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117results about How to "Preparation method green" patented technology

Carbon material-loading manganese dioxide nanowire array composite and method for producing same

The invention provides a carbon material-loading manganese dioxide nanowire array composite and a method for producing the same, and relates to a manganese dioxide nanocomposite and a method for producing the same. According to the invention, the material consists of a carbon material and manganese dioxide; and the method comprises the steps that the carbon material, potassium permanganate and sulfuric acid are taken as raw materials, and after simple technologies of mixing, stirring, oxidation-reduction reaction, solid-liquid separation, washing and drying, the product is obtained. The method is simple, is convenient to operate, is environment-friendly, consumes less energy, and is low in production cost and convenient to popularize and apply; and the product which is produced through the method has the characteristics of high conductivity, high specific surface area, high proton diffusion coefficient, quick charging and discharging capability, excellent electrochemical performance and the like. The method can be widely used for producing manganese dioxide nanocomposite, the product which is produced by adopting the method can be widely applied in lithium ion batteries, solar cells, supercapacitors and other new energy devices, and is particularly suitable for being used as electric and heat conduction materials, catalyst carriers, sensors and other materials.
Owner:重庆锦添翼新能源科技有限公司 +1

Gold nanocluster-gold nanoparticle-titanium dioxide compound photocatalyst and application thereof

InactiveCN105214656APhotocatalytic activity regulationControl the degree of in situ conversionCatalyst activation/preparationHydrogen productionNanoparticlePhysical chemistry
The invention discloses a gold nanocluster-gold nanoparticle-titanium dioxide compound photocatalyst and application thereof. The gold nanocluster-gold nanoparticle-titanium dioxide compound photocatalyst having different particle sizes is firstly obtained by preparing a gold nanocluster solution based on chloroauric acid and a reducing type glutathione as raw materials and carrying out an impregnation method and illumination condition control on gold nanocluster solution and titanium dioxide nanoparticles. The gold nanocluster-gold nanoparticle-titanium dioxide compound photocatalyst is simple in preparation method without high temperature and high pressure conditions; compared with the existing gold nanocluster-titanium dioxide and gold nanoparticle-titanium dioxide catalysts, the gold nanocluster-gold nanoparticle-titanium dioxide compound photocatalyst disclosed by the invention is higher in photocatalytic efficiency and hydrogen production efficiency, can be used for hydrogen production by photolysis of water, and is beneficial to sustainable development of environments and energy sources.
Owner:FUZHOU UNIV

Porous carbon, and preparation method and applications thereof

The invention discloses a porous carbon, and a preparation method and applications thereof. The preparation method of the porous carbon comprises the following steps: (1) under the non-oxidizing condition, calcining at least one of alginic acid, sodium alginate, kalium alginate, lithium alginate, magnesium alginate and calcium alginate to obtain the porous carbon precursor; (2) treating the porous carbon precursor, which is obtained in step (1), with water or acid solution to obtain wet porous carbon; and (3) drying the wet porous carbon obtained in step (2) to obtain porous carbon. When the porous carbon is used as an electrode material for electrochemical capacitors, due to abundant multilevel pore structures and oxygen functional groups, the porous carbon can fully utilize the surface area in the structures and provide additional pseudo capacitance, so that the porous carbon has the advantages of higher capacity, energy density, power density and electrochemical stability. The preparation method is green and environment-friendly, and is very suitable for large-scale production.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Preparation method of polysaccharide-based nanometer particles sensitive to tumor microenvironments

ActiveCN104974305ADoes not affect particle sizeDoes not affect particle size distributionPharmaceutical non-active ingredientsAbnormal tissue growthCross-link
The invention discloses a preparation method of polysaccharide-based nanometer particles sensitive to tumor microenvironments. The preparation method comprises the steps: preparing an initiator solution by adding an initiator to a water-soluble polysaccharide solution and adjusting pH, then adding a monomer-containing solvent (or directly adding monomers) and a cross-linking agent sensitive to reducing environments for carrying out polymerization and cross-linking reaction so as to obtain nanometer particles, and finally carrying out dialysis or centrifugal treatment and freeze drying to obtain the polysaccharide-based nanometer particles sensitive to tumor microenvironments. The preparation method is green, pollution-free, high in yield, efficient and convenient in synthesis and low in cost; the prepared polysaccharide-based nanometer particles are high in solid content and uniform in particle sizes; due to introduction of the cross-linking agent sensitive to reducing environments, the nanometer particles sensitive to tumor microenvironments can be prepared and have a wide application prospect in aspects of design and application of carriers for tumor treatment.
Owner:SHANGHAI JIAO TONG UNIV

