The invention discloses a method for preparing super
thermal isolation polymer materials from
polymer nanometer hollow capsules. According to the method, firstly, hydrophilic and oleophilic macromolecular reversible addition fragmentation
chain transfer reagents are used for preparing
polymer nanometer capsules, then, inter-
capsule cross linking agents are prepared, finally, the inter-
capsule cross linking agents and the polymer nanometer
capsule emulsion are mixed according to a
mass ratio of capsule to inter-capsule cross linking agents of 2.5:1 to 0.8:1, the pH is regulated to be 3.0 to 6.8, the reaction lasts 30 minutes to 24 hours at the temperature being 60 to 90 DEG C, the
emulsion is gelatinized, then, core
paraffin wax in the nanometer capsules is replaced through
tetrahydrofuran, and polymer nanometer porous materials are obtained through
vacuum drying. The method has the advantages that the preparation process is simple, and the
porosity and the pore size can be regulated through changing the
solid content of the nanometer capsule
emulsion, the consumption of etherified
melamine formaldehyde resin and the self
porosity of the nanometer hollow capsules. In addition, compared with the traditional
thermal isolation materials, the porous materials have high
mechanical strength.