The invention discloses a preparation process of multi-layer composite automobile leather. The automobile leather sequentially comprises a sunscreen
coating layer, a leather layer, a non-woven fabriclayer, a non-glue cotton layer and a knitted fabric layer from outside to inside. The preparation process of the automobile leather comprises the following steps: step 1, depilating,
degreasing,
softening and
pickling dry leather or salt leather to obtain leather collagen fibers, tanning and
dyeing the leather collagen fibers, washing the leather collagen fibers with water, taking the leather collagen fibers out of a drum, and carrying out stacking and
drying in vacuum to obtain leather; step 2, uniformly spraying a sun-screening
emulsion on the surface of the leather prepared in the step 1 ina spraying manner, and then performing heating and shaping to obtain leather containing a sun-screening
coating layer; and step 3, sequentially stacking the leather containing a sunscreen
coating layer prepared in the step 2, non-
woven fabric, non-glue cotton and knitted fabric, and performing pressing, sewing and trimming to obtain the multi-layer composite automobile leather. The sunscreen
emulsion is uniformly sprayed on the surface of the leather in a spraying manner, so that the protective property and the sunscreen property of the leather are improved, and the
ageing resistance of the automobile leather is improved.