Hot-work die steel with good cutting performance and preparation method thereof

The invention provides hot-work die steel with good cutting performance and a preparation method of the hot-work die steel. The die steel comprises the following components of, in percentage by weight, 0.28%-0.31% of C, 0.56%-0.70% of Si, 1.10%-1.20% of Mn, smaller than or equal to 0.020% of P, 0.01%-0.05% of S, 0.40%-0.80% of V, 7.00%-8.00% of Cr, 0.20%-1.00% of Ni, smaller than or equal to 0.01%of Alt, 0.10%-0.30% of Cu, and 0.01%-0.02% of Ca, and meanwhile, the content of gas in steel is required to meet the conditions that [O] is smaller than or equal to 20 ppm, [H] is smaller than or equal to 3 ppm, [N] is 80 ppm to 120 ppm, and the balance is Fe and inevitable impurities. The preparation method comprises smelting, large slab continuous casting, heating, rolling, pre-treatment, normalizing and tempering; and the hot-work die steel has the advantages of high machinability and high corrosion resistance, and is suitable for continuous casting large slab production.
Owner:ANGANG STEEL CO LTD

Preparation method of sericin-polyvinyl alcohol blended antibacterial film loaded with nano-silver, and product and application of antibacterial film

The invention relates to a preparation method of a sericin-polyvinyl alcohol blended antibacterial film loaded with nano-silver, and a product and application of the antibacterial film. The preparation method is characterized in that silkworm cocoons are treated at high temperature and high pressure to obtain a sericin solution; then, the sericin solution and a prepared polyvinyl alcohol solution are blended, and are poured into a container; through freezing-unfreezing circulation, sericin-polyvinyl alcohol blended gel is obtained; drying is performed; a sericin-polyvinyl alcohol blended film is obtained; finally, the prepared film is added into an AgNO3 solution; the sericin-polyvinyl alcohol blended antibacterial film loaded with the nano-silver is obtained by an ultraviolet radiation reduction method. The prepared sericin-polyvinyl alcohol blended antibacterial film loaded with the nano-silver has good mechanical performance, water absorption performance and antibacterial performance, and is hopeful to be applied to the field of biomedical materials.
Owner:SOUTHWEST UNIVERSITY

Preparation method and application of flaky nano copper oxide

The invention discloses a preparation method and application of flaky nano copper oxide. The preparation method of the flaky nano copper oxide mainly comprises the following steps: accurately weighingcopper salt and oxalic acid or oxalate, uniformly mixing the copper salt and the oxalic acid or the oxalate, then grinding, adding a proper amount of distilled water in the grinding process to enablethe mixture to be in a fluid state, heating, cleaning and drying after grinding to obtain a precursor copper oxalate, and calcining the precursor copper oxalate to obtain the flaky nano copper oxide.A preparation technology is simple, no organic solvent except ethanol is used in a preparation process, the preparation method is environment-friendly and safe, and prepared flaky nano copper oxide particles are uniform in size and small in particle size, and have good photocatalytic degradation performance on a methylene blue solution.
Owner:GANSU AGRI UNIV

Bactericidal scale and corrosion inhibitor for seawater desalination

The invention provides a bactericidal scale and corrosion inhibitor for seawater desalination, and belongs to the technical field of chemical engineering. The bactericidal scale and corrosion inhibitor comprises, by weight, 10-15% of polyquaternary ammonium salt, 20-30% of sodium polyepoxysuccinate, 20-30% of polyaspartic acid-polymaleic anhydride, 5-10% of a zinc salt, 5-10% of dodecyl dimethyl benzyl ammonium bromide, and the balance of water. The bactericidal scale and corrosion inhibitor has scale inhibition, corrosion inhibition and sterilization functions, and all components of the bactericidal scale and corrosion inhibitor have very good intermiscibility, cooperativity and complementarity, so the bactericidal scale and corrosion inhibitor can substitute present single function scale and corrosion inhibitors and bactericides, and has comprehensive functions; and a formula and a preparation method of the bactericidal scale and corrosion inhibitor are green, compound raw materials adopted in the invention contain no phosphorus and cause no water eutrophication, discharged water causes no pollution to environment, and the preparation method is simple and feasible, is a clean technology, and has no emission of industrial three wastes.
Owner:安徽省蓝天能源环保科技有限公司

