The invention relates to a
palladium complex containing a meta-position
carborane triazole ligand and a preparation method and application of the
palladium complex. The
palladium complex is prepared by the following steps: (1) dropwise adding an n-BuLi solution into a meta-position
carborane m-C2B10H12 solution, carrying out stirring and reacting, then adding 3-
propargyl bromide for a reaction again, and after the reaction is finished, carrying out separating to obtain 1,3-dipropargyl meta-
carborane; and (2) under the catalytic condition of a catalyst CuI, carrying out a reaction on 1,3-dipropargyl meta-carborane and
aryl azide, then adding PdCl2 into a
reaction system, continuing the reaction, and after the reaction is finished, carrying out separation to obtain the palladium complex containing the meta-carborane
triazole ligand. Compared with the prior art, the preparation method provided by the invention is simple and green; the complex can efficiently catalyze a
coupling reaction of mercaptan and halogenated
hydrocarbon to synthesize
thioether compounds;
reaction conditions are mild, substrate universality is good,
catalytic efficiency is high, and few byproducts are produced;and the catalyst has high stability and is not sensitive to air and water.