERCK PATENT GMBH

Branched polycarbonate-polysiloxane copolymers and processes for producing the same

Methods for making a branched polycarbonate-polysiloxane copolymer are provided. An interfacial mixture comprising water, an organic solvent, a polyhydric branching agent, a non-siloxane-containing dihydroxy compound, an endcapping agent, a phase transfer catalyst, and a base is formed. The base and the branching agent are dissolved in the mixture before the non-siloxane-containing dihydroxy compound is added and the interfacial mixture has a basic pH. A first carbonate precursor is added to the interfacial mixture while maintaining the pH at from about 3 to about 9 to form a branched polycarbonate mixture. Next, the pH is increased to from about 8 to about 13 and a siloxane oligomer is added to the branched polycarbonate mixture. The branched polycarbonate mixture is then reacted to form the branched polycarbonate-polysiloxane copolymer. The resulting branched copolymer contains 20 ppm or less of residual chloride, is transparent, has improved flow properties, and has good flame retardance at thin wall thicknesses.
Owner:SABIC INNOVATIVE PLASTICS IP BV

Polypyrrole/graphene nano composite and preparation method thereof

The invention discloses a polypyrrole / graphene nano composite which belongs to the technical field of composites. In the invention, ethanol is taken as a medium, para-toluenesulfonic acid is taken as a surface active agent, polyethylene glycol-400 is taken as phase transfer catalyst, FeCl3*6H2O is taken as an evocating agent, and under ultrasound conditions, pyrrole monomers are polymerized in situ on graphene, so as to obtain the polypyrrole / graphene nano composite. In the composite of the invention, through analysis by electron microscopy, the pyrrole monomers are polymerized in situ and evenly cover the grapheme, and the graphene and the polypyrrole are tightly combined in a nano level; and thermogravimetric analysis and electric conductivity study show that the composite has better heat stability, electric conductivity and processability and can be used in the fields of sensors, electron devices and biomedicine.
Owner:NORTHWEST NORMAL UNIVERSITY

Tazobactam synthesis method

The invention relates to a tazobactam synthesis method which comprises the steps of: with 6-APA(Amino Penicillanic Acid) as raw material, preparing a key intermediate 6,6-dihydro penam sulphoxide acid diphenylcarbinol ester through successive reactions of esterification, oxidation, reduetive debromination and the like without separation; then, reacting with 2-triphenyl silicon-1,2,3-triazole; introducing a triazole ring; and finally obtaining the final product of tazobactam through potassium permanganate oxidation and metacresol deprotection. The tazobactam synthesis method is mainly characterized in that a phase transfer catalyst is introduced in the first step, therefore, the reaction rate and the product purity are improved; since an environment-friendly hydrogen peroxide-cobalt acetate catalytic oxidation system is adopted in the third step, the characteristics of good reaction selectivity, high yield, catalyst recyclability and the like are achieved; a method for synthesizing 2 alpha-methyl-2 beta-(1,2,3- triazole-1- radical) methyl penam-3 alpha-carboxylic acid diphenylcarbinol ester by using 2-triphenyl silicon-1,2,3-triazole is adopted in the fifth step, and the tazobactamsynthesis method is simple and convenient to operate, is safe and reliable, shortens the reaction route and improves the total yield. Compared with the traditional process, the tazobactam synthesis method greatly reduces the production cost and the environment pollution and has greater implementation value and economic benefits.
Owner:YIYUAN XINQUAN CHEM

Composite material capable of releasing volatile substances persistently and preparation method thereof

The invention discloses a composite material capable of releasing volatile substances persistently and a preparation method thereof. The composite material is prepared from the following main components in parts by weight: 10-50 parts of aqueous resin, 50-180 parts of natural fiber, 3-8 parts of water-solubility hardening agent, 8-15 parts of phase transfer catalyst, 50-150 parts of filler, 2-9 parts of volatile substance and 100-200 parts of water. The invention uses the natural fiber and common high molecular materials as carriers of the volatile substances, has simple preparation and low production cost and can be decomposed directly in a natural state.
Owner:漳州市奈特新型建材有限责任公司

Multiphasic microchannel reactions

Multiphasic reactions, especially those reactions using a phase transfer catalyst, are conducted in microchannel apparatus. Advantageously, these reactions can be conducted with two, planar microlayers of reactants in adjacent laminar flow streams. Microchannel apparatus and methods for conducting unit operations such as reactions and separations in microchannel apparatus is also described. Microchannel apparatus can provide advantages for controlling reactions and separating products, solvents or reactants in multiphase reactions.
Owner:BATTELLE MEMORIAL INST