Triazinyl covalent network loaded metal single atom composite material, preparation method and application thereof

The invention relates to a triazinyl covalent network loaded metal single atom composite material, a preparation method and application thereof. The composite material comprises a triazinyl covalent network and transition metal single atoms loaded on the triazinyl covalent network, the triazinyl covalent network is composed of a structural unit shown in a formula (I), and the structural unit is formed by crosslinking a pyridine unit and a triazinyl ring. The composite material has a multilayer hierarchical porous structure, endows the material with extremely high specific surface area and rich catalytic active sites, and has excellent catalytic activity, excellent stability and methanol resistance in electrocatalytic oxygen reduction reaction. The method overcomes the defect that in the prior art, a monatomic catalyst is prone to agglomeration and causes unstable catalysis, single atoms can be evenly loaded in a triazinyl covalent network structure, the utilization rate of the single atoms is increased, side reactions in the electrocatalytic reaction are inhibited, and the selectivity of the electrocatalytic reaction is improved.
Owner:THE NAT CENT FOR NANOSCI & TECH NCNST OF CHINA

Preparation method for graphene

The invention discloses a preparation method for graphene. According to the method, the graphene is obtained by reduction and oxidization by adopting a food antioxidant. The preparation method is green, safe, mild and simple in the preparation process; and the obtained grapheme is high in quality and benefits mass preparation. The graphene prepared by the method has potential application value in aspects of separation, enriching, a composite material based on the grapheme and the like.
Owner:郴州博太超细石墨股份有限公司

Au@Se@Pt-Ce6 nano composite probe and preparation method thereof

The invention provides a preparation method of an Au@Se@Pt-Ce6 nano composite probe. The method comprises the following steps: (1) preparing Au nanoparticles, uniformly mixing an Au nanoparticle solution with a surfactant solution at 20-40 DEG C, adding a selenium source and ascorbic acid for reaction so as to obtain an Au@Se nanoparticle solution; (2) adding a Pt ion solution for reaction to obtain an Au@Se@Pt nanoparticle solution; and (3) modifying Ce6 in the Au@Se@Pt nanoparticle solution to obtain the Au@Se@Pt-Ce6 probe. The Au@Se@Pt-PAH-Ce6 nano composite probe synthesized by the methodhas good photothermal conversion performance, photodynamic treatment effect, photoacoustic imaging and thermal imaging capability, can be applied to photothermal treatment, photodynamic treatment andimaging for tumor cells, and has good application prospect in the aspect of multimodal imaging diagnosis and treatment of tumors.
Owner:NANJING UNIV OF POSTS & TELECOMM

Method for preparing high-crystallinity covalent organic framework film by using ionic liquid-water interface

The invention discloses a method for preparing a high-crystallinity covalent organic framework membrane by using an ionic liquid-water interface. The method comprises the following steps of: dissolving an aldehyde monomer in a hydrophobic ionic liquid to obtain a solution A; dissolving an amine monomer and an acid catalyst p-toluenesulfonic acid in deionized water to obtain a solution B; transferring the solution A into a reactor, adding deionized water to the surface of the solution A, layering, adding the solution B to the upper part of the deionized water layer, and performing a reaction for more than 3 days in the reactor under the condition of still standing at room temperature, so as tosynthesize the covalent organic framework membrane by using a double-diffusion control mechanism that the hydrogen-bond interaction of the acid catalyst and the amine monomer and the high viscosity of hydrophobic ionic liquid are utilized and the diffusion rates of the two monomers are limited at the same time. The covalent organic framework membrane prepared by the method has very high crystallinity, the specific surface area of themembrane is increased by 4 times compared with that of a covalent organic framework membrane synthesized on a traditional dichloromethane-water interface, and the solvent flux is also increased by 2 times under the condition that dye interception is not influenced.
Owner:HENAN NORMAL UNIV

