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220results about How to "Renewable" patented technology

Magnetic fluorescent difunctional nano material based on natural polymer and preparation method thereof

The invention relates to a multifunctional nano composite material of a core-shell structure and in particular relates to a carbon quantum dot magnetic fluorescent difunctional nano material and a preparation method thereof. Magnetic particle Fe3O is taken as a core, chitosan and polyanionic-based cellulose are taken as shell material, a carbon quantum dot is taken as a fluorescent material, and the carbon quantum dot magnetic fluorescent difunctional nano material is obtained by adopting a layer-by-layer self-assembly method; the carbon quantum dot is coated by adopting a natural polymer material, so that no free carbon quantum dot is formed, and stability is improved; magnetic property and fluorescence strength can be regulated and controlled by virtue of number of layers of the shell material and the addition amount of the carbon quantum dot; the obtained magnetic fluorescent difunctional nano material has a broad application prospect in the biological medicine fields of cell marking and absorption, bioimaging, medicine detection and disease diagnosis, medicine carrying and the like.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material and preparing method thereof

The invention discloses a plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material and a preparing method of the plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material. The plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material is formed by adding plant fibers which have different lengths and are of a hollow structure into phenolic resin. The preparing method of the plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material comprises the steps that the dried plant fibers, obtaining through cutting, with the different lengths are mechanically mixed with the phenolic resin, an emulsifying agent, a coupling agent, a foaming agent and a curing agent, the mixture is cured and foamed for 30 min to 120 min at the curing temperature ranging from 45 DEG C to 80 DEG C, and then the plant fiber reinforcing type phenolic foam material used for internal walls and external walls of buildings is obtained after demolding. According to the plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material and the preparing method of the plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material, phenolic foam is reinforced through the environment-friendly and renewable natural plant fibers, the heat-preservation property and the inflaming-retarding property of the material are good, and the production cost of the phenolic foam material is greatly reduced due to the fact that the plant fibers are cheap and easy to obtain.
Owner:BEIHANG UNIV

Amphoteric-cellulose-based composite material and application thereof

The invention discloses an amphoteric-cellulose-based composite material and application thereof. Quaternary ammonium-sulfonic acid cellulose serves as a carrier, grapheme oxide and chitosan are loaded in a blending manner, binding force among the three is utilized, and a quaternary ammonium-sulfonic acid cellulose / grapheme oxide / chitosan composite porous material is obtained through freeze drying. The quaternary ammonium-sulfonic acid cellulose / grapheme oxide / chitosan composite porous material comprises, by weight, 5-8 parts of quaternary ammonium-sulfonic acid cellulose, 0.5-3 parts of grapheme oxide and 0.5-3 parts of chitosan, is safe, non-poisonous and good in biocompatibility and degradability, has an orderly three-dimensional porous structure, good mechanical strength and efficient adsorption capability, can be used for water absorption and oil removal and processing of heavy metal ion waste water and organic waste water, and hopefully serves as a filtering material such as an air purification material and a medical adsorption material for use.
Owner:SUZHOU UNIV

Ethanol conversion method

Belonging to the chemical field of plasma synthesis, the invention relates to a method for direct preparation of polyols and higher alcohols from ethanol. The method is characterized by: choosing dielectric barrier discharge, corona discharge, pulsed corona discharge, glow discharge, radio frequency discharge, gliding arc discharge or microwave plasma and other discharge methods to perform selective activation to ethanol molecules, then setting the residence time of a reaction mixture in a reaction zone, the discharge reaction temperature, the discharge reaction pressure, and the mole ratio between a carrier gas and ethanol, conversing the selectively activated ethanol into target products. The method of the invention adopts ethanol as the raw material for preparing polyols and higher alcohols, while ethanol has various sources and renewability. The method provided in the invention belongs to a one-step synthesis technology, and has the advantages of no need for catalyst, no environmental pollution, as well as high selectivity.
Owner:DALIAN UNIV OF TECH

Method for preparing composite fibers in ionic liquid medium

The invention discloses a method for preparing composite fibers in an ionic liquid medium. The method comprises the following steps: (1) oxidating cellulose into carboxyl cellulose in an oxidation system prepared from ionic liquid, nitric acid and NaNO2, and preparing a carboxyl cellulose solution; (2) subjecting silkworm cocoons to soda boiling, degumming, LiBr dissolving, dialysis and vacuum freeze drying so as to obtain silk fibroin, and then, preparing a silk fibroin solution in ionic liquid; (3) grafting the carboxyl cellulose to the silk fibroin in ionic liquid, thereby obtaining the composite fibers. According to the method, the ionic liquid serves as a solvent, cellulosic materials and the silkworm cocoons serve as raw materials, the chemical principle of amidation reaction is adopted, the preparation process is simple, the reaction is green, environment-friendly and pollution-free, the ionic liquid solvent can be recovered and reused through rotary-evaporation drying, and the recovery rate reaches 98%. The reaction system only needs an isothermal reaction of 1 to 2 hours, the percentage of grafting of the cellulosic materials reaches 21% to the maximum, and the composite fibers are excellent in mechanical properties, crinkle resistance, wear resistance and hygroscopic property and are degradable and reproducible.
Owner:JIANGSU UNIV OF SCI & TECH

Preparation method of biocompatible silk fibroin film for flexible magnetoelectric device substrate

