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297 results about "Mn element" patented technology

Nickel-rich concentration gradient type lithium nickel cobalt aluminum oxide positive pole material, preparation method thereof and lithium ion battery

The invention provides a nickel-rich concentration gradient type lithium nickel cobalt aluminum oxide positive pole material, a preparation method thereof and a lithium ion battery. The nickel-rich concentration gradient type lithium nickel cobalt aluminum oxide positive pole material has a near-spherical appearance and a core-shell structure, wherein the content of Ni element in an inner layer is high, the content of Mn element in an outer layer is high, bulk molybdenum element doping is performed, and the surfaces of particles are coated with aluminum oxide. The reversible discharge capacity of the nickel-rich concentration gradient type lithium nickel cobalt aluminum oxide positive pole material provided by the invention under the current density of 350mA/g is more than 172mAh/g, and the capacity retention rate after 100 times of charge and discharge cycles at the rate of 2C is more than 85%. The lithium ion battery which takes nickel-rich concentration gradient type lithium nickel cobalt aluminum oxide as the positive pole material has the prominent advantages of high capacity, good thermal stability, good cycling stability, excellent rate property and the like, and has broad application prospects in the fields of electronic equipment, communication, transportation and the like.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Preparation method of nickel-cobalt-manganese ternary material enabling element content in gradient distribution

InactiveCN108598466AImprove co-precipitation synthesis processImprove stabilitySecondary cellsPositive electrodesManganeseLithium-ion battery
The invention belongs to the technical field of the lithium ion battery material preparation, and specifically relates to a preparation method of a nickel-cobalt-manganese ternary material enabling element content in gradient distribution. The chemical formula of the positive material is LiNixCoyMnzO2, x is not less than 0.5 and not more than 0.9, and the sum of x, y and z is equal to 1. The preparation process disclosed by the invention is based on co-precipitation method principle, the concentration of the metal ion entering the reaction kettle is continuously changed by changing the feedingway, the Mn element concentration is gradually increased, the concentration of each of the Ni element and the Co element is gradually reduced, thereby synthesizing the nickel-enriched positive material precursor particle with gradiently increased Mn element content and gradiently reduced Ni element content from center to the surface, and finally the nickel-enriched positive material with elementsin gradient distribution is formed by calcining the nickel-enriched positive material precursor particle with the lithium source in a mixed way. The full-gradient material is obviously different fromthe material with uniformly distributed elements from inside to outside and synthesized through the common co-precipitation method, and the higher specific capacity and good circulating performance and heat stability are provided.
Owner:HARBIN INST OF TECH AT WEIHAI

Manufacturing method of steel

InactiveCN101660020AAvoid strong churningImprove securitySlagCu element
The invention provides a manufacturing method of steel, comprising the following steps: smelting the molten steel to ensure that the content of P in the molten steel is less than or equal to 0.035%, the content of S is less than or equal to 0.015% and the content of V is less than or equal to 0.15%; then adding Cu element and Ni element to the molten steel to ensure that the content of Cu in the molten steel is 0.20-0.60% and the content of Ni is 0.15-0.55%; tapping to a steel ladle when the content of C in the molten steel is below 0.05%; adding physical mixture of lime and fluorite and predeoxidizing agent to the steel ladle in the tapping process to ensure that the content of S in the molten steel is less than or equal to 0.012%; adding Cr element, Si element and Mn element to the molten steel to ensure that the content of Si in the molten steel is 0.25-0.60%, the content of Mn is 0.80-1.60% and the content of Cr is 0.20-0.80%; feeding Al simple substance to the molten steel to carry out final deoxidation; heating the molten steel in the condition of argon blowing to lead the steel slag to melt; then adding Al simple substance to the steel ladle to ensure that the content of S in the molten steel is less than or equal to 0.010%; and then adding C element to the molten steel to ensure that the content of C in the molten steel is 0.08-0.16%; feeding Al simple substance and alloy containing Ti, V and N to the molten steel to control that the content of acid-soluble aluminium in the molten steel is 0.025-0.040%, the content of Ti is 0.005-0.015%, the content of V is 0.08-0.15% and the content of N is 0.010-0.020%.
Owner:PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP +3