Multifunctional natural super-hydrophobic material and application thereof

InactiveCN112264272AHas anti-fungal propertiesReduce wasteWax coatingsAnti-corrosive paintsCelluloseIcebox
The invention discloses a multifunctional natural super-hydrophobic material and application thereof. The material is a super-hydrophobic coating formed by modifying a safe and nontoxic hydrophobic substance on a phase transformation coating obtained by reducing protein with a reducing agent. The preparation method of the super-hydrophobic coating is simple, and the material can be adhered to thesurface of any base material and has good mechanical stability and hydrophobic stability. The super-hydrophobic coating can be used for modifying a cellulose membrane to obtain a recyclable super-hydrophobic packaging material with anti-mold performance, so that the adhesion of liquid food is resisted; medical materials (blood transfusion tubes, blood transfusion bags and the like) are modified, and the super-hydrophobic medical material capable of resisting biological fluid adhesion is obtained; ceramic surfaces of toilets, urinals and the like are subjected to super-hydrophobic modificationto resist adhesion of urine; super-hydrophobic modification is performed on living goods (clothes and aprons); and the material is used as a waterproof coating for large-area application scenarios (walls, ships, concrete reservoirs, wooden floors, interiors of refrigerators, interiors of range hoods, air conditioner water storage boxes and internal pipelines).
Owner:SHAANXI NORMAL UNIV

Preparation method and application of rare earth cerium-quantum dot coordination polymer double-emission fluorescent probe

The invention provides a preparation method of a rare earth cerium-quantum dot coordination polymer double-emission fluorescent probe. The method comprises the following steps that (1) triphosadenineis added into a tromethamine hydrochloride buffer solution; after the uniform mixing, carboxyl quantum dots and a Ce(NO3)3 solution are added; slow stirring and uniform mixing are performed at room temperature; a white turbid solution is formed; (2) the white turbid solution obtained in the first step is centrifugalized at a certain rotating speed for certain time; white precipitates are obtained;ultrapure water is used for cleaning for three times; the white precipitates are resuspended in 1mL of ultrapure water; the rare earth cerium-quantum dot coordination polymer double-emission fluorescent probe is prepared. The prepared double-emission fluorescent probe can be used for sensitive detection of hydrogen peroxide and glucose.
Owner:NANCHANG UNIV

Surface-enhanced Raman flexible substrate for quantitative detection of pesticide parathion-methyl and detection method

The invention discloses a surface-enhanced Raman flexible substrate and a method for quantitatively detecting a pesticide parathion-methyl. A filter paper sheet is soaked in a gold nanoparticle sol for a certain time, Au NP is adsorbed to the surface of the filter paper sheet to form the surface-enhanced Raman flexible substrate, and a strong Raman signal is generated, and residual pesticide molecules are detected; the reproducibility, stability and sensitivity of the substrate are evaluated by using a probe molecule 4-mercaptobenzoic acid, and a linear relationship between the concentrationof 4-MBA and Raman characteristic peak intensity is established; a parathion-methyl standard solution is detected by using the paper surface enhanced Raman flexible substrate, and a corresponding standard curve is established; and the substrate is applied to detection of pesticide residues on the surface of an actual sample through a pasting-uncovering method, and a result shows that the recoveryrate is high. According to the invention, the surface-enhanced Raman flexible substrate is constructed by combining a nano material with paper, and is used for rapidly detecting pesticide residues onthe surface of the actual sample, so that complex sample pretreatment is omitted, and the method has the characteristics of simplicity and high efficiency.
Owner:JIANGNAN UNIV

Solvent-free preparation method for substituted cyanoacetate compound

The invention discloses a solvent-free preparation method for a substituted cyanoacetate compound. The method is characterized by comprising the following steps: subjecting an aldehyde compound (I) represented by a formula shown in the description, cyanoacetate (II) represented by a formula shown in the description and a dihydropyridine ester (III) represented by a formula shown in the description to a hybrid reaction under solvent-free conditions, and carrying out separation and purification after the reaction is completed, thereby obtaining the substituted cyanoacetate (IV) represented by a formula shown in the description. According to the method, aldehydes, cyanoacetate and dihydropyridine esters serve as raw materials for the first time, and the substituted cyanoacetate can be efficiently synthesized through a one-pot method reaction without solvents and catalysts, so that the preparation method is simple, efficient and environmentally friendly.
Owner:XIHUA UNIV

