The present invention provides a method of manufacturing Group III
nitride crystals that are of high quality, are manufactured highly efficiently, and are useful and
usable as a substrate that is used in
semiconductor manufacturing processes. The method of manufacturing Group III
nitride crystals includes: forming a first layer made of a
semiconductor that is expressed by a composition formula of AlsGatIn1-s-tN (where 0≦s≦1, 0≦t≦1, and s+t≦1); forming a second layer by bringing the surface of the first layer into contact with a melt in an
atmosphere including
nitrogen, wherein the second layer includes greater defects in a
crystal structure, such as a
dislocation density for example, than those of the first layer, and the melt includes
alkali metal and at least one Group III element selected from the group consisting of
gallium, aluminum, and
indium; and forming a third layer through
crystal growth in the melt in an
atmosphere including
nitrogen, wherein the third layer is made of a
semiconductor that is expressed by a composition formula of AluGavIn1-u-vN (where 0≦u≦1, 0≦v≦1, and u+v≦1), and the third layer has less defects in a
crystal structure, such as a
dislocation density for example, than those of the second layer.