The invention provides an anticorrosive material for a chimney, a flue and other containers and pipelines and an anticorrosive construction process. The construction method of the anticorrosive material comprises the following steps: using crude rubber with higher fluorine content as a raw material, then adding curing agent, stabilizer, special stuffing and other components, and mixing to form precuring gross rubber; dissolving the rubber by using low-molecular weight esters and ketones as the solvent to form a putty type rubber paste; and finally, adding special additives, uniformly mixing, coating to the inner walls of a chimney, a flue and a chemical container, and curing into the polymerized fluororubber organic lining under the room-temperature condition. The material can be independently used as the anticorrosive material, and can also be used for protecting common foam glass bricks (ceramic bricks) and adhesive for anticorrosive purpose in the domestic chimney (flue) at present. The invention well solves the technical problems of fluororubber room-temperature curing and difficult anticorrosive construction, can be used in a high-temperature environment of more than 230 DEG C, and can endure high-concentration sulfuric acid, nitric acid, hydrochloric acid, phosphoric acid, hydrofluoric acid, corresponding salts and a mixture thereof. The anticorrosive lining material is economically affordable, has extremely high comprehensive anticorrosive properties such as temperature resistance, acid resistance and the like, and is applicable to the anticorrosive treatment of a cured chimney.