Single crystal ternary cathode material having gradient concentration distribution and primary particle oriented growth, preparation method thereof and lithium ion battery

The invention provides a single crystal ternary cathode material having gradient concentration distribution and primary particle oriented growth. The single crystal ternary cathode material having gradient concentration distribution and primary particle oriented growth microstructure does not easily produce stress to destroy the structure during charge and discharge compared to ternary cathode materials having a core-shell structure of a two-phase interface and a non-directional growth structure; the surface Mn content is the same as the bulk Mn content, which effectively alleviates the dissolution of Mn element during the cycle; the structure of primary particle oriented growth can greatly shorten the Li+ migration distance and increase the migration rate of Li+, thereby improving the rate performance and cycle stability of the material; the surface of single crystal particles is smooth, can be in good contact with a conductive agent, and is greatly compact, which is beneficial to increasing the volumetric energy density of the material.
Owner:NINGBO RONBAY LITHIUM BATTERY MATERIAL CO LTD

High-nickel lithium ion positive electrode material and preparation method thereof

InactiveCN110034297AReduce the mixing degree of lithium and nickelHigh discharge specific capacitySecondary cellsPositive electrodesLithiumCrystal structure
The invention discloses a high-nickel lithium ion positive electrode material. The molecular formula is LiNi<x>Co<y>Mn<1-x-y-z>M<z>O2, wherein M is a doping element, the lithium ion positive electrodematerial is spherical secondary particle formed by gathering primary particle, and the structure of the lithium ion positive electrode material is a homogeneous-phase structure, a core-shell structure and a concentration gradient structure. The preparation method of the lithium ion positive electrode material comprises the steps of preparing a high-nickel positive electrode material precursor andpreparing the lithium ion secondary battery positive electrode. The precursor of the high-nickel positive electrode material is synthesized by a co-precipitation method, uniform mixing of elements can be facilitated, reaction can be more sufficient by adding the aging process, and morphology control is facilitated; and with the adoption of multi-element co-doping, the stability of a material crystal structure can be improved, the content of a Mn element is reduced, other doping elements are introduced, the lithium and nickel mixed arrangement degree of the high-nickel positive electrode material can be reduced, the orderliness of a layered material is ensured, the structure of the material is stabilized, the discharging specific capacity is improved, so that the energy density of the battery is improved.
Owner:SUNWODA ELECTRIC VEHICLE BATTERY CO LTD

Method for preparing nano lithium manganese phosphate material with uniform size

The invention provides a method for preparing a nano lithium manganese phosphate material with uniform size. The method comprises the steps of adding H3PO4 into a mixed solvent consisting of an organic solvent and water, wherein the organic solvent and the water are in volume ratio of (0.2-1) to 1; adding LiOH, and adjusting the pH value to be 9.5 to 13; adding oleic acid and uniformly stirring, wherein the concentration of oleic acid is 0.02 to 0.2mol / L; adding MnSO4, and maintaining the molar ratio of Mn elements and P elements to be 1 to 1; transferring the solution into a hydrothermal reaction kettle and reacting for 5h to 30h under the temperature of 90 to 210 DEG C; cooling at room temperature, then opening the hydrothermal reaction kettle, filtering the solution, separating the mixture, and drying a product at the temperature of 50 to 90 DEG C to obtain the nano lithium manganese phosphate material with uniform size. The size of the material is uniform and is smaller than 40nm, the device is simple, and the energy consumption is low; the method has the characteristics that raw materials are easily available and environmentally friendly.
Owner:TIANJIN UNIV

Low-alloy high-intensity high-toughness steel and production method of low-alloy high-intensity high-toughness steel

