The invention discloses a production process of electrodeposited copper foil with a shiny surface subjected to roughening. The copper foil is subjected to acid pickling, roughening I, curing I, roughening II, curing II, curing III, curing IV, high-temperature anti-oxidation, water washing I, normal-temperature anti-oxidation, water washing II, silane spraying and drying in sequence; and the process conditions of the roughening I and the roughening II are that the current densities is 28 A / dm<2>-33 A / dm<2>, the temperature is 25 DEG C-35 DEG C, the sulfuric acid concentration is 160 g / l-180 g / l, the copper ion concentration is 7 g / l-13 g / l, the chloride ion concentration is 15 mg / l-30 mg / l, the sodium tungstate concentration is 0 mg / l-90 mg / l, the sodium molybdate concentration is 0 mg / l-70mg / l, and the cobalt sulfate concentration is 0 g / l-45 g / l. According to the process, tungsten, cobalt and molybdenum elements are added in the roughening procedures, so that the surface morphology of the copper foil is improved, and the anti-stripping strength of the electrodeposited copper foil is improved; and elements such as lanthanum or cerium are added in the high-temperature anti-oxidation process to form a special plating layer, and the structural morphology of the plating layer is changed, so that the anti-stripping strength and the corrosion resistance of the electrodeposited copper foil are improved.