Cellulose levulinate and method for preparing mixed ester with same

InactiveCN109134670AMild dissolutionEfficient functionalizationAcetic acidPropanoic acid
The invention discloses cellulose levulinate and a method for preparing mixed ester with the same. Hybrid reaction is carried out on celluloses, organic alkali and organic solvents to obtain cellulosesolution; levulinic acid base ester or angelica lactone is added into the cellulose solution, and reaction is carried out to obtain cellulose levulinate solution; anti-solvents are added into the cellulose levulinate solution, and then filtering, washing purification and drying are carried out to obtain the cellulose levulinate. The method includes dissolving the cellulose levulinate; adding acylation reagents; then adding C1-C4 low fatty alcohol, ethyl acetate or water; carrying out filtering, purification and drying to obtain the cellulose levulinic acid mixed ester. The cellulose levulinate and the method have the advantages that levulinic acid functional areas with active carboxyl are constructed on cellulose molecular chains in an in-situ manner, cellulose derivatives with novel structures, adjustable properties and levulinic acid structures are prepared, accordingly, the celluloses can be structurally specifically derived, and the cellulose levulinate and the method have important significance in high-valued utilization of the celluloses.
Owner:GUIZHOU UNIV

Method for preparing graphene composite based on combustion synthesis reaction

The invention discloses a method for preparing a graphene composite based on combustion synthesis reaction. The preparation method comprises the following steps of 1) uniformly mixing magnesium powderand aluminum oxide powder to obtain mixed powder; and 2) putting the mixed powder in a graphite grinding tool of a reactor, performing electrifying to induce propagating combustion reaction under thecarbon dioxide atmosphere, and performing cooling to obtain a graphene composite powder material. The invention provides a preparation technology based on magnesium thermal combustion, wherein by taking the magnesium powder and carbon dioxide as reactants, the combustion synthesis reaction is utilized to prepare graphene. The preparation method of the graphene is green, rapid and efficient and can realize scale production; and the technology has the advantages of simpleness in operation, short period and low cost.
Owner:TONGCHUANG KEXIN MATERIAL TECH CO LTD

Electrochemical method for self-doping modification of titanium dioxide photo-catalyst

The invention discloses an electrochemical method for self-doping modification of a titanium dioxide photo-catalyst. The electrochemical method comprises the following steps: firstly, anodizing a Ti sheet for in-situ growth of titanium dioxide nano-tubes (TiO2 NTs), then performing cathode reduction on the titanium dioxide nano-tubes to obtain Ti<3+> self-doped TiO2NTs and finally putting a samplein a tubular furnace in which nitrogen gas is introduced for high-temperature calcination to obtain self-modified TiO2NTs (Reduced TiO2 NTs) containing stable Ti<3+>. The electrochemical method disclosed by the invention has the benefits that firstly, due to the contained stable Ti<3+>, the material photo-catalytic activity is high, and the performance is stable; secondly, tubular structures of the prepared TiO2 NTs enable the directional transmission of photo-generated electrons, and due to larger specific surface area, light and contact contaminants are more easily captured; finally, a material preparation method is green and simple, and the prepared all-solid-state catalyst is convenient to use and recover and can also be used as an electrode to participate in the application to the electrochemical field. The catalyst with high performance loss can also be prepared again by ultrasonic cleaning, so that the catalyst regeneration is realized, and the cost is reduced.
Owner:NANCHANG HANGKONG UNIVERSITY

Method for determining ultratrace oleylamine grafted polysuccinimide based on carbon dot marked fluorometric immunosorbent method

The invention discloses a method for determining ultratrace oleylamine grafted polysuccinimide based on a carbon dot marked fluorometric immunosorbent method. The method comprises the following steps:preparing PSIOAm coating antigen and immunogen, injecting the immunogen into an animal body to obtain a high-specificity antibody, then preparing C-dots marked PSIOAm antibody into a fluorescent antibody, and then establishing carbon dot fluorometric immunosorbent to accurately determine the content of PSIOAm. By combining the specificity of the antigen and antibody reaction and the carbon dot with high fluorescent quantum yield, the PSIOAm nano particles are quantitatively detected and analyzed. A linear range of the detection method is 5*10<-4> to 5*10<2>ng / mL, and the detection limit can reach 0.15 pg / mL.
Owner:ANHUI NORMAL UNIV