A preparation method of a biocompatible silk fibroin film for a flexible magnetoelectric device substrate comprises the following steps: 1, preparing a pure aqueous silk fibroin solution from naturalsilk, used as a substrate making material; 2, cleaning a rigid substrate; 3, coating the clean rigid substrate with the aqueous silk fibroin solution; 4, carrying out natural air drying, convection air drying or drying on the solution-coated rigid substrate; and 5, stripping the silk fibroin film from the surface of the rigid substrate after the water is completely evaporated in order to form theindependently supported biocompatible flexible silk fibroin film. The method using the natural silk as the raw material for preparing the flexible magnetoelectric device substrate has a simple and rapid preparation process and a high success rate, and can provide a substrate for health monitoring flexible magnetoelectric devices having great application values.
Owner:XI AN JIAOTONG UNIV

Method of preparing small molecule polyol from carbohydrate under near-critical or supercritical conditions

The method provides a method of preparing small molecule polyol such as glycol and propylene glycol from Cn(H2O)m compounds such as straw, paper pulp, waste paper, cellulose, starch, semi-cellulose, cane sugar, glucose, fructose, fructosan, xylose, and soluble xylo oligosaccharide under the near-critical or supercritical conditions. In the method, carbohydrate is taken as the raw material, the 8, 9 and 10 groups of transition metals, namely iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, are taken as the catalytic active components, one-step catalytic conversion process is carried out under the near-critical and supercritical water conditions: temperature of 300 to 450 DEG C, hydrogen pressure of 1 to 10 MPa, and total pressure of 10 to 35 MPa, and high efficient, high selective, and high yield preparation of small molecule polyol such as glycol and propylene glycol is achieved. The reaction provided by the invention has the prominent advantages of recyclable raw material and high atom economy, and the preparation of the catalyst has the advantages of simple and easy process and low cost. Furthermore, compared to other technologies, which prepare polyol from biomass, the method has the advantages of simple reaction process, high space time yield, and convenience for industrial production.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Method of recovering tungsten-based catalyst from complex reaction substrate

In reaction for preparing low-carbon alcohol through catalytic conversion of a carbohydrate compound, a tungsten-based catalyst may be wholly or partly dissolved in a reaction substrate, and is difficult to recover, and the cost of the catalyst is increased. The invention provides a method of recovering the tungsten-based catalyst from a complex reaction substrate. The method is characterized in that the complex reaction substrate is a rectification residual product after the catalytic conversion of the carbohydrate compound, after reaction products are subjected to rectification for separation of glycol and propylene glycol, a kettle bottom residual product is obtained, a boiling point of the kettle bottom residual product is greater than or equal to 200 degrees, and the kettle bottom residual product contains tungsten salt; and through adding an organic solvent to the kettle bottom residual product, the tungsten salt is dissolved out and recovered, fusel having a high boiling point is obtained, and a mass recovery rate of the tungsten salt is greater than or equal to 90%. According to the method, a catalyst recovery process is simple, the catalyst recovery efficiency is high, and the cyclic activity of the tungsten-based catalyst is excellent. In addition, the overall process facilitates operation and industrialized production.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

High-roughness reproducible high-friction coefficient wear-resistant coating and preparing method thereof

The invention discloses a high-roughness reproducible high-friction coefficient wear-resistant coating and a preparing method thereof. 1) metal is used as a coating material, metal ceramic particles are used as a coated material, and the metal ceramic particles are coated with the metal to prepare a spraying powder raw material, wherein the metal as the coating material is the same as the metal used for the metal ceramic particles as the coated material or is similar with the metal used for the metal ceramic particles as the coated material in thermophysical characteristic; and 2) a heat spraying method is adopted to heat the spraying powder raw material prepared in the step 1) until the state that the metal as the coating material is completely melted or nearly completely melted is obtained, semi-molten particles with cores of the metal ceramic particles of the coated material not melted are formed, and the semi-molten particles collide a metal substrate to be sprayed and deposited onthe surface of the metal substrate to form a metal ceramic coating, namely the high-roughness reproducible high-friction coefficient wear-resistant coating. A new method is provided for preparing thehigh-performance long-life high-roughness reproducible metal-based wear-resistant coating.
Owner:XI AN JIAOTONG UNIV

Hybrid industrialized architectural structural system and construction method thereof

The invention discloses a hybrid industrialized architectural structural system and a construction method thereof. The hybrid industrialized architectural structural system comprises a structural system, wherein the structural system is formed by connecting structural columns, structural beams, shear walls and floors; the structural columns are steel columns or concrete filled steel tube columns or steel tube reinforced concrete columns; at least one of the structural beams is a prefabricated variable-stiffness hybrid combination beam; at least one of the shear beams is a prefabricated shear wall; the prefabricated shear wall is connected into a frame structure formed by being enclosed by the structural columns and the prefabricated variable-stiffness hybrid combination beam; the prefabricated variable-stiffness hybrid combination beam comprises a steel skeleton and reinforced concrete blocks arranged on two sides of a web plate of the steel skeleton. By using the hybrid industrialized architectural structural system and the construction method thereof, the technical problems that a conventional cast-in-place concrete structure is poor in shock resistance performance and long in construction time and a conventional steel structure is poor in fire resistance are solved.
Owner:姚攀峰
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