The invention provides a comprehensive recovering method of waste
lithium iron phosphate batteries, which has simple and reasonable process, low recovering cost and high added value. The method comprises the following steps: utilizing an
organic solvent to dissolve an
adhesive on
battery cell fragments, and realizing the separation of
lithium iron phosphate material and clean aluminum and
copper foils through screening, wherein the aluminum and
copper foils are recovered by
smelting; utilizing a NaOH solution to remove residual
aluminum foil scraps in the
lithium iron phosphate material, and removing
graphite and remaining
adhesive by heat treatment; after dissolving the
lithium iron phosphate with acid, utilizing
sodium sulphide to remove
copper ions, and utilizing the NaOH solution or
ammonia solution to allow iron, lithium and
phosphorus ions in the solution to generate sediments; adding
iron source, lithium source or
phosphorus source compounds to adjust the
molar ratio of iron, lithium and
phosphorus; and finally adding a
carbon source, and obtaining a
lithium iron phosphate cathode material through ball milling and
calcination in
inert atmosphere. After the treatment of the steps, the
recovery rate of valuable metals in the batteries is more than 95%, and the comprehensive
recovery rate of the
lithium iron phosphate cathode material is more than 90%.