Preparation method of sulfydryl chitosan photochromic microcapsule and material prepared from sulfydryl chitosan photochromic microcapsule and application thereof

The invention discloses a preparation method of a sulfydryl chitosan photochromic microcapsule and a material prepared from the sulfydryl chitosan photochromic microcapsule and application thereof. According to the method, first chitosan is modified with sulfydryl, a photochromic dye is coated with the sulfydryl-modified chitosan as a wall material by an emulsification-chemical crosslinking methodto obtain the photochromic microcapsule with excellent thermal stability and photo fatigue resistance. In application, the photochromic microcapsule is bonded to fabrics woven by protein fibers suchas wool and silk by a dipping-rolling method, thus giving the fabric photochromic properties. Compared with the existing technology, the preparation method is simple and easy to operate, toxic gases are released in the whole preparation process, and the preparation method is green, and environmental friendly, conforms to the concept of sustainable development, has no special requirements for equipment, can carry out large-scale production, and has good and broad application prospects.
Owner:JIANGNAN UNIV

Treatment process for degrading printing and dyeing wastewater through bismuth-based composite photocatalyst

The invention discloses a treatment process for degrading printing and dyeing wastewater through photocatalysis. An adopted photocatalyst is a bismuth nanocluster-bismuth nanoparticle / TiO2 / graphene composite photocatalyst. According to the catalyst, oxidized graphene is firstly prepared, then TiO2 with photocatalytic activity is loaded on a slice layer of the oxidized graphene, a bismuth nanocluster is modified onto a graphene slice layer of TiO2, and photo-reduction is carried out. The composite photocatalyst has high catalytic degradation activity aiming at the printing and dyeing wastewater. The treatment process provided by the invention solves the problem of low degrading efficiency of the printing and dyeing wastewater in the prior art, and is applicable to degrading organic dyes inthe printing and dyeing wastewater.
Owner:李雪琴

Porous magnesium manganate and preparation method and application thereof

The invention relates to porous magnesium manganate and a preparation method and application thereof. The preparation method of the porous magnesium manganate comprises the following steps of S1, mixing magnesium nitrate and manganese nitrate according to a molar ratio of (1 to 1.1):(1 to 1.1), adding a complexing agent and water, and dissolving to form a uniform solution; S2, gradually dripping ammonia water into the obtained uniform solution in step S1, stirring, reacting for 0.5 to 72h at the temperature of 40 to 100 DEG C, and drying, so as to obtain xerogel; S3, calcining the obtained xerogel in step S2 for 0.1 to 240h at the temperature of 150 to 750 DEG C, cooling, and grinding, so as to obtain the porous magnesium manganate. The preparation method of the porous magnesium manganatehas the advantages that the conditions are mild, the operation is simple, and the cost is low; the prepared porous magnesium manganate can be used as a catalyst to catalyze to degrade the undegradablepollutants in the environment.
Owner:SUN YAT SEN UNIV

Spicy pickled vegetable preparation method

The invention discloses a spicy pickled vegetable preparation method. The method includes steps: (a) Daokou oil preparation; (b) Ciba pepper preparation; (c) pickled vegetable preparation, to be morespecific, heating aged rapeseed oil obtained in the step (a) to 125-135 DEG C, adding pickled ginger, garlic and a part of Ciba pepper obtained in the step (b) into the heated aged rapeseed oil, keeping the temperature at 118-122 DEG C, and stir-frying for 4-6min; adding sauce, green peppers and a part of Daokou oil prepared in the step (a), controlling the temperature at 113-118 DEG C, and stir-frying for 4-6min; adding chopped pickled vegetables, controlling the temperature at 88-92 DEG C, stir-frying for 4-6min, stopping heating, adding high fructose corn syrup, seasonings and lactic acid,and well stirring to obtain spicy pickled vegetable. The spicy pickled vegetable preparation method is simple and beneficial to batch production, and the spicy pickled vegetable prepared according tothe method keeps original flavor and is a natural green food.
Owner:四川道泉老坛酸菜股份有限公司

Bamboo cellulose aerogel thermal insulation material as well as preparation method and application thereof

