The present invention provides a modified conjugated dienepolymer that is prepared by polymerization of a conjugated diene compound using a catalyst containing a lanthanoid rare earth element compound in an organic solvent and then modifying the resulting polymer having an active organic metal site with a modifier, wherein the modification efficiency is not less than 15% and the cis-1,4 bond content in the conjugated dienemoiety measured by Fourier transforminfraredspectroscopy satisfies the relationship (I):cis-1,4 bond content≧98.00(%) (I),or the modification efficiency is not less than 75% and the cis-1,4 bond content in the conjugated dienemoiety measured by Fourier transforminfraredspectroscopy satisfies the relationship (II):94.00(%)≦cis-1,4 bond content<98.00(%) (II).The invention further provides a rubber composition containing the modified conjugated dienepolymer and giving a tire exhibiting low heat build-up, satisfactory failure characteristics, and high abrasion resistance, and a tire composed of the rubber composition and exhibiting these characteristics.
The invention discloses an Al-Fe-Zn-Mg rare earthalloy wire and a preparation method thereof. The aluminum alloy comprises the following elements: 0.3-1.2wt% of Fe, 0.01-0.3wt% of Zn, 0.01-0.4wt% of Mg, 0.1-1.5wt% of rare earth element and the balance of Al and inevitable impurities, wherein the rare earth element is composed of one or more of cerium, lanthanum, neodymium and yttrium. The preparation method of the aluminum alloy wire comprises the following steps: preparing an aluminum alloy rod through smelting, casting and rolling, performing insulation treatment in a heat holding cover at 240-320 DEG C for 10-20 hours, wiredrawing and extruding insulating material on the wire; or preparing an aluminum alloy rod through smelting, casting and rolling, drawing the aluminum alloy rod to prepare the aluminum alloy wire, performing semi-annealing treatment in an annealing furnace at 340-380 DEG C for 5-10 hours, and finally extruding insulating material on the wire. The aluminum alloy wire prepared by the method of the invention has excellent electrical property, mechanical property and corrosion resistance and can be used in the wire and cable conductors.
The invention relates to a catalytic material for purifying tail gas of an automobile, in particular to a ceriumoxide and zirconiumoxide based sosoloid catalyst, a preparation method and application thereof. The ceriumoxide and zirconium oxide based sosoloid catalyst comprises 50-79.5wt% of zirconium oxide, 20-49.5wt% of cerium oxide and 0.5-25wt% of oxides of other elements, wherein the zirconium oxide, the cerium oxide and the oxides of other elements is present in a sosoloid form, and the oxides of other elements are one or more oxides of lanthanons except cerium. The preparation method is as follows: continuous coprecipitation is carried out on zirconium oxychloride, saline solution of cerium and saline solution of lanthanons except cerium to obtain the cerium oxide and zirconium oxide based sosoloid catalyst. In the invention, by adding the zirconium oxide and the oxides of the lanthanons except cerium, the prepared cerium oxide and zirconium oxide based sosoloid catalyst has favorable catalytic performance and greatly improved thermal stability. The preparation method can prepare the cerium oxide and zirconium oxide based sosoloid catalyst under relatively lower temperature and normal pressure.
The invention provides a novel sintered neodymium-iron-boron permanent-magnet material containing holmium and a manufacture method thereof. The novel sintered neodymium-iron-boron permanent-magnet material has the structural formula as follows: LnAlphaHoBetaBGammaMxNyFe100-Alpha-Beta-Gamma-x-y, wherein Ln is lanthanon comprising Nd and one or more selected from Pr, Dy and Tb; M is an additive element comprising Co and Cu; N is an additive element comprising one or more selected from Al, Ga, Nb, Zr and Ti; Alpha, Beta, Gamma, x and y are weight percentages of each element; Fe is an Fe element or unavoidable impurities; and Alpha is mare than or equal to 29 and less than or equal to 33, Beta is more than or equal to 0.5 and less than or equal to 4, Gamma is more than or equal to 0.95 and less than or equal to 1.20, x is more than or equal to 0 and less than or equal to 3.5, and y is more than or equal to 0 and less than or equal to 1.50. In the invention, the addition of Ho has a remarkable function in improving the Hcj of a magnet.
This invention discloses a fin heat-exchanger made of aluminum alloy foil and its preparation method. The ingredient and ratio of the alloy are as follows: iron is 0.15-0.40%, silicon is 0.05-0.30%, copper is 0-0.10%, manganese is 0.05-0.30%, the element of rare-earth is 0.05-0.4%, titanium is 0.010-0.060%, the other is aluminum. The ingredient and ratio of rare-earth is as follows: lanthanum is 20-40%, cerium is 45-65%, praseodymium is 5-15%, neodymium is 1-9%, samarium is 0-0.05%, yttrium is 0-0.05%,the other is impurities. The preparation method includes four processes: the preparation of rare-earth aluminum alloy, the casting of blank, cold-rolling of slat and heat treating. Contrasting to the existing aluminum alloy material, the product has the better extension and toughness, the smaller aeolotropism at the same thickness and hardness, and it can be suitable to punch at high flanged fill heat-exchanger and could not crack.
The invention provides a manganese-copper based composite oxide doped rare earth element catalyst for catalyzing volatile organic compounds (VOCs) as well as a preparation method and application of the catalyst. The catalyst disclosed by the invention adopts a high-pore-volume cordieritehoneycombceramic material as a carrier, and the carrier is sequentially coated with a first metaloxidecoating layer, a second metaloxidecoating layer and a third metaloxidecoating layer from the inside to the outside, wherein the first metal oxide coating layer is active aluminum oxide, the second metaloxide coating layer is a hafnium-lanthanum-cerium oxide, and the third metal oxide coating layer is a manganese-copper based oxide. The catalyst provided by the invention adopts a non-precious metalinstead of a precious metal; and the catalyst provided by the invention has uniformly-dispersed coating layers, binding force between an active component and a matrix is strong, the coating layers arenot easy to fall or crack, and the catalyst can maintain higher activity under high-speed airflow and thermal shock, has stable activity when being used repeatedly, strong catalytic activity to the VOCs, a simple preparation process and low costs, and is suitable for large-scale production.
A method is provided for forming a rare earth (RE) element-doped silicon (Si) oxide film with nanocrystalline (nc) Si particles. The method comprises: providing a first target of Si, embedded with a first rare earth element; providing a second target of Si; co-sputtering the first and second targets; forming a Si-rich Si oxide (SRSO) film on a substrate, doped with the first rare earth element; and, annealing the rare earth element-doped SRSO film. The first target is doped with a rare earth element such as erbium (Er), ytterbium (Yb), cerium (Ce), praseodymium (Pr), or terbium (Tb). The sputtering power is in the range of about 75 to 300 watts (W). Different sputtering powers are applied to the two targets. Also, deposition can be controlled by varying the effective areas of the two targets. For example, one of the targets can be partially covered.