Process for preparing epoxy cyclohexane by catalytic cyclooxidation of cyclohexene

A process for preparing epoxy cyclohexane by catalytic epoxidation of cyclohexene is disclosed. It is characterized by use of a phase-transfer catalyst which is insoluble in reaction medium but can become the active substance soluble in reactino medium under action of hydrogen peroxide. Said catalyst can be cyclically used. Its advantages are high selectivity (97%), easy recovery of catalyst, no by-product and low cost.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI +1

Polythiophenes

Polythiophenes which are soluble or dispersible in anhydrous or low-water-content solvents can be prepared if they are prepared in anhydrous or low-water-content solvents and a phase-transfer catalyst is added during the reaction.
Owner:H C STARCK GMBH

Preparation method of electronic grade triglycidyl isocyanurate

The invention mainly aims to provide a preparation method of electronic grade triglycidyl isocyanurate (TGIC). In order to realize the aim, the technical scheme in the invention is as follows: the preparation method of electronic grade TGIC comprises the following steps: a) adding epichlorohydrin, cyanuric acid, quaternary ammonium salt phase transfer catalyst and water according to a ratio, heating and stirring to react; b) adding flake caustic soda in the reaction system obtained in the step a) to react, then performing pressure filtration to remove solid salt; and c) performing vacuum distillation after the reaction, then using a high vacuum film evaporator to distill and remove epichlorohydrin, crystallizing the coarse product, centrifuging, grinding, and drying to obtain electronic grade TGIC. According to the treatment method provided by the invention, the purity of the TGIC product can be effectively increased, and the purity of TGIC can be increased from 92% to more than 99%, which reaches the electronic grade.
Owner:HUANGSHAN HUAHUI TECH

Topical film delivery system

The described invention provides a topical bioadhesive film-forming pharmaceutical composition formulated for application directly to skin or to a substrate. The composition includes a therapeutic amount of an active agent; and one or more excipients selected from the group consisting of a non-cellulosic polymer or copolymer, a film forming agent, a plasticizer, a permeation enhancer, an antioxidant, a preservative, a solubilizer, a phase transfer catalyst, a viscosity modifier, a vitamin, a mineral nutrient, a solvent, a colorant and a fragrance. It further provides a delivery system comprising the composition and a means for administering the composition. It also describes uses of the delivery system in the manufacture of a medicament for treating a skin condition, disease or disorder, and a method for treating a skin condition, disease or disorder with the composition. The composition is characterized by: controlled release. The formed film is characterized by: locally sustained levels of a minimum effective concentration (MEC) of the active agent between applications; its adherence and conformance to a surface of the skin; its pliability, its resistance to breaking under tension (tensile strength); maintained potency of the active agent; and removability of the film from the skin without a residue.
Owner:SIDMAK LAB INDIA PVT LTD

Ultrasound-Assisted Oxidative Desulfurization of Diesel Fuel Using Quaternary Ammonium Fluoride and Portable Unit for Ultrasound-Assisted Oxidative Desulfurization

The desulfurization of fossil fuels is effected by the combination of fossil fuels with an aqueous mixture of hydroperoxide and quaternary ammonium fluoride phase transfer catalyst, the mixture then subjected to ultrasound to oxidize sulfur compounds present in the fuels. The polar oxidized species are removed via extraction. Another aspect is a portable, continuous ultrasound assisted desulfurization device having a sonoreactor for subjecting mixtures of fossil fuels to sonication to effect removal of sulfur containing compounds.
Owner:UNIV OF SOUTHERN CALIFORNIA

Natural fiber resin composite and preparation method thereof

The invention discloses a natural fiber resin composite and a preparation method thereof. The natural fiber resin composite is prepared from the following components in part by weight: 10-50 parts of waterborne resin, 10-50 parts of non-aqueous epoxy resin, 50-200 parts of natural fiber, 3-15 parts of water soluble hardening agent, 6-15 parts of phase transfer catalyst, 50-150 parts of filler and 100-200 parts of water. The natural fiber resin composite has the characteristics of high strength and low cost.
Owner:漳州市奈特新型建材有限责任公司

Hydroxyalkyl cationic guar gum and its preparation method and application

A process for preparing the cationic hydroxyalkyl guar gum includes such steps as dispersing the raw powder of guar gum in the aqueous solution of low-carbon alcohol, adding high-alkaline catalyst, immersing, adding cationic etherifying agent, cationic graft reaction, adding phase-transfer catalyst and alkoxy etherifying agent, hydro-xyalkylating reaction, neutralizing and filtering. It can be used as the retention aid or filter aid of paper pulp.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method of perfluorethyl isopropyl ketone

