Polyether sulfone/poly butylene carbonate hollow fiber blend membrane and preparation method thereof
A technology of polybutylene carbonate and polyethersulfone, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve the problems of polyethersulfone non-biodegradation, environmental pollution, etc., and achieve good biodegradation Sex, the effect of improving hydrophilicity
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Embodiment 1
[0033] The ingredients and mass percentages are as follows: polyethersulfone 10%, PBC 5%, dimethyl sulfoxide 75%, polyvinylpyrrolidone (PVP-K30) 10%. Add the above raw materials into the container, heat to 70°C, stir and dissolve to make a solution, filter the solution, and vacuum defoam for 5 hours. Fill the spinning solution into a barrel with heating and heat preservation function, and keep the temperature at 70°C. The spinning solution is extruded from the spinneret used for spinning hollow fiber membranes, and solidified and formed by wet spinning process. The parameters are: air layer height 0 cm, coagulation bath water, temperature 20°C. Single-stage stretching, the water bath is used as the stretching medium, the temperature of the water bath is 50°C, and the stretching ratio is 1.5 times. Then the solvent and part of the porogen were removed in water at 75°C, dried under nitrogen protection, and sterilized to obtain the polyethersulfone and polybutylene carbonate hol...
Embodiment 2
[0035] The ingredients and mass percentages are as follows: polyethersulfone 11%, PBC 4%, polyethylene glycol (molecular weight 10000) 10%, dimethylacetamide 75%. Put the above-mentioned raw materials into a container, heat to 75°C, stir and dissolve to form a solution, filter the solution, and vacuum defoam for 5 hours. The spinning solution is loaded into a barrel with heating and heat preservation function, and the temperature is kept at 75°C. Dimethylacetamide and water are prepared into a spinning coagulation bath, and the mass percent concentration of dimethylacetamide is 2%. It is extruded with a spinneret for spinning hollow fiber membranes, and solidified by a dry-wet spinning process. The parameters are: the height of the air layer is 5cm, and the coagulation bath is dimethyl acetamide with a mass percentage concentration of 2%. Acetamide aqueous solution, temperature 15°C. The stretching is carried out in two stages, the water bath is used as the stretching medium...
Embodiment 3
[0037] The ingredients and mass percentages are as follows: polyethersulfone 12%, PBC 3%, polyvinylpyrrolidone (PVP-K90) 8%, N-methyl-2-pyrrolidone 77%. Add the above-mentioned raw materials into a container, heat to 65°C, stir and dissolve to form a solution, filter the solution, and vacuum defoam for 5 hours. The spinning solution is loaded into a barrel with a heating and heat preservation function, and the temperature is kept at 65°C. N-methyl-2-pyrrolidone and water are prepared into a spinning coagulation bath, and the mass percent concentration of N-methyl-2-pyrrolidone is 3%. It is extruded with a spinneret spinning a hollow fiber membrane, and solidified by a dry-wet spinning process. The parameters are: the height of the air layer is 10 cm, and the coagulation bath is methyl-2-pyrrolidone with a mass percentage concentration of 3%. -2-Pyrrolidone aqueous solution, temperature 10°C. The stretching is carried out in two stages, the water bath is used as the stretchin...
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