The invention discloses a high-
Curie-point low-resistivity lead-free PTCR (
Positive Temperature Coefficient of Resistance)
ceramic material with a constitution formula (1): [Bi0.5(Na1-xKx)0.5]y[Ba1-y-z-j]TiO3+zLn3++jCn2++kSi2++wMn(NO3)2. In the formula, x is equal to 0.1-0.5, y is equal to 0.1-0.3, z is equal to 0.001-0.01, j is equal to 0.1-0.2, k is equal to 0.01-0.05, w is equal to 0.0001-0.001, Ln comprises one or two elements of Sm, Nd, Y and La, and Cn comprises at lest one of Ca and Sr. The preparation method comprises the following steps of: (1) respectively preparing solutions containing Bi, Na, K, Ba, Ti, Ln, Cn, Si and Mn ions and preparing a
mixed solution according to a mol ratio given in formula (1); (2) mixing the
mixed solution, organic monomers and a crosslinking agent according to a proportion of 100ml: (6-20)g: (0.5-8)g and crosslinking and polymerizing the organic monomers and the crosslinking agent in the solution to obtain gel; (3) calcining at 700-800 DEG C for 1-3h to obtain
ceramic powder; and (4) granulating the
powder, drily pressing to form and calcining at a high temperature of 1200-1300 DEG C for 1-2h. The
ceramic material has the advantages of high
Curie point and low resistivity.