The invention discloses an all-
solid-state
lithium battery with a gradient structure and a preparation method thereof. The all-
solid-state
lithium battery comprises a
cathode with a gradient structure layer, a
solid electrolyte layer, and a
metal anode or an
anode with a gradient structure layer; the preparation method comprises the following steps: preparing
cathode slurries with different component concentrations or particle sizes or molecular weights,
coating a collector
electrode with the
cathode slurries according to the component
concentration gradient or particle size gradient or molecular weight gradient to prepare an
electrode layer,
coating the
electrode layer with the solid
electrolyte layer, finally attaching the
metal anode, or preparing anode slurries with different component concentrations or particle sizes or molecular weights,
coating the
electrolyte layer with the anode slurries according to an opposite
concentration gradient or particle size gradient or molecular weight gradient based on the preparation method of the
cathode electrode layer, and finally attaching a collector electrode to obtain the all-solid-state
lithium battery with a gradient structure; the preparation method is simple, and the prepared all-solid-state
lithium battery is stable in large-rate
charge and discharge, and can work normally at large current.