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1735 results about "Samarium" patented technology

Samarium is a chemical element with the symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually assumes the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide. The last compound is a common reducing agent in chemical synthesis. Samarium has no significant biological role but is only slightly toxic.

Method and apparatus for analyte sensing

In one aspect, the present invention is directed to a glucose sensing device for implantation within subcutaneous tissue of an animal body. In one embodiment, the glucose sensing device includes a first chamber containing first magnetic particles and a hydrocolloid solution (for example, ConA-dextran hydrocolloid) wherein the first magnetic particles are dispersed in the hydrocolloid solution. In operation, glucose within the animal may enter and exit the first chamber and the hydrocolloid solution changes in response to the presence or concentration of glucose within the first chamber. The sensing device also includes a reference chamber containing second magnetic particles and a reference solution wherein the second magnetic particles are dispersed in the reference solution. The reference solution (for example, oil or alcohol compounds) includes a known or fixed viscosity. The reference solution may also be a hydrocolloid solution (for example, ConA-dextran hydrocolloid). The first and / or second magnetic particles may include amine-terminated particles, at least one rare earth element (for example, neodymium or samarium), and / or a ferromagnetic material.
Owner:BIOTEX

Layered thermal barrier coatings containing lanthanide series oxides for improved resistance to CMAS degradation

A coating applied as a two layer system. The outer layer is an oxide of a group IV metal selected from the group consisting of zirconium oxide, hafnium oxide and combinations thereof, which are doped with an effective amount of a lanthanum series oxide. These metal oxides doped with a lanthanum series addition comprises a high weight percentage of the outer coating. As used herein, lanthanum series means an element selected from the group consisting of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and combinations thereof, and lanthanum series oxides are oxides of these elements. When the zirconium oxide is doped with an effective amount of a lanthanum series oxide, a dense reaction layer is formed at the interface of the outer layer of TBC and the CMAS. This dense reaction layer prevents CMAS infiltration below it. The second layer, or inner layer underlying the outer layer, comprises a layer of partially stabilized zirconium oxide.
Owner:GENERAL ELECTRIC CO

High performance lithium ion battery anode material lithium manganate and preparation method thereof

The invention provides a high performance lithium ion battery anode material lithium manganate and a preparation method of the material. The lithium manganate is a doped lithium manganate LiMn2-yXy04 which is doped with one kind or a plurality of other metal elements X, wherein X element is at least one kind selected form the group of aluminium, lithium, fluorine, silver, copper, chromium, zinc, titanium, bismuth, germanium, gallium, zirconium, stannum, silicon, cobalt, nickel, vanadium, magnesium, calcium, strontium, barium and rare earth elements lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, and y is larger than 0 but less than or equal to 0.11. The lithium ion battery anode material lithium manganate provided in the invention has extraordinary charge and discharge cycle performance both in the environments of normal temperature and high temperature. According to the invention, the preparation method of the material is a solid phase method, the operation is simple and controllable and the cost is low so that it is easy to realize large-scale productions.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Rare-earth doping modified lithium ion battery ternary positive electrode material and preparation method thereof

The invention relates to a rare-earth doping modified lithium ion battery ternary positive electrode material and a preparation method of the rare-earth doping modified lithium ion battery ternary positive electrode material. The chemical general formula of the material is as follows: LiNiaCo<1-a-b>MnbRxO2/M, wherein a is more than 0 and less than 1, b is more than 0 and less than 1, (1-a-b) is more than 0 and less than 1, x is more than 0.005 and less than 0.1, R is one or more of rare-earth lanthanum, cerium, praseodymium and samarium, and M is a composite cladding layer of oxide of aluminum, titanium or magnesium and carbon. The soluble metal nickel salt, cobalt salt, manganese salt and rare-earth compound are mixed to prepare a mixed salt solution, the mixed salt solution is reacted with a mixed alkaline solution prepared by mixing NaOH and ammonium hydroxide, after the reaction solution is filtered, washed and dried, the obtained product is uniformly mixed with lithium salt powder to be ball milled, then the mixture is calcined at the high temperature and coated with the composite cladding layer of the aluminum, titanium or magnesium oxide and carbon, and finally the calcined mixture is calcined at a constant temperature to obtain the rare-earth doping modified lithium ion battery ternary positive electrode material. After doping the rare earth, the metal oxide and carbon composite cladding layer, which are cheap and easy to obtain, are adopted, so that the cycling performance and the rate performance can be improved, and the charging-discharging efficiency of the material also can be improved.
Owner:ZHEJIANG MEIDARUI NEW MATERIAL TECH CO LTD