The invention discloses low-alloy high-intensity high-toughness steel and a production method of low-alloy high-intensity high-toughness steel. The method comprises the following work procedures of: the casting work procedure: the casting is carried out according to the following ingredients and contents to obtain low-alloy steel cast ingots: 0.15 to 0.30 weight percent of C elements, 0.30 to 0.70 weight percent of Si elements, 0.60 to 1.00 weight percent of Mn elements, 0.60 to 1.10 weight percent of Cr elements, 0.50 to 1.00 weight percent of Ni elements, 0.20 to 0.60 weight percent of Mo elements and the balance Fe and unavoidable impurities; the forging work procedure: the low-alloy steel cast ingots are forged, in addition, the blank opening forging heating temperature is 1160 DEG C to 1200 DEG C, the final forging temperature is 650 DEG C to 900 DEG C, and the deformation in each firing time is not smaller than 30 percent; and the heat treatment work procedure: the temperature of the forged and formed forgings is raised to 900 to 940 DEG C to be subjected to normalizing, the temperature is raised to 880 to 920 DEG C for carrying out quenching after the normalizing treatment, the temperature is raised to 530 to 600 DEG C for carrying out high-temperature tempering after the quenching treatment, and the low-alloy high-intensity high-toughness steel is obtained. In the embodiment of the invention, the low-alloy high-intensity high-toughness steel has high intensity and high toughness.
Owner:SANY GRP

Activating method of cathode material

InactiveCN102169979AAvoid attenuationAvoid problems with degraded cycle performanceCell electrodesUltrasound attenuationPhysical chemistry
The invention belongs to the technical field of lithium ion cells, and in particular discloses an activating method of a cathode material, which comprises the step of: under a water and oxygen-free environment, soaking the cathode material in an activating solution to activate the cathode material, wherein the general formula of the cathode material is xLi2MnO3.yLiMO3, x is more than 0 or less than 1, y is equal to 1-x, M is a metal element, both Li2MnO3 and LiMO3 have a laminated structure, the activating solution is an organic solution of an activating agent, and the activating agent is NO2BF4 or NO2PF4. The method provided by the invention can not cause loss of the Mn element in the cathode material and introduction of impurities in the generated cathode material. Meanwhile, because the activation is not acid activation, a cubic structure for damaging an oxygen layer is avoided being brought by the acid activation, problems of high capacity attenuation and reduced cycle performance of the cathode material prepared in the invention are avoided.
Owner:BYD CO LTD

Method for quantitatively examining center segregations of wire rod

The invention discloses a method for quantitatively examining the center segregation of a wire rod. The method comprises the following steps: taking two wire rod samples, rubbing down the cross section of one of the wire rod samples, splitting the other sample at the 2 / 3 position along the vertical direction of the wire rod sample, rubbing down the profile of the lager sample, putting the two rubbed surfaces next to each other in a same plane, inlaying through using a conductive resin, grinding the samples, polishing the plane when the width of the vertical profile of the wire rod sample is equal to the diameter of the other wire rod sample, and corroding the samples through using an alcohol solution of nitric acid; marking through drawing a line at the severest segregation position, and polishing the samples; and putting the samples in an electronic probe analyzer, finding the made mark through using a secondary electron image, carrying out C and Mn element X-ray intensity line analysis measurement of the full width of the samples through utilizing element characteristic X-ray spectrum analysis under an acceleration voltage of 10-20kV, an electron beam current of above 100nA and a beam spot dimension of 20-50mum, recording through using curves, testing the X-ray intensities of a standard sample of the analytic elements under same test conditions, converting the X-ray intensities in the curves into concentration contents, obtaining maximum concentrations and average concentrations from the curves, and obtaining the center segregation rates through calculating according to a formula of the center segregation rate=(the maximum value / the average value)*100%.
Owner:ANGANG STEEL CO LTD

Aluminum clad manganese-base laminated composite lithium ion battery cathode material and preparation method thereof

ActiveCN102593445AEliminate oxygen deficiencyStable structureCell electrodesAutomotive batteryManganese
The invention discloses an aluminum clad manganese-base laminated composite lithium ion battery cathode material and a preparation method thereof. According to the anode material, aluminum salt is coated on an outer surface of a manganese-base cathode material with a laminated structure in a chemical formula of Li(LixMn1-y-zM1yM2z)O2. The preparation method comprises the following steps of: (1) preparing a mixture; (2) sintering and treating powder; (3) preparing a corresponding amount of soluble aluminum salt, adding the soluble aluminum salt into the manganese-base laminated cathode material, and uniformly stirring; (4) preparing a NH3.H2O solution, a NH4F solution or a NH4H2PO4 solution, adding the solution into slurry of aluminum nitrate and the manganese-base laminated cathode material, and uniformly stirring; and (5) drying the slurry obtained in the step (4), and sintering at the temperature of between 400 and 800 DEG C for 5 to 15 hours. The aluminum clad manganese-base laminated composite lithium ion battery cathode material has high capacity, low first charging voltage platform and excellent long cycle performance, takes an Mn element as a basis, and is low in raw material cost and particularly suitable for preparing large batteries such as batteries of electric vehicles.
Owner:HUNAN SHANSHAN ENERGY TECH CO LTD