The invention provides a preparation method of perfluorethyl isopropyl ketone. The preparation method specifically comprises the step of: with a hexafluoropropylene dipolymer mixture and perfluo-4-methyl-2-amylene or perfluo-2-methyl-2-amylene as raw materials, carrying out reaction processes such as olefin epoxidation, structural rearrangement of epoxide to prepare the perfluorethyl isopropyl ketone. An aprotic polar solvent, a catalyst and a phase transfer catalyst are used in a preparation process, high selectivity and high transformation rate of all steps of reactions are realized, and after a reaction mixture is simply separated so that an intermediate and a perfluorethyl isopropyl ketone product with high quality can be obtained. Meanwhile, a one-pot technology of double bond isomerization and epoxidation reaction is established. The preparation method provided by the invention has the characteristics that raw materials are easily available, the cost is low, reaction conditions are mild, operation is safe and simple, reaction selectivity and transformation rate are high, little environment influence is low; therefore, the preparation method is suitable for industrial application.
Owner:CHINESE PEOPLES ARMED POLICE FORCE ACAD

Preparation method of polyvinylidene fluoride grafted p-styrenesulfonic acid proton exchange membrane

The invention provides a preparation method of a polyvinylidene fluoride grafted p-styrenesulfonic acid proton exchange membrane. The method comprises the following steps of: firstly, adding a phase transfer catalyst into a prepared alkaline alcohol solution to obtain an alkaline alcohol solution containing the phase transfer catalyst; adding polyvinylidene fluoride into the solution and processing to obtain alkaline-treatment polyvinylidene fluoride powder; adding the obtained powder into an organic solvent to obtain an alkaline-treatment polyvinylidene fluoride powder solution; adding a p-styrene sulfonate monomer and an initiator, and reacting in a nitrogen atmosphere; performing ultrasonic oscillation, and putting the product in a polytetrafluoroethylene membrane frame; drying and stripping the membrane; replacing the monovalent cations in the membrane; removing the residual sulfuric acid; and storing the product in the deionized water to obtain the polyvinylidene fluoride grafted p-styrenesulfonic acid proton exchange membrane. Through the method, a proton exchange membrane with high electric conductivity can be prepared, and the electric conductivity is relatively approximate to that of a Nafion membrane; and the preparation method is simple and easy to implement, has relatively low cost and can be applied to large-scale production.
Owner:HUBEI UNIV

Preparation method of macromolecular water-absorbent resin with low reverse osmosis

ActiveCN103910896AImprove liquid absorption capacityImprove anti-reverse seepage abilityCoatingsPolymer scienceReverse osmosis
The invention provides a preparation method of macromolecular water-absorbent resin with low reverse osmosis. According to the method, a polymerization stabilizing additive is added and process conditions are reasonably controlled during a polymerization process, so that the polymerization reaction is stable and the process is simple. A surfactant is added before the surface crosslinking of water-absorbent resin powder; meanwhile, a phase transfer catalyst is added during the surface crosslinking. Thus, the phenomenon of caking of the water-absorbent resin powder during the surface crosslinking is avoided, so that surface crosslinking solution is uniformly distributed. Therefore, the solution absorbing ability and the reverse osmosis resisting ability of the water-absorbent resin are greatly improved. The water-absorbent resin is suitable for physical hygiene products.
Owner:WANHUA CHEM GRP CO LTD +1

Phosphor A containing novolac epoxy and method for producing the same

The invention relates to the technical field of novolac epoxy resin, in particular to a bisphenol A novolac epoxy resin containing phosphorous and a relative preparation method, wherein the compound formula is represented as below, n is 0-7. The invention condensates formaldehyde or cavaform and bisphenol A in the presence of acid catalyst to prepare phenol resin compound, processes etherification with epichlorohydrin in the presence of phase transfer catalyst, generates bisphenol A novolac epoxy resin in the presence of alkal catalyst, and reacts the bisphenol A novolac epoxy resin with organic phosphorous compound in the presence of catalyst to obtain bisphenol A novolac epoxy resin containing phosphorous. The solid product has good thermal resistance, flameproof, mechanical property and wide application in the technical fields of laminated board, insulated material, semi-conductor package and composite material.
Owner:DONGGUAN UNIV OF TECH

