The invention discloses a preparation method of a textured structure of a
crystalline silicon solar cell. The method includes the steps of (1) cleaning and texture preparation, (2) soaking a
silicon wafer in a solution containing
metal ions to enable the surface of the
silicon wafer to be coated with a layer of
metal nanometer particles, (3) corroding the surface of the
silicon wafer to form a nanometer-grade texture, (4) cleaning to remove the
metal particles, (5) carrying out
microstructure amendment
etching in second chemical corrosive liquid, and (6) cleaning and spin-
drying. As is proved by a test, the size of the textured structure is between 100nm-500nm; the textured structure is of a
nanopore shape with a large hole
diameter and a small depth, or a nanometer
pyramid with edge angles, or of a nanometer pit shape structure with an edge angle nanometer cone body or with an edge angle; and compared with a nanometer-
micrometer composite textured structure disclosed in CN102610692A, the textured structure enables conversion efficiency of a
cell piece to be improved by about 0.2%-0.5%, and an unexpected effect is achieved.