Preparation method of high-entropy alloy powder and cladding layer and application

The invention discloses a preparation method of high-entropy alloy powder and a cladding layer and application. The high-entropy alloy powder is composed of Fe, Ni, Cr, Al, Cu and Mn element powder, the composition is represented as FeNiCrAlCuMnx, wherein x is the mole ratio of Mn and its value range is 0-1. Matching calculation is carried out according to the mole ratio of each element, the mass of each component is accurately weighed, then the components are fully mixed to obtain the high-entropy alloy powder, and the high-entropy alloy powder is mixed with ethanol, then the mixture is used for coating the surface of a substrate material evenly, and after drying, laser cladding is carried out, thus obtaining the cladding layer. The invention provides the high-entropy alloy powder entirely composed of metal elements to conduct material surface modification, and through laser cladding, the cladding layer with a good shape can be obtained, thus improving the material hardness and wear resistance.
Owner:TIANJIN UNIV

980MPa-grade cold-rolled Q&P steel with excellent plasticity and manufacturing method thereof

The invention provides 980MPa-grade cold-rolled Q&P steel with excellent plasticity and a manufacturing method thereof. The 980MPa-grade cold-rolled Q&P steel comprises the following components of 0.18%-0.21% of C, 1.4%-1.6% of Si, 1.8%-2.1% of Mn, 0.04%-0.06% of Nb, 0.02%-0.05% of Al, less than or equal to 0.01% of P, less than or equal to 0.01% of S and the balance Fe. According to the 980MPa-grade cold-rolled Q&P steel with the excellent plasticity, compared with the prior art, noble metal elements such as Al, Ni and Mo are not added, the content of Mn is relatively low, the Mn element is mainly used for enriching and stabilizing austenite in the austenite, the plasticity of the material is obviously improved, and the product of strength and elongation can reach 25 GPa%; two-phase region annealing is adopted, the annealing temperature is low, and quenching partition treatment can be implemented on an existing continuous annealing production line through adopting an approximate one-step method; and on the other hand, through annealing treatment of the hot-rolled coil, the influence of the alloy element Mn on the material performance is improved, and equipment does not need to betransformed and invested.
Owner:MAANSHAN IRON & STEEL CO LTD

British standard B500B ribbed thread steel bar and production method thereof

The invention discloses a British standard B500B ribbed thread steel bar and a production method thereof. The British standard B500B ribbed thread steel bar comprises, by mass, 0.18%-0.22% of C, 0.20%-0.50% of Si, 0.80%-1.20% of Mn, 0%-0.035% of P and S, 0.10%-0.12% of V, 0.018%-0.025% of N, 0%-0.15% of Cr, Mo, Ni and Cu, and the balance Fe and inevitable impurities, wherein the carbon equivalent Ceq is smaller than or equal to 0.50%. According to the British standard B500B ribbed thread steel bar, the precipitation temperature and the brittle transition temperature of carbonitride can be lowered by optimizing and adjusting the content of the C element, the Si element and the Mn element and adding microalloy elements V, so that tensile strength, toughness and yield strength of coiled reinforced bars are effectively improved, and thus the British standard B500B ribbed thread steel bar meeting the tensile strength and yield strength requirements is obtained. According to the method, low-manganese and high-vanadium alloying is adopted, the control-rolling temperature and the control-cooling technology are matched to be reasonably designed, and the British standard B500B ribbed thread steel bar which is qualified in low-cost production performance and excellent in weldability is obtained. Economical benefits and social benefits are achieved.
Owner:HEBEI IRON AND STEEL
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