The invention discloses a bamboo cellulose aerogel thermal insulation material and a preparation method and application thereof. The preparation method comprises the steps that bamboo processing wasteis subjected to bleaching treatment to remove lignin to prepare holocellulose, the holocellulose is prepared into suspension liquid and then subjected to ultrasonic crushing, and then pre-freezing and vacuum freeze-drying treatment are conducted in sequence. The preparation method comprises a chemical treatment step, an ultrasonic treatment step and a freezing treatment step, so that the use of chemical agents can be greatly reduced, and the preparation method is green and environmentally friendly; the preparation method is simple in preparation process, low in energy consumption, short in preparation time, wide in raw material source, low in price, low in cost and wide in practical application prospect; the prepared bamboo cellulose aerogel thermal insulation material not only has certain strength, but also has a good thermal insulation effect, can effectively improve the utilization rate and the industrial added value of the bamboo processing waste, expands the recycling way of thebamboo processing waste, and is of great theoretical significance.
Owner:INT CENT FOR BAMBOO & RATTAN

Lanthanum-based two-dimensional metal organic framework Ln-TDA nanosheet and preparation method and application thereof

The invention provides a lanthanum-based two-dimensional metal organic framework Ln-TDA nanosheet and a preparation method and application thereof, and belongs to the technical field of water treatment materials. The preparation method comprises the following steps: dissolving 2, 2'-thiodicarboxylic acid and lanthanide metal salt into an alkali metal hydroxide aqueous solution to obtain reaction liquid; and carrying out microwave reaction on the reaction liquid under an ultrasonic condition to obtain the lanthanum-based two-dimensional metal organic framework Ln-TDA nanosheet. According to the preparation method, 2, 2'-thiodicarboxylic acid is taken as an organic ligand, lanthanide series metal is taken as a metal source, under the condition that layered-structure MOFs are synthesized through microwave heating, interlayer force can be effectively destroyed through ultrasonic vibration, and single-layer or few-layer two-dimensional nanosheets can be obtained through a one-step method; operation is simple and efficient; and the tedious steps of post-treatment and the like for obtaining the nanosheet by ultrasonically stripping the layered blocky material through an organic solvent are avoided.
Owner:YUNNAN UNIV

High-activity molybdenum compound loaded boron fuel and ion exchange method preparation method

The invention provides a molybdenum compound-loaded boron fuel and an ion exchange method preparation method, the method adopts an ion exchange method to load molybdenum compound particles or films on the surface of boron powder to form the molybdenum compound-loaded boron fuel; the ion exchange method comprises the following steps: by taking molybdenum salt as a molybdenum source, carrying out ion exchange on the molybdenum source and the surface of boron powder to obtain an exchange intermediate product, and heating the exchange intermediate product at high temperature to prepare the boron fuel loaded with the molybdenum compound. The content of the molybdenum compound in the boron fuel loaded with the molybdenum compound is 0.1 wt.%-10 wt.%. The prepared molybdenum compound / B can provide more molybdenum compound-B active interfaces, the oxidation process of boron powder can be obviously catalyzed even if the content of the molybdenum compound is low, and the activity is high.
Owner:XIAN MODERN CHEM RES INST

Deacidfieation method of high-acid-value vegetable oil

The invention discloses a deacidfieation method of high-acid-value vegetable oil. The deacidified vegetable oil is obtained by mixing and dissolving the high-acid-value vegetable oil and monoethanolamine in an organic solvent, adding a catalyst, reacting for 1-24 hours at the temperature of 50-100 DEG C, and removing the catalyst, the unreacted monoethanolamine and fatty acid glycollic amide in the vegetable oil after the reaction. The invention provides a deacidfieation process of the high-acid-value vegetable oil, calcium oxide which is extensive in sources, low in price and easy to obtain is taken as the catalyst, and monoethanolamine is taken as an acyl acceptor for an amidation reaction with free fatty acid in the high-acid-value vegetable oil, so that the problems of high consumptionof neutral oil, high energy consumption, a large number of byproducts, strict process, high cost and the like in the previous deacidfieation process are avoided, and the deacidfieation method is suitable for the high-acid-value vegetable oil. The deacidfieation method meets the new national standard for the vegetable oil that an acid value is not higher than 3 mg KOH per g, and is simple in process, low in cost, green, efficient, and huge in application potential.
Owner:JIANGNAN UNIV
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