Method for producing conductive polyaniline and organic polymer composition

A method for producing a conductive polyaniline comprising oxidative polymerizing aniline or its derivative in the presence of at least one member of a sulfonic acid compound and a water-insoluble organic polymer compound having protonic acid group in a mixed layer composed of an aqueous layer and organic layer, during which it establishes the presence of a molecular weight adjusting agent and, optionally, a phase transfer catalyst so as to stably disperse them in an organic solvent, and an organic polymer composition containing the conductive polyaniline.
Owner:YOKOHAMA RUBBER CO LTD

Prepn. of expanding halide-free fire-retardant and products thereof

This invention relates to a method to prepare a flame retardant and its product, and especially relates to a method to prepare graft nitrogenous heterocyclic compounds with P-O backbones from phosphorus pentoxide and ammonium dihydrophosphate, a method to prepare nonhalogen intumescent flame retardant for polyolefin and its product. The nonhalogen intumescent flame retardant produced in this invention has following advantages compared to nonhalogen intumescent flame retardants produced by current techniques: a) two-step method is adopted so that production time is shortened, temperature is lowered, operation is simple and energy cost is low; b) phase transmission catalyst is solid-liquid system so that grafting efficiency of oxygen-containing amine is ensured; c) crystallization is accelerated by the introduction of ammonia and tightly and perfectly crystallized nonhalogen intumescent flame retardant backbone intermediate can be obtained.
Owner:HANGZHOU JLS FLAME RETARDANTS CHEM

Method for preparing bisphenol-A liquid epoxy resin

The invention relates to a method for preparing bisphenol-A liquid epoxy resin, and belongs to the field of high polymer preparation. The method comprises the following steps: 1) adding a quaternary ammonium salt phase-transfer catalyst, and performing etherification at a temperature of between 70 and 85 DEG C for 45 to 240 minutes; 2) at a constant temperature of between 60 and 70DEG C, droppingalkali by NaOH aqueous solution for 1.5 to 4 hours, keeping epoxy chloropropane refluxing in the alkali dropping period, and discharging water out of a reaction system; and 3) separating unreacted epoxy chloropropane by a rotary evaporator at a temperature of 135DEG C, dissolving a mixture of resin and salt, removing solid salt by a filter, washing the resin for 3 to 5 times by water, separating solvent, and obtaining the final product. The prepared epoxy resin has the epoxy value between 0.55 and 0.56 through titration by hydrochloric acid acetone solution, low viscosity (between 7,000 and 10,000mPas), and the epoxy index between 0.595 and 0.622 through infrared spectroscopic analysis, and comprises 91 to 92 percent of micro molecular epoxy resin.
Owner:CHINA PETROCHEMICAL CORP

Surface hydrophilic modification of polystyrene material and product

ActiveCN101440168AIncreased hydrophilicityReduced non-specific adsorption capacityComponent separationChromatographic separationMicrosphere
The invention provides a method for preparing surface hydrophilic modified polystyrene materials, and a product thereof, and the method is characterized by grafting and coupling the surface of polystyrene with a layer of hydrophilic macromolecular polyvinyl alcohol (PVA) through a stable chemical bond, particularly performing hydrophilic modification on the surfaces of super-macroporous polystyrene microspheres. The method comprises the following concrete steps: (1) benzene ring of polystyrene is subjected to halogen acetylation or halogen methylation in an organic solvent under the action of acidic catalysts through Friedel-Crafts reaction, and is added to active radical halogen acetyl or halogen methyl; and (2) under alkaline conditions and the action of phase transfer catalyst, Williamson etherification is utilized to couple the hydrophilic PVA to the surface of polystyrene through ether linkage. The method has the advantages of simple operation and mild conditions. A hydrophilic coating is stable, not easy to fall off and rich in hydroxyl. The method has great application potential in biotechnology, particularly the chromatographic separation field.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Gemini anionic surface active agent and preparation method thereof

The invention relates to a gemini anion surfactant and a preparation method thereof. The surfactant has two synthesis routes: one is alkylated reaction which uses bromoalkane and diphenyl ether as raw materials to produce intermediate alkyl diphenyl ether under the catalysis of lewis acid AlCl3; the other is phase transfer catalytic reaction which uses alkylphenol and oxygen ether vinylicus as raw materials to produce alkylphenol oxygen ether vinylicus under the catalysis of the phase transfer catalyst of hexadecyl trimethyl ammonium bromide. Sulfonation and neutralization are conducted to the produced intermediate to acquire Gemini anion surfactant. With good surface activity, the surfactant has good synergistic effect with other surfactants, and can be widely applied in tertiary recovery.
Owner:TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGY
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