Nanoparticles of rare earth oxides

Rare earth compositions comprising nanoparticles, methods of making nanoparticles, and methods of using nanoparticles are described. The compositions of the nanomaterials discussed may include scandium (Sc), yttrium (Y), lanthanum(La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium(Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu). The nanoparticles can be used to make organometallics, nitrates, and hydroxides. The nanoparticles can be used in a variety of applications, such as pigments, catalysts, polishing agents, coatings, electroceramics, catalysts, optics, phosphors, and detectors.
Owner:PPG IND OHIO INC

Coproduction of hydrofluoroolefins

Disclosed is a process for the co-manufacture of the hydrofluoroolefins HFC-1225ye and HFC-1234yf. The process comprises contacting a blend of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2,3-pentafluoropropane at a temperature of from about 200° C. to about 500° C. with a catalyst, optionally in the presence of an inert gas. The catalyst includes, but is not limited to, aluminum fluoride; fluorided alumina; metals on aluminum fluoride; metals on fluorided alumina; oxides, fluorides, and oxyfluorides of magnesium, zinc and mixtures of magnesium and zinc and / or aluminum; lanthanum oxide and fluorided lanthanum oxide; chromium oxides, fluorided chromium oxides, and cubic chromium trifluoride; carbon, acid-washed carbon, activated carbon, three dimensional matrix carbonaceous materials; and metal compounds supported on carbon. The metal compounds are oxides, fluorides, and oxyfluorides of at least one metal selected from the group consisting of sodium, potassium, rubidium, cesium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, chromium, iron, cobalt, rhodium, nickel, copper, zinc, and mixtures thereof. The product hydrofluoroolefins are separated from unreacted hydrofluorocarbons and hydrogen fluoride. In another embodiment, the unreacted hydrofluorocarbons optionally may be recirculated back through the process.
Owner:EI DU PONT DE NEMOURS & CO

Niobium powder, sintered body thereof, and capacitor using the same

A niobium powder comprising at least one element selected from the group consisting of chromium, molybdenum, tungsten, boron, aluminum, gallium, indium, thallium, cerium, neodymium, titanium, rhenium, ruthenium, rhodium, palladium, silver, zinc, silicon, germanium, tin, phosphorus, arsenic, bismuth, rubidium, cesium, magnesium, strontium, barium, scandium, yttrium, lanthanum, praseodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, hafnium, vanadium, osmium, iridium, platinum, gold, cadmium, mercury, lead, selenium and tellurium; a sintered body of the niobium powder; and a capacitor comprising a sintered body as one electrode, a dielectric material formed on the surface of the sintered body, and counter electrode provided on the dielectric material.
Owner:SHOWA DENKO KK

Anti-carbon-deposition Ni-based catalyst for hydrogen production by methane steam reforming and preparation method thereof

The invention relates to an anti-carbon-deposition Ni-based catalyst for hydrogen production by methane steam reforming and a preparation method thereof. By taking lanthanum nitrate, praseodymium nitrate, samarium nitrate, yttrium nitrate, zirconium nitrate, zirconium carbonate, zirconium oxychloride, and the like as precursors and taking ammonia as a precipitant, a pyrochlore composite oxide is prepared through using a coprecipitation method; and then the pyrochlore composite oxide is mixed with alumina by using a mechanical mixing method so as to obtain a pyrochlore alumina composite carrier. Nickel nitrate, nickel chloride, nickel sulfate, nickel oxalate and the like serving as nickel sources are loaded on the pyrochlore alumina composite carrier through direct immersion. The loading capacity of nickel in the catalyst accounts for 5-30% of the weight of the catalyst, the pyrochlore content of the catalyst is 5-50%, and the alumina content of the catalyst is 20-90%. By taking the pyrochlore alumina composite oxide as a carrier, the reaction activity and anti-carbon-deposition performance of the catalyst can be greatly increased; the preparation method of the catalyst is simple; and the catalyst has excellent catalytic activity and stability to methane steam reforming in a stationary bed.
Owner:NANCHANG UNIV +1

Catalyst for complete catalytic oxidation of indoor low concentration formaldehyde at room temperature

The invention discloses a catalyst for complete catalytic oxidation of indoor low concentration formaldehyde at room temperature, the catalyst is characterized by comprising a nano metal oxide, a noble metal component and an assistant component, the nano metal oxide is used as a carrier, the noble metal component is at least one from platinum, palladium, ruthenium, rhodium, gold and silver, and the assistant is one or more than one substance from rare earth elements lanthanum, cerium, praseodymium, samarium, yttrium and neodymium, one or more than one kind of. The catalyst has the advantages that: the catalyst uses one or two rare earth modified nano inorganic oxide carrier, and is helpful to improve the dispersity and formaldehyde catalytic oxidation activity of metal nanoparticles. Therefore, under the circumstances of maintaining the same catalytic activity, the amount of noble metals can be reduced, and the cost of the catalyst can be reduced. The catalyst can completely oxidize formaldehyde at room temperature, does not need the help of optical, electric and other complex external auxiliary equipment. The catalyst can catalytically oxidize indoor low concentration harmful gas formaldehyde into non-toxic harmless carbon dioxide and water at room temperature.
Owner:BEGOOD TECH

