The invention discloses a method for preparing a hollow
antimony-based
binary alloy composite
nanofiber material based on electrostatic
spinning and
potassium storage application of the hollow
antimony-based
binary alloy composite
nanofiber material. According to the method, PAN and PMMA are taken as precursors, after
antimony trichloride, CNT,
nickel acetate, stannous
chloride and
cobalt chlorideare dissolved into DMF according to a certain proportion to form a
spinning solution, the
spinning solution is transferred into a disposable
injector, electrostatic spinning is carried out in electrostatic spinning equipment, and a
nanofiber membrane is obtained. After
vacuum drying, the
fiber membrane is put into a tubular furnace, the temperature is increased to 230-300 DEG C at a low temperature increase rate, heat preservation is carried out for a certain time, pre-
carbonization is carried out, then the temperature is increased to 600-800 DEG C at a large temperature increase rate,
carbonization is carried out, and a sample obtained after
carbonization is marked as XSb (X = Ni, Sn, Co) / CNT / PC. A carbon framework provides a three-dimensional conductive network, the PMMA is pyrolyzed togenerate a hollow channel,
alloy particles are embedded in the inner and outer surfaces of
carbon fibers, by means of the CNT, the overall
conductivity of the material is improved in the
carbon fibers, and therefore the material shows excellent comprehensive electrochemical performance when used as a
potassium ion battery electrode material.