The invention relates to a preparation method of an enamel plate for a flue of a thermal power plant. The enamel plate prepared through the method has excellent chemical durability, corrosion resistance and thermal stability and is suitable for the inner wall, where a smoke wet desulphurization and dedusting treatment device is installed, of the flue the thermal power plant. The preparation method specifically comprises the following steps that enamel glaze is prepared, specifically, a, raw materials are mixed, the raw materials for preparing the enamel glaze are evenly mixed in solvent water, and the raw materials of the enamel glaze include glaze, quartz, borax, barium nitrate, clay and sodium nitrite; b, melting is conducted, the raw materials which are evenly mixed are placed in a crucible and melted for 1-3 hours at the temperature of 1200-1400 DEG C; c, chilling is conducted, the melted raw materials are placed in water and rapidly cooled to the room temperature and then fished out to be dried, and the raw materials are solidified, so that blocky frit is obtained; and d, ball milling is conducted, the frit, clay and water are added into a ball mill to be ground till the mixture can pass through a sieve with 40-80 meshes, and glaze slip is prepared.