Dehydrogenation catalyst applicable to raw gas rich in carbon monoxide, and preparation and application thereof

The invention relates to gas purification techniques and specifically to a dehydrogenation catalyst applicable to raw gas rich in carbon monoxide and preparation and application thereof. Palladium is used as an active component of the catalyst, auxiliary agents for the catalyst are two to four selected from the group consisting of silver, zinc, lanthanum, cerium, samarium, praseodymium, iron, stannum, manganese, calcium, magnesium, tungsten and molybdenum, and a carrier of the catalyst is alumina. The catalyst realizes selective catalytic oxidation removal of hydrogen in the raw gas rich in carbon monoxide by directing using synergism of palladium and oxides of a plurality of the auxiliary agents. Components of the catalyst comprise, based on the weight of the carrier, 0.05 to 1% of the active component and 0.5 to 5% of the total auxiliary agents. According to the invention, the catalyst has high activity and stability even when the application amount of a precious metal is small; through usage of the catalyst in a gas source rich in carbon monoxide, outlet hydrogen content is less than 100 ppm, outlet oxygen content is less than 0.1%, and purifying indexes of hydrogen and oxygen in reaction tail gas still accord with requirements after continuous operation for 1000 hours.
Owner:DALIAN CATALYTIC ENG TECH

Method of preparing samarium iron nitrogen permanent amgnet material using mechanical alloying

Final mass percent of SmFeN permanent magnetic material is prepared according to 25-30%Sm and 70-75%Fe. In order to increase infiltration capacity of nitrogen, element such as Cr, Ni, Co etc. with mass percent 0.1-2% is added. The mixed material powder is ball milled for 1- 20 hrs. The ball mill machine stops for 5- 20 minutes in every 5 - 30 minutes in order to prevent high temperature in tank. Its advantages are high nitrogen content, compact structure, simple equipment, easy of operation, high efficiency and low cost.
Owner:UNIV OF SCI & TECH BEIJING

Spark plug for internal-combustion engines

A spark plug for an internal-combustion engine is provided wherein the central and ground electrodes exhibit a long service life and wherein the fatigue strength at high temperatures is improved. The ground electrode is made from an alloy comprised of nickel (Ni) as a primary component, chromium: 20-30% by weight, iron: 7-20% by weight, aluminum: 1-3% by weight, titanium: 0.05-0.5% by weight, manganese: not higher than 0.1% by weight, silicon: not higher than 0.1% by weight, and carbon: not higher than 0.5% by weight. The alloy further includes at least one specific element selected from zirconium, yttrium, neodymium, cerium, lanthanum and samarium. Further, the total content of the specific element group is 5% or more of the aluminum content and is not higher than 1% by weight.
Owner:NGK SPARK PLUG CO LTD

Magnetic field orientation three-dimensional printing anisotropic bonded permanent magnet and preparation method thereof

ActiveCN104269265AAchieve regulationElimination of magnetic interaction forcesInductances/transformers/magnets manufactureRare earthNitrogen
The invention relates to the technical field of rare earth permanent magnetic materials, in particular to a magnetic field orientation three-dimensional printing anisotropic bonded permanent magnet and a preparation method thereof. The magnetic field orientation three-dimensional printing anisotropic bonded permanent magnet, adopts magnet powder having magnetocrystalline anisotropy, comprises one or a plurality of anisotropic neodymium iron boron magnetic powder, samarium cobalt magnetic powder and samarium iron nitrogen powder and is a semi-continuous or continuous orientation changed anisotropic bonded permanent magnet. The magnetic field orientation three-dimensional printing anisotropic bonded permanent magnet is prepared by the following steps of powder filling, orienting and forming into sheet layers, thermal demagnetizing, cutting the sheet layers into required-shaped unit sheet layers, stacking and solidifying the unit sheet layers layer by layer and magnetizing. According to the magnetic field orientation three-dimensional printing anisotropic bonded permanent magnet and the preparation method thereof, preparation of the three-dimensional printing anisotropic bonded permanent magnet is achieved, adjustment of the orientation and the order degree of powder in the sheet layers are achieved by adjusting the magnetic field direction and or the magnetic field strength, the defect that orientation of the traditional bonded permanent magnet cannot be changed is overcame, and continuous or semi-continuous change of magnetic orientation in the same three-dimensional entity is achieved.
Owner:CENT IRON & STEEL RES INST
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